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    Ethylene/dicyclopentadiene copolymers and functionalized derivatives thereof
    2.
    发明申请
    Ethylene/dicyclopentadiene copolymers and functionalized derivatives thereof 有权
    乙烯/二环戊二烯共聚物及其官能化衍生物

    公开(公告)号：US20080015314A1

    公开(公告)日：2008-01-17

    申请号：US11801633

    申请日：2007-05-10

    申请人： Lisa Saunders Baugh ,  Abhimanyu Onkar Patil ,  Christian Peter Mehnert ,  Kevin R. Squire ,  Kenneth A. Cook ,  Caiguo Gong ,  Enock Berluche ,  Karla Schall Colle ,  Alan J. Oshinski ,  Stephen Zushma ,  Beverly J. Poole

    发明人： Lisa Saunders Baugh ,  Abhimanyu Onkar Patil ,  Christian Peter Mehnert ,  Kevin R. Squire ,  Kenneth A. Cook ,  Caiguo Gong ,  Enock Berluche ,  Karla Schall Colle ,  Alan J. Oshinski ,  Stephen Zushma ,  Beverly J. Poole

    IPC分类号： C08L45/00

    CPC分类号： C08F210/02 ,  C08F8/04 ,  C08F8/08 ,  C08F232/00

    摘要： Disclosed is a selected type of copolymer composition comprising copolymers having units derived from ethylene and dicyclopentadiene (DCPD) co-monomers. Such copolymer compositions: a) have a DCPD-derived comonomer unit content of from about 25 mole % to about 45 mole %; b) have a Weight Average Molecular Weight, Mw, of greater than about 170,000; c) comprise amorphous material and have glass transition temperatures, Tg, of from about 8° C. to about 129° C., which also fit the equation Tg (in ° C.)≧[(mole % DCPD×3.142)−4.67]; and d) comprise no significant amount of crystalline polyethylene homopolymer or crystallizable polyethylene segments within the ethylene-dicylopentadiene copolymers. Such copolymers can be readily derivatized by hydrogention and/or epoxidation to provide polymeric materials suitable for use as engineering thermoplastics.Also disclosed are processes for preparing and optionally further derivatizing ethylene/dicyclopentadiene copolymers having the characteristics hereinbefore described. Such processes comprise: a) contacting ethylene with a polymerization mixture comprising greater than about 4.0 molar dicyclopentadiene, in the presence of a selected activated cyclopentadienyl-fluorenyl metallocene catalyst bearing a substituent, preferably a methyl substituent, at the 3-position of the cyclopentadienyl ring, under specific polymerization conditions including relatively high ethylene pressures to thereby form the desired ethylene-dicyclopentadiene copolymers within the polymerization mixture. Such copolymers are then recovered and/or further hydrogenated or functionalized.

    摘要翻译： 公开了一种选择类型的共聚物组合物，其包含具有衍生自乙烯和二环戊二烯（DCPD）共聚单体的单元的共聚物。 这种共聚物组合物：a）具有约25摩尔％至约45摩尔％的DCPD衍生的共聚单体单元含量; b）具有大于约170,000的重均分子量，M < c）包含非晶材料，并且具有约8℃至约129℃的玻璃化转变温度，其也适合方程式T（g） （℃）] = [（摩尔％DCPDx 3.142）-4.67]; 和d）在乙烯 - 二茂二烯共聚物内不含有显着量的结晶聚乙烯均聚物或可结晶的聚乙烯链段。 这样的共聚物可以通过水合和/或环氧化来容易地衍生，以提供适合用作工程热塑性塑料的聚合材料。 还公开了制备和任选地进一步衍生具有上述特征的乙烯/二环戊二烯共聚物的方法。 这样的方法包括：a）在选择的活化的环戊二烯基 - 芴基茂金属催化剂存在下，在含有大于约4.0摩尔二环戊二烯的聚合混合物的存在下，使乙烯与环戊二烯基环的3位具有取代基，优选甲基取代基接触 在包括相对较高的乙烯压力的特定聚合条件下，从而在聚合混合物内形成所需的乙烯 - 二环戊二烯共聚物。 然后回收和/或进一步氢化或官能化此类共聚物。

    Polymer compositions comprising cyclic olefin copolymers and polyolefin modifiers
    5.
    发明申请
    Polymer compositions comprising cyclic olefin copolymers and polyolefin modifiers 审中-公开
    包含环烯烃共聚物和聚烯烃改性剂的聚合物组合物

