公开(公告)号：US06911403B2

公开(公告)日：2005-06-28

申请号：US10645675

申请日：2003-08-20

申请人： Lihua Li ,  Tsutomu Tanaka ,  Tzu-Fang Huang ,  Li-Qun Xia ,  Dian Sugiarto ,  Visweswaren Sivaramakrishnan ,  Peter Wai-Man Lee ,  Mario David Silvetti

发明人： Lihua Li ,  Tsutomu Tanaka ,  Tzu-Fang Huang ,  Li-Qun Xia ,  Dian Sugiarto ,  Visweswaren Sivaramakrishnan ,  Peter Wai-Man Lee ,  Mario David Silvetti

IPC分类号： C23C16/40 ,  C23C16/509 ,  H01L21/312 ,  H01L21/316 ,  H01L21/768 ,  H01L21/31

CPC分类号： C23C16/5096 ,  C23C16/401 ,  H01L21/02126 ,  H01L21/02216 ,  H01L21/02274 ,  H01L21/3122 ,  H01L21/31612 ,  H01L21/31633 ,  H01L21/76801

摘要： A method for depositing an organosilicate layer on a substrate includes varying one or more processing conditions during a process sequence for depositing an organosilicate layer from a gas mixture comprising an organosilicon compound in the presence of RF power in a processing chamber. In one aspect, the distance between the substrate and a gas distribution manifold in the processing chamber is varied during processing. Preferably, the method of depositing an organosilicate layer minimizes plasma-induced damage to the substrate.

摘要翻译： 用于在衬底上沉积有机硅酸盐层的方法包括在用于在处理室中的RF功率存在下从包含有机硅化合物的气体混合物沉积有机硅酸盐层的工艺顺序期间改变一个或多个处理条件。 在一个方面，在处理过程中，衬底与处理室中的气体分配歧管之间的距离是变化的。 优选地，沉积有机硅酸盐层的方法使等离子体对衬底的损伤最小化。

公开(公告)号：US20050042885A1

公开(公告)日：2005-02-24

申请号：US10645675

申请日：2003-08-20

申请人： Lihua Li ,  Tsutomu Tanaka ,  Tzu-Fang Huang ,  Li-Qun Xia ,  Dian Sugiarto ,  Visweswaren Sivaramakrishnan ,  Peter Lee ,  Mario Silvetti

发明人： Lihua Li ,  Tsutomu Tanaka ,  Tzu-Fang Huang ,  Li-Qun Xia ,  Dian Sugiarto ,  Visweswaren Sivaramakrishnan ,  Peter Lee ,  Mario Silvetti

IPC分类号： C23C16/40 ,  C23C16/509 ,  H01L21/312 ,  H01L21/316 ,  H01L21/768 ,  H01L21/31 ,  H01L21/469

CPC分类号： C23C16/5096 ,  C23C16/401 ,  H01L21/02126 ,  H01L21/02216 ,  H01L21/02274 ,  H01L21/3122 ,  H01L21/31612 ,  H01L21/31633 ,  H01L21/76801

摘要： A method for depositing an organosilicate layer on a substrate includes varying one or more processing conditions during a process sequence for depositing an organosilicate layer from a gas mixture comprising an organosilicon compound in the presence of RF power in a processing chamber. In one aspect, the distance between the substrate and a gas distribution manifold in the processing chamber is varied during processing. Preferably, the method of depositing an organosilicate layer minimizes plasma-induced damage to the substrate.

公开(公告)号：US07459404B2

公开(公告)日：2008-12-02

申请号：US11405852

申请日：2006-04-18

申请人： Lihua Li ,  Tzu-Fang Huang ,  Jerry Sugiarto, legal representative ,  Li-Qun Xia ,  Peter Wai-Man Lee ,  Hichem M'Saad ,  Zhenjiang Cui ,  Sohyun Park

发明人： Dian Sugiarto

IPC分类号： H01L21/31 ,  H01L21/469

CPC分类号： H01L21/31633 ,  C23C16/02 ,  C23C16/325 ,  C23C16/401 ,  H01L21/02126 ,  H01L21/02274 ,  H01L21/02304 ,  H01L21/76801 ,  H01L21/7681 ,  H01L21/76826 ,  H01L21/76832

摘要： Methods are provided for processing a substrate for depositing an adhesion layer having a low dielectric constant between two low k dielectric layers. In one aspect, the invention provides a method for processing a substrate including introducing an organosilicon compound and an oxidizing gas at a first ratio of organosilicon compound to oxidizing gas into the processing chamber, generating a plasma of the oxidizing gas and the organosilicon compound to form an initiation layer on a barrier layer comprising at least silicon and carbon, introducing the organosilicon compound and the oxidizing gas at a second ratio of organosilicon compound to oxidizing gas greater than the first ratio into the processing chamber, and depositing a first dielectric layer adjacent the dielectric initiation layer.

