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公开(公告)号：US4066628A
公开(公告)日：1978-01-03
申请号：US710607
申请日：1976-08-02
IPC分类号： C07D263/24 , C08G18/00 , C08G18/22 , C08G18/58 , C09D175/00 , C08G59/14
CPC分类号： C08G18/003 , C07D263/24 , C08G18/222
摘要： Oxazolidones are produced by reacting an organic isocyanate with an epoxide in the presence of a catalyst selected from the group consisting of dialkyl zinc, zinc carboxylate, organozinc chelate compound and trialkyl aluminum. Polyoxazolidones produced according to the present invention are useful starting materials for the manufacture of a wide variety of product including foams, coatings, adhesives, elastomers and the like.
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2.发明授权
公开(公告)号：US5091436A
公开(公告)日：1992-02-25
申请号：US482298
申请日：1990-02-20
申请人： Kurt C. Frisch , Kaneyoshi Ashida
发明人： Kurt C. Frisch , Kaneyoshi Ashida
CPC分类号： C08G18/6705 , C04B26/16 , C08G18/637 , C04B2201/20 , C08G2101/0066 , C08G2101/0075 , C08G2101/0083 , Y02W30/92 , Y10T428/249955 , Y10T428/249958 , Y10T428/249964 , Y10T428/249981 , Y10T428/249986 , Y10T428/24999 , Y10T428/31551 , Y10T428/31554 , Y10T428/31598 , Y10T428/31601
摘要： There is disclosed a polyurethane/unsaturated polyester hybrid foam of the rigid type prepared from novel components including not only polyol and polyisocyanate but also a unique hydroxy-containing vinyl ester and vinyl monomer, optionally together with an additional polar vinyl monomer, all together providing the necessary components for a hybrid polyurethane-polyvinyl ester matrix, which mixture of components before foaming is capable of having suspended therein fillers and reinforcing fibers to produce a foam or reinforced foam composite having a density between about 20 and 100 pounds per cubic foot. The reinforced foam can be made into baords and the like and advantageously has continuous fiberglass strands or yarn disposed longitudinally in or adjacent the surface skin of the foam. The strands or yarn are preferably parallel and close together and are preferably flattened out in the foam-forming process so that the surfaces have a continuous fiberglass implant longitudinally and substantially so transversely. One preferred structural composite is illustrated in the drawings.
摘要翻译： 公开了一种由新型成分制成的刚性类型的聚氨酯/不饱和聚酯混合泡沫体，其不仅包括多元醇和多异氰酸酯，而且还包括独特的含羟基的乙烯基酯和乙烯基单体，任选与另外的极性乙烯基单体一起提供 用于混合聚氨酯 - 聚乙烯酯基质的必需组分，其中发泡前组分的混合物能够悬浮在填料和增强纤维中以产生密度在约20和100磅/立方英尺之间的泡沫或增强泡沫复合材料。 增强的泡沫可以制成保持器等，并且有利地具有连续的玻璃纤维束或纱线，其纵向放置在泡沫的表面皮肤中或附近。 绞线或纱线优选平行并靠近在一起，并且优选在泡沫形成过程中被平坦化，使得表面具有纵向和基本上如此横向的连续玻璃纤维植入物。 在附图中示出了一种优选的结构复合材料。
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公开(公告)号：US4680214A
公开(公告)日：1987-07-14
申请号：US838942
申请日：1986-03-12
申请人： Kurt C. Frisch , Kaneyoshi Ashida
发明人： Kurt C. Frisch , Kaneyoshi Ashida
CPC分类号： C08J9/0085 , C08G18/092 , C08G18/4009 , C08G18/4018 , C08J9/0066 , E04C2/205 , C08G2101/0025 , C08G2101/0066 , C08J2375/04 , Y10T428/24074 , Y10T428/249946 , Y10T428/249989
摘要： There is disclosed a polyurethane foam of the rigid type having three different types of polyol components capable of having suspended therein fillers and reinforcing fibers. The foam is made into boards and the like and has continuous fiber glass strands or yarn disposed longitudinally in or adjacent the surface skin of the foam. The strands or yarn are parallel and close together and are flattened out in the foam-forming process so that the surfaces have a continuous fiber glass implant longitudinally and substantially so transversely.