    公开(公告)号：US20080033112A1

    公开(公告)日：2008-02-07

    申请号：US11820739

    申请日：2007-06-20

    申请人： Kevin R. Squire ,  Alan J. Oshinski ,  Kevin D. Robinson ,  Christian Peter Mehnert ,  Marsha M. Arvedson ,  Beverly J. Poole ,  Abhimanyu Onkar Patil ,  Lisa Saunders Baugh ,  Karla Schall Colle

    发明人： Kevin R. Squire ,  Alan J. Oshinski ,  Kevin D. Robinson ,  Christian Peter Mehnert ,  Marsha M. Arvedson ,  Beverly J. Poole ,  Abhimanyu Onkar Patil ,  Lisa Saunders Baugh ,  Karla Schall Colle

    IPC分类号： C08L23/00

    CPC分类号： C08L23/0823 ,  C08L23/16 ,  C08L53/00 ,  C08L2314/06 ,  C08L2666/24 ,  C08L2666/06

    摘要： A polymer composition comprises (a) greater than 50 wt % (based upon the weight of the composition) of a cyclic olefin copolymer comprising at least one acyclic olefin and at least 20 weight % of one or more cyclic olefins (based upon the weight of the cyclic olefin copolymer), wherein at least a portion of the cyclic olefin copolymer has a glass transition temperature of greater than 150° C.; and (b) less than 50 wt % (based upon the weight of the composition) of an acyclic olefin polymer modifier, at least a portion of the modifier having a glass transition temperature of less than −30° C.; and no portion of the modifier having a softening point greater than +30° C., wherein the Bicerano solubility parameter of the modifier being no more than 0.6 J0.5/cm1.5 less than the Bicerano solubility parameter of the cyclic olefin copolymer. The polymer composition has a notched Izod impact resistance measured at 23° C. of greater than 500 J/m and a heat distortion temperature measured using a 0.46 MPa load of greater than 135° C.

    摘要翻译： 聚合物组合物包含（a）大于50重量％（基于组合物的重量）的包含至少一种非环烯烃和至少20重量％的一种或多种环烯烃的环烯烃共聚物（基于 环烯烃共聚物），其中至少一部分环烯烃共聚物的玻璃化转变温度大于150℃; 和（b）小于50重量％（基于组合物的重量）非环烯烃聚合物改性剂，至少一部分改性剂的玻璃化转变温度低于-30℃; 并且所述改性剂的任何部分的软化点大于+ 30℃，其中所述改性剂的二辛醇溶解度参数不大于0.6J / 小于环烯烃共聚物的Bicerano溶解度参数。 该聚合物组合物在23℃下测得的切口悬臂梁式冲击强度大于500J / m，并且使用大于135℃的0.46MPa载荷测量的热变形温度。

    Ethylene/dicyclopentadiene/norbornene terpolymer materials having desirable structural and thermal properties
    6.
    发明申请
    Ethylene/dicyclopentadiene/norbornene terpolymer materials having desirable structural and thermal properties 审中-公开
    乙烯/二环戊二烯/降冰片烯三元共聚物材料具有理想的结构和热性能

    公开(公告)号：US20080221275A1

    公开(公告)日：2008-09-11

    申请号：US12074213

    申请日：2008-02-29

    申请人： Lisa S. Baugh ,  Enock Berluche ,  Abhimanyu O. Patil ,  Beverly J. Poole ,  Kevin D. Robinson ,  Kevin R. Squire

    发明人： Lisa S. Baugh ,  Enock Berluche ,  Abhimanyu O. Patil ,  Beverly J. Poole ,  Kevin D. Robinson ,  Kevin R. Squire

    IPC分类号： C08F4/76 ,  C08F36/00 ,  C08F36/04 ,  C08F4/80

    CPC分类号： C08C19/06 ,  C08F8/04 ,  C08F8/08 ,  C08F210/02

    摘要： Provided are selected types of terpolymer components comprising terpolymers having monomer units derived from ethylene (E), dicyclopentadiene (DCPD) and norbornene-based (NB) co-monomers. Such terpolymer components have certain specified amounts of each co-monomer as well as certain specified molecular weight and glass transition temperature characteristics. Terpolymer components which are derivatized by hydrogenation and/or by epoxidation and/or hydroxylation are also disclosed, as well as thermoplastic polyolefin compositions which contain the terpolymer components and which have especially desirable structural and thermal properties.Also provided are processes for preparing and derivatizing the terpolymer components herein. Such preparation processes comprise: a) contacting ethylene with a polymerization mixture comprising selected amounts of both DCPD and NB co-monomers, in the presence of a selected activated cyclopentadienyl-fluorenyl metallocene catalyst under specific polymerization conditions to thereby form the desired ethylene-dicyclopentadiene-norbornene terpolymer components within the polymerization mixture. These terpolymer components can then be subsequently derivatized by hydrogenation or functionalization of the residual double bonds therein.

