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1.发明申请PROCESS FOR THE PREPARATION OF HIGH IMPACT VINYLAROMATIC (CO)POLYMERS GRAFTED ON AN ELASTOMER 有权制备在IMPASTOMER上制备的高度影响的乙烯（CO）聚合物的方法公开(公告)号：US20090281246A1
公开(公告)日：2009-11-12
申请号：US11720677
申请日：2005-12-06
申请人： Leonardo Chiezzi , Luca Monti , Aldo Longo
发明人： Leonardo Chiezzi , Luca Monti , Aldo Longo
IPC分类号： C08F279/02 , C08F8/00
CPC分类号： C08F255/06 , C08F255/02 , C08F255/04 , C08F279/02 , C08F212/08 , C08F212/06
摘要： A process for the preparation of vinylaromatic (co)polymers grafted on an elastomer comprising a rigid matrix consisting of vinylaromatic polymers or copolymers and of an elastomeric phase dispersed in the matrix in form of particles with a strictly bimodal distribution which comprises the functionalization of a first elastomeric fraction by means of a catalytic system containing a stable free radical initiator and subsequently the polymerization of the thus obtained mixture also in presence of a second non functionalized elastomeric fraction.
摘要翻译： 一种制备接枝在弹性体上的乙烯基芳族（共）聚合物的方法，包括由乙烯基芳族聚合物或共聚物组成的刚性基质和分散在基质中的具有严格双峰分布的颗粒形式的弹性体相，其包括第一 通过含有稳定的自由基引发剂的催化体系，随后在第二非官能化弹性体级分的存在下聚合得到的混合物。
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2.发明授权Process for the preparation of high impact vinylaromatic (co)polymers grafted on an elastomer 有权用于制备接枝在弹性体上的高冲击乙烯基芳族（共）聚合物的方法公开(公告)号：US08349961B2
公开(公告)日：2013-01-08
申请号：US11720677
申请日：2005-12-06
申请人： Leonardo Chiezzi , Luca Monti , Aldo Longo
发明人： Leonardo Chiezzi , Luca Monti , Aldo Longo
IPC分类号： C08F279/02
CPC分类号： C08F255/06 , C08F255/02 , C08F255/04 , C08F279/02 , C08F212/08 , C08F212/06
摘要： A process for the preparation of vinylaromatic (co)polymers grafted on an elastomer comprising a rigid matrix consisting of vinylaromatic polymers or copolymers and of an elastomeric phase dispersed in the matrix in form of particles with a strictly bimodal distribution which comprises the functionalization of a first elastomeric fraction by means of a catalytic system containing a stable free radical initiator and subsequently the polymerization of the thus obtained mixture also in presence of a second non functionalized elastomeric fraction.
摘要翻译： 一种制备接枝在弹性体上的乙烯基芳族（共）聚合物的方法，包括由乙烯基芳族聚合物或共聚物组成的刚性基质和分散在基质中的具有严格双峰分布的颗粒形式的弹性体相，其包括第一 通过含有稳定的自由基引发剂的催化体系，随后在第二非官能化弹性体级分的存在下聚合得到的混合物。
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3.发明授权Process for the preparation of vinylaromatic (co)polymers grafted on an elastomer in a controlled way 有权以受控的方式制备接枝在弹性体上的乙烯基芳族（共）聚合物的方法公开(公告)号：US08039557B2
公开(公告)日：2011-10-18
申请号：US11578412
申请日：2005-03-07
申请人： Aldo Longo , Leonardo Chiezzi
发明人： Aldo Longo , Leonardo Chiezzi
IPC分类号： C08F279/02
CPC分类号： C08F279/02 , C08F285/00 , Y10S525/902
摘要： A process for the preparation of vinylaromatic (co)polymers grafted on an elastomer in a controlled way, comprising the dissolving of an elastomer, such as polibutadiene, in a mixture consisting of a monomer and of a solvent in the presence of a polymerization catalytic system, which comprises an initiator of free radicals and a stable initiator of free radicals. The mixture obtained in this way is heated to a temperature of about 100° C. to functionalize the rubber, then more monomer is added and the temperature is raised to start the polymerization reaction.