摘要翻译： 提供了用于处理用于沉积在两个低k电介质层之间具有低介电常数的粘合层的衬底的方法。 一方面，本发明提供一种处理基板的方法，包括以有机硅化合物的第一比例将有机硅化合物和氧化气体与氧化气体导入处理室，产生氧化气体的等离子体和有机硅化合物，形成 在至少包含硅和碳的阻挡层上的起始层，以有机硅化合物的第二比例将有机硅化合物和氧化气体与大于第一比例的氧化气体引入到处理室中，以及沉积与第 电介质起始层。

公开(公告)号：US07745328B2

公开(公告)日：2010-06-29

申请号：US12255644

申请日：2008-10-21

申请人： Kang Sub Yim ,  Melissa M. Tam ,  Dian Sugiarto ,  Chi-I Lang ,  Peter Wai-Man Lee ,  Li-Qun Xia

发明人： Kang Sub Yim ,  Melissa M. Tam ,  Dian Sugiarto ,  Chi-I Lang ,  Peter Wai-Man Lee ,  Li-Qun Xia

IPC分类号： H01L21/4763

CPC分类号： H01L21/76834 ,  C23C16/30 ,  C23C16/325 ,  C23C16/401 ,  C23C16/505 ,  C23C16/56 ,  H01L21/02126 ,  H01L21/02167 ,  H01L21/022 ,  H01L21/02211 ,  H01L21/02274 ,  H01L21/31116 ,  H01L21/31138 ,  H01L21/31144 ,  H01L21/312 ,  H01L21/3122 ,  H01L21/3127 ,  H01L21/3148 ,  H01L21/31633 ,  H01L21/3185 ,  H01L21/76807 ,  H01L21/7681 ,  H01L21/76825 ,  H01L21/76826 ,  H01L21/76828 ,  H01L21/76829 ,  H01L21/76832

摘要： Methods are provided for depositing a silicon carbide layer having significantly reduced current leakage. The silicon carbide layer may be a barrier layer or part of a barrier bilayer that also includes a barrier layer. Methods for depositing oxygen-doped silicon carbide barrier layers are also provided. The silicon carbide layer may be deposited by reacting a gas mixture comprising an organosilicon compound, an aliphatic hydrocarbon comprising a carbon-carbon double bond or a carbon-carbon triple bond, and optionally, helium in a plasma. Alternatively, the silicon carbide layer may be deposited by reacting a gas mixture comprising hydrogen or argon and an organosilicon compound in a plasma.

摘要翻译： 提供了用于沉积具有显着降低的电流泄漏的碳化硅层的方法。 碳化硅层可以是还包括阻挡层的阻挡层或阻挡层双层的一部分。 还提供了沉积氧掺杂的碳化硅阻挡层的方法。 可以通过使包含有机硅化合物，包含碳 - 碳双键或碳 - 碳三键的脂族烃和任选地在等离子体中的氦气的气体混合物反应来沉积碳化硅层。 或者，可以通过在等离子体中使包含氢或氩的气体混合物和有机硅化合物反应来沉积碳化硅层。

公开(公告)号：US07157384B2

公开(公告)日：2007-01-02

申请号：US11021319

申请日：2004-12-22

申请人： Kang Sub Yim ,  Melissa M. Tam ,  Dian Sugiarto ,  Chi-I Lang ,  Peter Wai-Man Lee ,  Li-Qun Xia

发明人： Kang Sub Yim ,  Melissa M. Tam ,  Dian Sugiarto ,  Chi-I Lang ,  Peter Wai-Man Lee ,  Li-Qun Xia