    摘要翻译： 提供了包含来自乙烯（E），二环戊二烯（DCPD）和降冰片烯基（NB））共聚单体的单体单元的三元共聚物的选择类型的三元共聚物组分。 这些三元共聚物组分具有特定量的每种共聚单体以及某些特定的分子量和玻璃化转变温度特性。 还公开了通过氢化和/或通过环氧化和/或羟基化衍生化的三元共聚物组分，以及含有三元共聚物组分并且具有特别期望的结构和热性质的热塑性聚烯烃组合物。 还提供了用于制备和衍生本文中三元共聚物组分的方法。 这样的制备方法包括：a）在选择的活化的环戊二烯基 - 芴基茂金属催化剂存在下，在特定的聚合条件下，使乙烯与包含选定量的DCPD和NB共聚单体的聚合混合物接触，从而形成所需的乙烯 - 二环戊二烯 - 降冰片烯三元共聚物组分在聚合混合物内。 然后可以通过氢化或官能化其中的残余双键将这些三元共聚物组分衍生化。

    Nanocomposite comprising stabilization functionalized thermoplastic polyolefins
    7.
    发明授权
    Nanocomposite comprising stabilization functionalized thermoplastic polyolefins 有权
    包含稳定官能化的热塑性聚烯烃的纳米复合材料

    公开(公告)号：US07371793B2

    公开(公告)日：2008-05-13

    申请号：US10800455

    申请日：2004-03-15

    申请人： Caiguo Gong ,  Alan J. Oshinski ,  Beverly J. Poole ,  Jerry W. Ball ,  Thomas W. Sykes

    发明人： Caiguo Gong ,  Alan J. Oshinski ,  Beverly J. Poole ,  Jerry W. Ball ,  Thomas W. Sykes

    IPC分类号： C08K9/04

    CPC分类号： B82Y30/00 ,  C08F8/32 ,  C08K2201/011 ,  C08L21/00 ,  C08F255/02 ,  C08F8/46 ,  C08F110/06

    摘要： This invention relates to nanocomposites comprising organo-clay and at least one stabilization functionalized thermoplastic polyolefin. Preferably the stabilization functionalized thermoplastic polyolefin is represented by the formula: T-(R1G)n Wherein T represents the thermoplastic polyolefin Each R1 is a bridging group, preferably independently selected from the group consisting of C1 to C20 aliphatic; C1 to C20 aromatic; substituted C1 to C20 aliphatic; substituted C1 to C20 aromatic; C1 to C20 aliphatic ester; C1 to C20 aliphatic ether; C1 to C20 aliphatic amide; C1 to C20 aliphatic imide; n is the number of stabilization functional/bridging groups bound to T and may be from 1-300; and G is selected from one or more of phenols, ketones, hindered amines, substituted phenols, substituted ketones, substituted hindered amines, or combinations thereof.

    摘要翻译： 本发明涉及包含有机粘土和至少一种稳定官能化的热塑性聚烯烃的纳米复合材料。 优选地，稳定化官能化的热塑性聚烯烃由下式表示：<？in-line-formula description =“In-line Formulas”end =“lead”？> T-（R＆lt; 1＆gt; G） > n <？in-line-formula description =“In-line Formulas”end =“tail”？>其中T表示热塑性聚烯烃。每个R 1是桥连基，优选 独立地选自C 1至C 20脂族基团; C 1至C 20芳族; 取代的C 1至C 20脂族基; 取代的C 1至C 20芳族; C 1至C 20脂族酯; C 1至C 20脂族醚; C 1至C 20脂族酰胺; C 1至C 20脂族酰亚胺; n是与T结合的稳定性功能性/桥连基团的数目，可以是1-300; 并且G选自酚，酮，受阻胺，取代酚，取代的酮，取代的受阻胺或其组合中的一种或多种。

    Nanocomposite comprising stabilization functionalized thermoplastic polyolefins
    8.
    发明授权
    Nanocomposite comprising stabilization functionalized thermoplastic polyolefins 有权
    包含稳定官能化的热塑性聚烯烃的纳米复合材料

    公开(公告)号：US07825182B2

    公开(公告)日：2010-11-02

    申请号：US12060608

    申请日：2008-04-01

    申请人： Caiguo Gong ,  Alan J. Oshinski ,  Beverly J. Poole ,  Jerry W. Ball ,  Thomas W. Sykes

    发明人： Caiguo Gong ,  Alan J. Oshinski ,  Beverly J. Poole ,  Jerry W. Ball ,  Thomas W. Sykes