摘要翻译： 公开了一种具有三种不同类型的能够悬浮在其中的多元醇组分的刚性类型的聚氨酯泡沫和增强纤维。 泡沫制成板等，并且具有连续的玻璃纤维束或在纵向上布置在泡沫的表面表面上的纱线。 股线或纱线平行并靠近在一起，并且在泡沫形成过程中被平坦化，使得表面具有纵向和基本如此横向的连续的玻璃纤维植入物。
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公开(公告)号：US4614615A
公开(公告)日：1986-09-30
申请号：US723309
申请日：1985-04-15
IPC分类号： C08G18/10 , C08G69/18 , C08G69/20 , C07D223/10 , C07D211/16 , C07D207/38
摘要： The invention relates to a process for preparing an N-substituted carbamoyl-lactam compound having the formula: ##STR1## by admixing a polyhydroxy compound having the formula R(OH).sub.n with a polyisocyanate having the formula OCH--R'--NCO, wherein saidn has a value of at least 3,R' is a di-valent hydrocarbon group having 6-25 carbon atoms, andY is a C.sub.3 -C.sub.14 alkylene group,and reacting the product thereof with a lactam. The n value may advantageously range from 3 to 10. The invention also relates to certain novel n-substituted carbamoyl-lactam compounds which can advantageously be used in the preparation of nylon 6 block copolymers, and are particularly useful in reaction injection molding nylon 6.
摘要翻译： 本发明涉及通过将具有式R（OH）n的多羟基化合物与具有式OCH-R'-NCO的多异氰酸酯混合制备具有下式的N-取代氨基甲酰基 - 内酰胺化合物的方法：其中 所述n的值至少为3，R'是具有6-25个碳原子的二价烃基，Y是C3-C14亚烷基，并使其产物与内酰胺反应。 n值可以有利地在3至10的范围内。本发明还涉及某些新颖的n-取代氨基甲酰基 - 内酰胺化合物，其可有利地用于制备尼龙6嵌段共聚物，并且特别适用于反应注射成型尼龙6。
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5.发明授权
公开(公告)号：US4582879A
公开(公告)日：1986-04-15
申请号：US592081
申请日：1984-03-22
IPC分类号： B29C39/00 , B29C45/00 , C08G18/00 , C08G18/08 , C08G69/00 , C08G69/18 , C08L75/00 , C08L75/04 , C08L77/00 , C08L77/02
CPC分类号： C08L77/00 , C08G18/00 , C08L75/00 , C08G2120/00 , Y10S525/903
摘要： A reaction injection molding process is disclosed comprising:introducing a mixture of substantially stable reactant streams into a mold, said mixture, in the aggregate, containing polyamide polymer forming compounds and polyurethane polymer forming compounds, said polyamide polymer forming compounds including lactam, an anionic polymerization catalyst and a polymerization activator, said polyurethane polymer forming compounds including a polyol, a polyisocyanate, a chain extender if desired, and a polyurethane polymerization catalyst, said polyamide polymer forming compounds and said polyurethane forming compounds reacting to respectively form polyamide and polyurethane polymers in said mold to thereby yielding a reaction injection molded product composed of said polymers; andrecovering said product from said mold.
摘要翻译： 公开了一种反应注射成型方法，包括：将基本上稳定的反应物流的混合物引入模具中，所述混合物在聚集体中，含有聚酰胺聚合物形成化合物和形成聚氨酯聚合物的化合物，所述聚酰胺聚合物形成化合物包括内酰胺，阴离子聚合 催化剂和聚合活化剂，所述聚氨酯聚合物形成化合物，包括多元醇，多异氰酸酯，扩链剂，如果需要，和聚氨酯聚合催化剂，所述聚酰胺聚合物形成化合物和所述聚氨酯形成化合物在所述聚合反应中分别形成聚酰胺和聚氨酯聚合物 从而产生由所述聚合物组成的反应注塑产品; 并从所述模具中回收所述产品。
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6.发明授权Process for preparing a polymer alloy, molded product, and reaction injection molded products 失效制备聚合物合金，模制产品和反应注塑产品的方法
公开(公告)号：US4742128A
公开(公告)日：1988-05-03
申请号：US787139
申请日：1985-10-15
CPC分类号： C08L75/00 , C08G18/10 , C08G18/2855 , C08L77/02 , C08G2105/02 , C08G2120/00 , C08G2270/00 , Y10S525/903
摘要： The present invention provides a molded product composed of a polymer alloy of a polyamide polymer and at least one polyurethane polymer, polyurea polymer, and/or polyisocyanurate polymer. The polymer alloy is an interpenetrated network of different polymers, a semi-interpenetrating network of different polymers, or a polyblend of different polymers.Reactant streams containing the compounds for forming the polymers of the polymer alloy are admixed to form a reaction mixture. The liquid reaction mixture is preferably a substantially homogeneous mixture of the reactant compounds. Each reactant stream thus contains only a portion of the components required to obtain the polymer alloy product. The resulting mixture is then rapidly introduced into a mold wherein chemical reaction takes place and the polymer alloy forms. Preferably, the mold is heated. The solid polymer alloy product is then recovered from the mold.