IPC分类号： H01L21/31 ,  H01L21/469

CPC分类号： H01L21/76834 ,  C23C16/30 ,  C23C16/325 ,  C23C16/401 ,  C23C16/505 ,  C23C16/56 ,  H01L21/02126 ,  H01L21/02167 ,  H01L21/022 ,  H01L21/02211 ,  H01L21/02274 ,  H01L21/31116 ,  H01L21/31138 ,  H01L21/31144 ,  H01L21/312 ,  H01L21/3122 ,  H01L21/3127 ,  H01L21/3148 ,  H01L21/31633 ,  H01L21/3185 ,  H01L21/76807 ,  H01L21/7681 ,  H01L21/76825 ,  H01L21/76826 ,  H01L21/76828 ,  H01L21/76829 ,  H01L21/76832

摘要： Methods are provided for depositing a silicon carbide layer having significantly reduced current leakage. The silicon carbide layer may be a barrier layer or part of a barrier bilayer that also includes a barrier layer. Methods for depositing oxygen-doped silicon carbide barrier layers are also provided. The silicon carbide layer may be deposited by reacting a gas mixture comprising an organosilicon compound, an aliphatic hydrocarbon comprising a carbon-carbon double bond or a carbon-carbon triple bond, and optionally, helium in a plasma. Alternatively, the silicon carbide layer may be deposited by reacting a gas mixture comprising hydrogen or argon and an organosilicon compound in a plasma.

摘要翻译： 提供了用于沉积具有显着降低的电流泄漏的碳化硅层的方法。 碳化硅层可以是还包括阻挡层的阻挡层或阻挡层双层的一部分。 还提供了沉积氧掺杂的碳化硅阻挡层的方法。 可以通过使包含有机硅化合物，包含碳 - 碳双键或碳 - 碳三键的脂族烃和任选地在等离子体中的氦气的气体混合物反应来沉积碳化硅层。 或者，可以通过在等离子体中使包含氢或氩的气体混合物和有机硅化合物反应来沉积碳化硅层。

公开(公告)号：US07465659B2

公开(公告)日：2008-12-16

申请号：US11426141

申请日：2006-06-23

申请人： Kang Sub Yim ,  Melissa M. Tam ,  Dian Sugiarto ,  Chi-I Lang ,  Peter Wai-Man Lee ,  Li-Qun Xia

发明人： Kang Sub Yim ,  Melissa M. Tam ,  Dian Sugiarto ,  Chi-I Lang ,  Peter Wai-Man Lee ,  Li-Qun Xia

IPC分类号： H01L21/4763

CPC分类号： H01L21/76834 ,  C23C16/30 ,  C23C16/325 ,  C23C16/401 ,  C23C16/505 ,  C23C16/56 ,  H01L21/02126 ,  H01L21/02167 ,  H01L21/022 ,  H01L21/02211 ,  H01L21/02274 ,  H01L21/31116 ,  H01L21/31138 ,  H01L21/31144 ,  H01L21/312 ,  H01L21/3122 ,  H01L21/3127 ,  H01L21/3148 ,  H01L21/31633 ,  H01L21/3185 ,  H01L21/76807 ,  H01L21/7681 ,  H01L21/76825 ,  H01L21/76826 ,  H01L21/76828 ,  H01L21/76829 ,  H01L21/76832

摘要： Methods are provided for depositing a silicon carbide layer having significantly reduced current leakage. The silicon carbide layer may be a barrier layer or part of a barrier bilayer that also includes a barrier layer. Methods for depositing oxygen-doped silicon carbide barrier layers are also provided. The silicon carbide layer may be deposited by reacting a gas mixture comprising an organosilicon compound, an aliphatic hydrocarbon comprising a carbon-carbon double bond or a carbon-carbon triple bond, and optionally, helium in a plasma. Alternatively, the silicon carbide layer may be deposited by reacting a gas mixture comprising hydrogen or argon and an organosilicon compound in a plasma.

摘要翻译： 提供了用于沉积具有显着降低的电流泄漏的碳化硅层的方法。 碳化硅层可以是还包括阻挡层的阻挡层或阻挡层双层的一部分。 还提供了沉积氧掺杂的碳化硅阻挡层的方法。 可以通过使包含有机硅化合物，包含碳 - 碳双键或碳 - 碳三键的脂族烃和任选地在等离子体中的氦气的气体混合物反应来沉积碳化硅层。 或者，可以通过在等离子体中使包含氢或氩的气体混合物和有机硅化合物反应来沉积碳化硅层。