    IPC分类号： C08K3/34

    CPC分类号： B82Y30/00 ,  C08F8/32 ,  C08K2201/011 ,  C08L21/00 ,  C08F255/02 ,  C08F8/46 ,  C08F110/06

    摘要： This invention relates to nanocomposites comprising organo-clay and at least one stabilization functionalized thermoplastic polyolefin. Preferably the stabilization functionalized thermoplastic polyolefin is represented by the formula: T-(R1G)n wherein T represents the thermoplastic polyolefin Each R1 is a bridging group, preferably independently selected from the group consisting of C1 to C20 aliphatic; C1 to C20 aromatic; substituted C1 to C20 aliphatic; substituted C1 to C20 aromatic; C1 to C20 aliphatic ester; C1 to C20 aliphatic ether; C1 to C20 aliphatic amide; C1 to C20 aliphatic imide; n is the number of stabilization functional/bridging groups bound to T and may be from 1-300; and G is selected from one or more of phenols, ketones, hindered amines, substituted phenols, substituted ketones, substituted hindered amines, or combinations thereof.

    摘要翻译： 本发明涉及包含有机粘土和至少一种稳定官能化的热塑性聚烯烃的纳米复合材料。 优选地，稳定官能化热塑性聚烯烃由下式表示：T-（R1G）n其中T表示热塑性聚烯烃。每个R 1是桥连基团，优选独立地选自C 1 -C 20脂族基团; C1至C20芳族; 取代的C 1 -C 20脂族基; 取代的C 1 -C 20芳族; C1〜C20脂肪族酯; C1〜C20脂肪族醚; C1〜C20脂肪族酰胺; C1〜C20脂肪族酰亚胺; n是与T结合的稳定性功能性/桥连基团的数目，可以是1-300; 并且G选自酚，酮，受阻胺，取代酚，取代的酮，取代的受阻胺或其组合中的一种或多种。

    Nanocomposite Comprising Stabilization Functionalized Thermoplastic Polyolefins
    9.
    发明申请
    Nanocomposite Comprising Stabilization Functionalized Thermoplastic Polyolefins 有权
    纳米复合材料包括稳定化官能化热塑性聚烯烃

    公开(公告)号：US20080214707A1

    公开(公告)日：2008-09-04

    申请号：US12060608

    申请日：2008-04-01

    申请人： Caiguo Gong ,  Alan J. Oshinski ,  Beverly J. Poole ,  Jerry W. Ball ,  Thomas W. Sykes

    发明人： Caiguo Gong ,  Alan J. Oshinski ,  Beverly J. Poole ,  Jerry W. Ball ,  Thomas W. Sykes

    IPC分类号： C08K5/54 ,  C08K3/34 ,  C08K5/544 ,  C08K5/548

    CPC分类号： B82Y30/00 ,  C08F8/32 ,  C08K2201/011 ,  C08L21/00 ,  C08F255/02 ,  C08F8/46 ,  C08F110/06

    摘要： This invention relates to nanocomposites comprising organo-clay and at least one stabilization functionalized thermoplastic polyolefin. Preferably the stabilization functionalized thermoplastic polyolefin is represented by the formula: T-(R1G)n wherein T represents the thermoplastic polyolefin Each R1 is a bridging group, preferably independently selected from the group consisting of C1 to C20 aliphatic; C1 to C20 aromatic; substituted C1 to C20 aliphatic; substituted C1 to C20 aromatic; C1 to C20 aliphatic ester; C1 to C20 aliphatic ether; C1 to C20 aliphatic amide; C1 to C20 aliphatic imide; n is the number of stabilization functional/bridging groups bound to T and may be from 1-300; and G is selected from one or more of phenols, ketones, hindered amines, substituted phenols, substituted ketones, substituted hindered amines, or combinations thereof.

    摘要翻译： 本发明涉及包含有机粘土和至少一种稳定官能化的热塑性聚烯烃的纳米复合材料。 优选地，稳定化官能化的热塑性聚烯烃由下式表示：<？in-line-formula description =“In-line Formulas”end =“lead”？> T-（R＆lt; 1＆gt; G） > n <？in-line-formula description =“In-line Formulas”end =“tail”？>其中T表示热塑性聚烯烃。每个R 1是桥连基，优选 独立地选自C 1至C 20脂族基团; C 1至C 20芳族; 取代的C 1至C 20脂族基; 取代的C 1至C 20芳族; C 1至C 20脂族酯; C 1至C 20脂族醚; C 1至C 20脂族酰胺; C 1至C 20脂族酰亚胺; n是与T结合的稳定性功能性/桥连基团的数目，可以是1-300; 并且G选自酚，酮，受阻胺，取代酚，取代的酮，取代的受阻胺或其组合中的一种或多种。