摘要翻译： 一种制备以受控方式接枝在弹性体上的乙烯基芳族（共）聚合物的方法，包括在聚合催化体系存在下，将由弹性体如聚乙二醇混合的混合物溶解在由单体和溶剂组成的混合物中 ，其包含自由基的引发剂和稳定的自由基引发剂。 将以这种方式获得的混合物加热至约100℃的温度以使橡胶官能化，然后加入更多的单体并升高温度以开始聚合反应。
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4.发明申请SEMI-CONTINUOUS INTEGRATED PROCESS FOR THE PRODUCTION OF HIGH IMPACT VINYL AROMATIC (CO)POLYMERS BY ANIONIC/RADICAL POLYMERIZATION IN SEQUENCE 有权用于通过序列中的阴离子/自由基聚合生产高度影响的乙烯芳族（CO）聚合物的半连续一体化方法公开(公告)号：US20100305264A1
公开(公告)日：2010-12-02
申请号：US12747749
申请日：2008-11-28
IPC分类号： C08L55/00
CPC分类号： C08F279/02 , C08C19/44 , C08F6/06 , Y02P20/125 , C08L51/04 , C08L25/10
摘要： Butadiene is anionically polymerized (or block copolimerized with styrene) in a low-boiling non-polar solvent in presence of rganolithiura compounds. At the end of the polymerization, the non-polar solvent is switched with styrene and the new solution is stored in tanks in relation to the type of polybutadiene (or its block copolymer with styrene) obtained. The polybutadiene solution (and/or its block copolymer with styrene) with the desired set of properties is then fed to a production plant of high impact vinyl aromatic (co) polymers.
摘要翻译： 丁二烯在低沸点非极性溶剂中在牛磺胆酸化合物的存在下进行阴离子聚合（或与苯乙烯嵌段共聚合）。 在聚合结束时，非极性溶剂用苯乙烯切换，新溶液相对于获得的聚丁二烯（或其与苯乙烯的嵌段共聚物）的类型储存在罐中。 然后将具有所需性质的聚丁二烯溶液（和/或其与苯乙烯的嵌段共聚物）加入到高冲击乙烯基芳族（共）聚合物的生产设备中。
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5.发明授权Process for the synthesis of functionalized poly (1,3-alkadienes) and use thereof in the preparation of high impact vinyl aromatic polymers 有权官能化聚（1,3-链二烯）的合成方法及其在制备高冲击乙烯基芳族聚合物中的应用公开(公告)号：US09029479B2
公开(公告)日：2015-05-12
申请号：US13059533
申请日：2009-08-07
IPC分类号： C08F279/02 , C08F2/38 , C08C19/44 , C08F2/00 , C08F291/00 , C08F293/00 , C08L15/00 , C08L51/04 , C08F212/08 , C08F212/12
CPC分类号： C08C19/44 , C08F2/00 , C08F212/08 , C08F212/12 , C08F279/02 , C08F291/00 , C08F293/005 , C08L15/00 , C08L51/04 , C08L2666/02
摘要： Process for the preparation of vinyl aromatic (co) polymers grafted on an elastomer in a controlled manner, comprising: dissolving an elastomer functionalized with bromoalkanes and nitroxy radicals, soluble in non-polar solvents, in a liquid phase consisting of a mixture of vinyl aromatic monomer(s)/polymerization solvent; feeding at least one radical initiator to the mixture, containing the functionalized elastomer in solution, and polymerizing the mixture thus obtained at a temperature higher than or equal to 1200 C; recovering the vinyl aromatic (co) polymer obtained after devolatization; and recycling the solvent/monomer(s) mixture, coming from the devolatization, to step (a).
摘要翻译： 制备以可控方式接枝在弹性体上的乙烯基芳族（共）聚合物的方法，包括：将可溶于非极性溶剂的溴烷烃和硝基氧基官能化的弹性体溶解在由乙烯基芳族化合物 单体/聚合溶剂; 在混合物中加入至少一种自由基引发剂，在溶液中含有官能化弹性体，并在高于或等于1200℃的温度下聚合所得混合物; 回收脱挥发后获得的乙烯基芳族（共）聚合物; 并将来自脱挥发分的溶剂/单体混合物再循环到步骤（a）。
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6.发明申请RUBBER-REINFORCED VINYL AROMATIC (CO)POLYMER, HAVING AN OPTIMUM BALANCE OF PHYSICO-MECHANICAL PROPERTIES AND A HIGH GLOSS 审中-公开橡胶增强的VINYL AROMATIC（CO）聚合物，具有物理机械性能和高GLOSS的最佳平衡公开(公告)号：US20120289660A1
公开(公告)日：2012-11-15
申请号：US13139823
申请日：2009-12-10
申请人： Alessandro Casalini , Leonardo Chiezzi , Anna Grazia Rossi , Leonardo Castellani , Giulia Castellani , Luca Soddu
发明人： Alessandro Casalini , Leonardo Chiezzi , Anna Grazia Rossi , Leonardo Castellani , Giulia Castellani , Luca Soddu
IPC分类号： C08L9/00
CPC分类号： C08F279/02 , C08F279/04 , C08L51/04 , C08L55/02 , C08L2666/24 , C08L2666/04 , C08L2666/02
摘要： Vinyl aromatic (co) polymer reinforced with a rubber selected from a linear diene rubber (i) with a solution viscosity lower than 70 cPs; a partially radial diene rubber (ii), with a solution viscosity lower than 70 cPs; a three-chain diene rubber (iii) with a solution viscosity lower than 70 cPs; a blend of linear diene rubbers (i) and radial diene rubbers (iv) in a maximum ratio between them (i)/(iv) of between 99.5/0.5 and 85/15.