摘要翻译： 本发明提供了由聚酰胺聚合物和至少一种聚氨酯聚合物，聚脲聚合物和/或聚异氰脲酸酯聚合物的聚合物合金构成的模塑产品。 聚合物合金是不同聚合物的互穿网络，不同聚合物的半互穿网络，或不同聚合物的聚合物。 将含有形成聚合物合金的聚合物的化合物的反应物流混合以形成反应混合物。 液体反应混合物优选为反应物化合物的基本上均匀的混合物。 因此，每个反应物流仅含有获得聚合物合金产品所需的部分组分。 然后将所得混合物快速引入模具，其中发生化学反应并形成聚合物合金。 优选地，模具被加热。 然后从模具中回收固体聚合物合金产品。
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公开(公告)号：US4752626A
公开(公告)日：1988-06-21
申请号：US90008
申请日：1987-08-27
CPC分类号： B29C73/02 , C08G18/28 , C08G18/4063 , C08G18/698 , C08G18/70 , B29K2075/00 , B29K2105/045 , C08G2101/0008 , C08G2101/005 , C08G2101/0058
摘要： This invention generally relates to a high resilience urethane foam (HR foam) having low compression set at a wide range of isocyanate index for use in small void filling in integrated foam parts.The small voids formed in the molding process of integrated foam parts can be filled without penetration of foaming liquids into existing foam cells. In addition, resulting foams have very low compression set values at a wide range of isocyanate index.The foaming system of the present invention is composed of two components, i.e., thixotropic polyisocyanate component and thixotropic polyol component. Their thixotropicity is obtained by adding benzal sorbitol into respective components. The polyisocyanate is selected from organic polyisocyanates and the polyol component is prepared by mixing a polyol blend composed of a polyolefinic polyol and a polyoxyalkylene polyol in a weight ratio between 95/5 to 50/50, a blowing agent, a surfactant and a catalyst.
摘要翻译： 本发明一般涉及在广泛的异氰酸酯指数范围内具有低压缩永久变形的高回弹性聚氨酯泡沫（HR泡沫），用于集成泡沫部件的小空隙填充。 在一体化泡沫部件的成型过程中形成的小空隙可以填充而不会将泡沫液渗透到现有的泡沫单元中。 此外，所得泡沫在异氰酸酯指数的宽范围内具有非常低的压缩永久变形值。 本发明的发泡体系由触变性多异氰酸酯成分和触变性多元醇成分两部分组成。 通过将苯甲酸山梨糖醇加入到相应的组分中来获得它们的触变性。 多异氰酸酯选自有机多异氰酸酯，多元醇组分通过以95/5至50/50的重量比混合由聚烯烃多元醇和聚氧化烯多元醇组成的多元醇共混物，发泡剂，表面活性剂和催化剂来制备。
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8.发明授权Halogen-free blowing agents that include cycloaliphatic hydrocarbons and are suitable for isocyanate-based polymeric foams 失效无卤素的发泡剂，其包括脂环族烃并且适用于异氰酸酯基聚合物泡沫
公开(公告)号：US5336696A
公开(公告)日：1994-08-09
申请号：US165362
申请日：1993-12-10
申请人： Kaneyoshi Ashida
发明人： Kaneyoshi Ashida
CPC分类号： C08J9/149 , C08J2203/12 , C08J2203/14 , C08J2375/04
摘要： A halogen-free blowing agent is used to produce isocyanate-based polymeric foams. The blowing agent is an organic liquid which is free from halogens and contains a positive binary azeotrope having a minimum boiling temperature in the range of about 15.degree. C. to about 80.degree. C. at normal atmospheric pressure. Particularly preferred is a binary azeotrope of an alicyclic hydrocarbon such as cyclopentane or cyclohexane and methyl formate.The halogen-free blowing agents contemplated herein provide the following advantages: no ozone depletion potential, no global warming potential, direct replacement in foam formulations for trichloromonofluoromethane (CFC-11), relatively higher blowing action, relatively lower foam density, relatively lower thermal conductivity, better compatibility, and relatively lower materials cost.