公开(公告)号：US06838393B2

公开(公告)日：2005-01-04

申请号：US10247404

申请日：2002-09-19

申请人： Kang Sub Yim ,  Melissa M. Tam ,  Dian Sugiarto ,  Chi-I Lang ,  Peter Wai-Man Lee ,  Li-Qun Xia

发明人： Kang Sub Yim ,  Melissa M. Tam ,  Dian Sugiarto ,  Chi-I Lang ,  Peter Wai-Man Lee ,  Li-Qun Xia

IPC分类号： C23C16/30 ,  C23C16/40 ,  C23C16/56 ,  H01L21/311 ,  H01L21/312 ,  H01L21/316 ,  H01L21/768 ,  H01L21/469 ,  H01L21/31

CPC分类号： H01L21/76834 ,  C23C16/30 ,  C23C16/325 ,  C23C16/401 ,  C23C16/505 ,  C23C16/56 ,  H01L21/02126 ,  H01L21/02167 ,  H01L21/022 ,  H01L21/02211 ,  H01L21/02274 ,  H01L21/31116 ,  H01L21/31138 ,  H01L21/31144 ,  H01L21/312 ,  H01L21/3122 ,  H01L21/3127 ,  H01L21/3148 ,  H01L21/31633 ,  H01L21/3185 ,  H01L21/76807 ,  H01L21/7681 ,  H01L21/76825 ,  H01L21/76826 ,  H01L21/76828 ,  H01L21/76829 ,  H01L21/76832

摘要： Methods are provided for depositing a silicon carbide layer having significantly reduced current leakage. The silicon carbide layer may be a barrier layer or part of a barrier bilayer that also includes a barrier layer. Methods for depositing oxygen-doped silicon carbide barrier layers are also provided. The silicon carbide layer may be deposited by reacting a gas mixture comprising an organosilicon compound, an aliphatic hydrocarbon comprising a carbon-carbon double bond or a carbon-carbon triple bond, and optionally, helium in a plasma. Alternatively, the silicon carbide layer may be deposited by reacting a gas mixture comprising hydrogen or argon and an organosilicon compound in a plasma.

摘要翻译： 提供了用于沉积具有显着降低的电流泄漏的碳化硅层的方法。 碳化硅层可以是还包括阻挡层的阻挡层或阻挡层双层的一部分。 还提供了沉积氧掺杂的碳化硅阻挡层的方法。 可以通过使包含有机硅化合物，包含碳 - 碳双键或碳 - 碳三键的脂族烃和任选地在等离子体中的氦气的气体混合物反应来沉积碳化硅层。 或者，可以通过在等离子体中使包含氢或氩的气体混合物和有机硅化合物反应来沉积碳化硅层。

公开(公告)号：US20090053902A1

公开(公告)日：2009-02-26

申请号：US12255644

申请日：2008-10-21

申请人： Kang Sub Yim ,  Melissa M. Tam ,  Dian Sugiarto ,  Chi-I Lang ,  Peter Wai-Man Lee ,  Li-Qun Xia

发明人： Kang Sub Yim ,  Melissa M. Tam ,  Dian Sugiarto ,  Chi-I Lang ,  Peter Wai-Man Lee ,  Li-Qun Xia

IPC分类号： H01L21/31

CPC分类号： H01L21/76834 ,  C23C16/30 ,  C23C16/325 ,  C23C16/401 ,  C23C16/505 ,  C23C16/56 ,  H01L21/02126 ,  H01L21/02167 ,  H01L21/022 ,  H01L21/02211 ,  H01L21/02274 ,  H01L21/31116 ,  H01L21/31138 ,  H01L21/31144 ,  H01L21/312 ,  H01L21/3122 ,  H01L21/3127 ,  H01L21/3148 ,  H01L21/31633 ,  H01L21/3185 ,  H01L21/76807 ,  H01L21/7681 ,  H01L21/76825 ,  H01L21/76826 ,  H01L21/76828 ,  H01L21/76829 ,  H01L21/76832

摘要： Methods are provided for depositing a silicon carbide layer having significantly reduced current leakage. The silicon carbide layer may be a barrier layer or part of a barrier bilayer that also includes a barrier layer. Methods for depositing oxygen-doped silicon carbide barrier layers are also provided. The silicon carbide layer may be deposited by reacting a gas mixture comprising an organosilicon compound, an aliphatic hydrocarbon comprising a carbon-carbon double bond or a carbon-carbon triple bond, and optionally, helium in a plasma. Alternatively, the silicon carbide layer may be deposited by reacting a gas mixture comprising hydrogen or argon and an organosilicon compound in a plasma.