摘要翻译： 用选自溶液粘度低于70cPs的线性二烯橡胶（i）的橡胶增强的乙烯基芳族（共）聚合物; 部分径向二烯橡胶（ii），溶液粘度低于70cPs; 溶液粘度低于70cPs的三链二烯橡胶（iii）; 线性二烯橡胶（i）和径向二烯橡胶（iv）的混合物之间的最大比例（i）/（iv）为99.5 / 0.5至85/15。
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7.发明授权Semi-continuous integrated process for the production of high impact vinyl aromatic (co)polymers by anionic/radical polymerization in sequence 有权通过阴离子/自由基聚合顺序生产高冲击乙烯基芳族（共）聚合物的半连续一体化方法公开(公告)号：US08404781B2
公开(公告)日：2013-03-26
申请号：US12747749
申请日：2008-11-28
IPC分类号： C08L55/00
CPC分类号： C08F279/02 , C08C19/44 , C08F6/06 , Y02P20/125 , C08L51/04 , C08L25/10
摘要： Butadiene is anionically polymerized (or block copolimerized with styrene) in a low-boiling non-polar solvent in presence of rganolithiura compounds. At the end of the polymerization, the non-polar solvent is switched with styrene and the new solution is stored in tanks in relation to the type of polybutadiene (or its block copolymer with styrene) obtained. The polybutadiene solution (and/or its block copolymer with styrene) with the desired set of properties is then fed to a production plant of high impact vinyl aromatic (co)polymers.
摘要翻译： 丁二烯在低沸点非极性溶剂中在牛磺胆酸化合物的存在下进行阴离子聚合（或与苯乙烯嵌段共聚合）。 在聚合结束时，非极性溶剂用苯乙烯切换，新溶液相对于获得的聚丁二烯（或其与苯乙烯的嵌段共聚物）的类型储存在罐中。 然后将具有所需性质的聚丁二烯溶液（和/或其与苯乙烯的嵌段共聚物）加入到高冲击乙烯基芳族（共）聚合物的生产设备中。
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8.发明申请PROCESS FOR THE SYNTHESIS OF FUNCTIONALIZED POLY (1,3- ALKADIENES) AND USE THEREOF IN THE PREPARATION OF HIGH IMPACT VINYL AROMATIC POLYMERS 有权功能性聚（1,3-烷氧基）的合成方法及其在制备高活性乙烯芳族聚合物中的应用公开(公告)号：US20110207884A1
公开(公告)日：2011-08-25
申请号：US13059533
申请日：2009-08-07
IPC分类号： C08F279/02 , C08F2/38
CPC分类号： C08C19/44 , C08F2/00 , C08F212/08 , C08F212/12 , C08F279/02 , C08F291/00 , C08F293/005 , C08L15/00 , C08L51/04 , C08L2666/02
摘要： Process for the preparation of vinyl aromatic (co) polymers grafted on an elastomer in a controlled manner, comprising: dissolving an elastomer functionalized with bromoalkanes and nitroxy radicals, soluble in non-polar solvents, in a liquid phase consisting of a mixture of vinyl aromatic monomer (s)/polymerization solvent; feeding at least one radical initiator to the mixture, containing the functionalized elastomer in solution, and polymerizing the mixture thus obtained at a temperature higher than or equal to 1200C; recovering the vinyl aromatic (co) polymer obtained after devolatization; and recycling the solvent/monomer (s) mixture, coming from the devolatization, to step (a).
摘要翻译： 制备以可控方式接枝在弹性体上的乙烯基芳族（共）聚合物的方法，包括：将可溶于非极性溶剂的溴烷烃和硝基氧基官能化的弹性体溶解在由乙烯基芳族化合物 单体/聚合溶剂; 将至少一种自由基引发剂加入到混合物中，在溶液中含有官能化弹性体，并在高于或等于1200℃的温度下聚合由此获得的混合物; 回收脱挥发后获得的乙烯基芳族（共）聚合物; 并将来自脱挥发分的溶剂/单体混合物再循环到步骤（a）。
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