摘要翻译： 使用无卤发泡剂来生产基于异氰酸酯的聚合物泡沫。 发泡剂是不含卤素的有机液体，并且含有在正常大气压下沸点温度在约15℃至约80℃范围内的正二元共沸物。 特别优选的是脂环族烃例如环戊烷或环己烷和甲酸甲酯的二元共沸物。 本文考虑的无卤发泡剂提供以下优点：没有臭氧消耗潜力，没有全球变暖潜力，用于三氯一氟甲烷（CFC-11）的泡沫制剂中的直接替代，相对较高的吹塑作用，相对较低的泡沫密度，相对较低的热导率 更好的兼容性，相对较低的材料成本。
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9.发明授权Open cell rigid isocyanurate foams and method for producing the same and vacuum heat insulating layer by use of the same 失效开孔单元刚性异氰脲酸酯泡沫及其制造方法及使用该真空绝热层的方法
公开(公告)号：US5260344A
公开(公告)日：1993-11-09
申请号：US850816
申请日：1992-03-13
申请人： Kaneyoshi Ashida , Josho Kashiwame
发明人： Kaneyoshi Ashida , Josho Kashiwame
IPC分类号： C08G18/08 , C08G18/00 , C08G18/09 , C08G18/30 , C08G18/32 , C08G101/00 , C08J9/14 , C08G18/42 , C08G18/48
CPC分类号： C08J9/149 , C08G18/092 , C08G2101/0025 , C08G2101/005 , C08G2101/0058 , C08J2375/04 , Y10S521/902
摘要： Rigid isocyanurate foams having a substantially open cell structure are prepared by foaming a mixture of an organic polyisocyanate and a polyol having a NCO/OH equivalent ratio of 3.5 to 13.
摘要翻译： 通过使有机多异氰酸酯和NCO / OH当量比为3.5〜13的多元醇的混合物发泡来制备具有基本上开孔结构的刚性异氰脲酸酯泡沫体。
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公开(公告)号：US4514525A
公开(公告)日：1985-04-30
申请号：US665527
申请日：1976-03-10
申请人： Kaneyoshi Ashida , Masaaki Ohtani , Shoichi Ohkubo
发明人： Kaneyoshi Ashida , Masaaki Ohtani , Shoichi Ohkubo
CPC分类号： C08G18/022 , C08G18/10 , C08J9/0061 , C08J2379/04 , C08J2443/00 , C08J2483/00 , Y10S521/902
摘要： In a process for preparing a smoke-retardant polyisocyanurate foam by reacting an organic polyisocyanate in the presence of a blowing agent and an isocyanate-trimerization catalyst, the improvement comprising conducting the reaction by adding 0.5 to 6 wt. % as Si to the total components of the foam of an organosilicone surfactant having a Si content of 4-22%, and selected from an organopolysiloxane-poly-oxyalkylene copolymer, polyvinylsilane having polyoxyalkylene side chain or modified products thereof wherein the mole % of the ethylene oxide units of the polyoxyalkylene moiety of the organosilicone surfactant is greater than 40 mole % based on the total number of ethylene oxide and propylene oxide units in said polyoxyalkylene moiety.
摘要翻译： 在有机多异氰酸酯在发泡剂和异氰酸酯 - 三聚催化剂存在下反应制备阻燃聚异氰脲酸酯泡沫的方法，其改进包括通过加入0.5至6wt。 Si为Si含量为4〜22％的有机硅氧烷表面活性剂的总成分的Si，选自有机聚硅氧烷 - 聚 - 氧化烯共聚物，具有聚氧化烯侧链的聚乙烯基硅烷或其改性产物，其中摩尔％ 基于所述聚氧化烯部分中的环氧乙烷和环氧丙烷单元的总数，有机硅氧烷表面活性剂的聚氧化烯部分的环氧乙烷单元大于40摩尔％。
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