摘要翻译： 提供了用于沉积具有显着降低的电流泄漏的碳化硅层的方法。 碳化硅层可以是还包括阻挡层的阻挡层或阻挡层双层的一部分。 还提供了沉积氧掺杂的碳化硅阻挡层的方法。 可以通过使包含有机硅化合物，包含碳 - 碳双键或碳 - 碳三键的脂族烃和任选地在等离子体中的氦气的气体混合物反应来沉积碳化硅层。 或者，可以通过在等离子体中使包含氢或氩的气体混合物和有机硅化合物反应来沉积碳化硅层。

公开(公告)号：US07153787B2

公开(公告)日：2006-12-26

申请号：US11044246

申请日：2005-01-27

申请人： Seon-Mee Cho ,  Peter Wai-Man Lee ,  Chi-I Lang ,  Dian Sugiarto ,  Chen-An Chen ,  Li-Qun Xia ,  Shankar Venkataraman ,  Ellie Yieh

发明人： Seon-Mee Cho ,  Peter Wai-Man Lee ,  Chi-I Lang ,  Dian Sugiarto ,  Chen-An Chen ,  Li-Qun Xia ,  Shankar Venkataraman ,  Ellie Yieh

IPC分类号： H01L21/469

CPC分类号： H01L21/02126 ,  C23C16/30 ,  H01L21/02211 ,  H01L21/02216 ,  H01L21/02274 ,  H01L21/02304 ,  H01L21/02362 ,  H01L21/31633 ,  Y10S438/931 ,  Y10T428/31909

摘要： A low dielectric constant film having silicon-carbon bonds and dielectric constant of about 3.0 or less, preferably about 2.5 or less, is provided. The low dielectric constant film is deposited by reacting a cyclic organosilicon compound and an aliphatic organosilicon compound with an oxidizing gas while applying RF power. The carbon content of the deposited film is between about 10 and about 30 atomic percent excluding hydrogen atoms, and is preferably between about 10 and about 20 atomic percent excluding hydrogen atoms.

摘要翻译： 提供了具有约3.0或更小，优选约2.5或更小的硅 - 碳键和介电常数的低介电常数膜。 通过使环状有机硅化合物和脂族有机硅化合物与氧化气体反应同时施加RF功率来沉积低介电常数膜。 沉积膜的碳含量除氢原子以外约为10至约30原子百分比，优选除氢原子之外约10至约20原子％。

公开(公告)号：US06486082B1

公开(公告)日：2002-11-26

申请号：US09885985

申请日：2001-06-18

申请人： Seon-Mee Cho ,  Peter Wai-Man Lee ,  Chi-I Lang ,  Dian Sugiarto ,  Chen-An Chen ,  Li-Qun Xia ,  Shankar Venkataraman ,  Ellie Yieh

发明人： Seon-Mee Cho ,  Peter Wai-Man Lee ,  Chi-I Lang ,  Dian Sugiarto ,  Chen-An Chen ,  Li-Qun Xia ,  Shankar Venkataraman ,  Ellie Yieh

IPC分类号： H07L21477

CPC分类号： H01L21/02126 ,  C23C16/30 ,  H01L21/02211 ,  H01L21/02216 ,  H01L21/02274 ,  H01L21/02304 ,  H01L21/02362 ,  H01L21/31633 ,  Y10S438/931 ,  Y10T428/31909

摘要： A low dielectric constant film having silicon-carbon bonds and dielectric constant of about 3.0 or less, preferably about 2.5 or less, is provided. The low dielectric constant film is deposited by reacting a cyclic organosilicon compound and an aliphatic organosilicon compound with an oxidizing gas while applying RF power. The carbon content of the deposited film is between about 10 and about 30 atomic percent excluding hydrogen atoms, and is preferably between about 10 and about 20 atomic percent excluding hydrogen atoms.

摘要翻译： 提供了具有约3.0或更小，优选约2.5或更小的硅 - 碳键和介电常数的低介电常数膜。 通过使环状有机硅化合物和脂族有机硅化合物与氧化气体反应同时施加RF功率来沉积低介电常数膜。 沉积膜的碳含量除氢原子以外约为10至约30原子百分比，优选除氢原子之外约10至约20原子％。