Imaging member containing a copolymer of styrene and ethyl acrylate
    1.
    发明授权
    Imaging member containing a copolymer of styrene and ethyl acrylate 失效
    含有苯乙烯和丙烯酸乙酯共聚物的成像构件

    公开(公告)号:US4853307A

    公开(公告)日:1989-08-01

    申请号:US140441

    申请日:1988-01-04

    IPC分类号: G03G5/02 G03G13/22 G03G17/08

    CPC分类号: G03G13/22 G03G17/08

    摘要: An imaging system including a migration imaging member comprising a substrate and an electrically insulating softening layer adjacent the substrate, the softenable layer comprising a fracturable layer of electrically photosensitive migration marking material located substantially at or near the surface of the softenable layer spaced from the substrate, and a copolymer of styrene and ethyl acrylate in at least one layer adjacent the substrate, the copolymer comprising between about 40 and about 80 mole percent styrene, between about 20 and about 60 mole percent ethyl acrylate, the copolymer having a M.sub.n between about 4,000 and about 35,000, a M.sub.w between about 10,000 and about 80,000, a T.sub.g between about 30.degree. C. and about 75.degree. C., and a melt viscosity between about 1.times.10.sup.2 poise and about 1.times.10.sup.6 poise at 115.degree. C.The migration imaging member may be imaged by charging, imagewise exposing to activating radiation and developing with heat, solvent vapor, or solvent vapor pretreatment followed by heat. Some embodiments of the imaged member, wherein the softenable layer contains a charge transport material, may be utilized as a master in a zeroprinting process. The copolymer of styrene and ethyl acrylate may be in an adhesive layer of charge transport spacing layer between the substrate and the sofenable layer, or in the softenable layer itself. If desired, the copolymer in any of the aforesaid layers may be a terpolymer of styrene, ethyl acrylate and a copolymerizable organic acid having carbon-to-carbon unsaturation or a copolymerizable derivative of the organic acid.

    摘要翻译: 一种成像系统,其包括迁移成像构件,所述迁移成像构件包括基底和邻近所述基底的电绝缘软化层,所述可软化层包括位于所述可软化层的与所述基底隔开的表面的表面附近或附近的电光敏迁移标记材料的可破裂层, 和苯乙烯和丙烯酸乙酯在邻近基材的至少一层中的共聚物,所述共聚物包含约40至约80摩尔%的苯乙烯,约20至约60摩尔%的丙烯酸乙酯,所述共聚物的Mn在约4,000和 约35,000,约10,000至约80,000的Mw,约30℃至约75℃之间的Tg,以及在115℃下约1×102泊至约1×10 6泊的熔体粘度。迁移成像构件可以是 通过充电成像,成像暴露于活化辐射并用热,溶剂蒸气或溶剂蒸气预处理进行显影 加热。 成像构件的一些实施方案,其中可软化层含有电荷传输材料,可以在压印过程中用作母体。 苯乙烯和丙烯酸乙酯的共聚物可以在基材和可渗透层之间或在可软化层本身中的电荷输送间隔层的粘合剂层中。 如果需要,任何上述层中的共聚物可以是苯乙烯,丙烯酸乙酯和具有碳 - 碳不饱和键的可共聚有机酸或有机酸的可共聚衍生物的三元共聚物。

    Infrared or red light sensitive migration imaging member
    2.
    发明授权
    Infrared or red light sensitive migration imaging member 失效
    红外或红光敏感迁移成像构件

    公开(公告)号:US5215838A

    公开(公告)日:1993-06-01

    申请号:US771910

    申请日:1991-10-04

    CPC分类号: G03G17/10 G03G13/26 G03G17/04

    摘要: Disclosed is a migration imaging member comprising a substrate, an infrared or red light radiation sensitive layer comprising a pigment predominantly sensitive to infrared or red light radiation, and a softenable layer comprising a softenable material, a charge transport material, and migration marking material predominantly sensitive to radiation at a wavelength other than that to which the infrared or red light radiation sensitive pigment is sensitive contained at or near the surface of the softenable layer. When the migration imaging member is imaged and developed, it is particularly suitable for use as a xeroprinting master and can also be used for viewing or for storing data.

    摘要翻译: 公开了一种迁移成像构件,其包括基底,包含主要对红外或红光辐射敏感的颜料的红外或红光辐射敏感层,以及包含可软化材料,电荷传输材料和迁移标记材料的可软化层,其主要是敏感的 以在红外或红光敏感颜料敏感的波长以外的波长处辐射包含在可软化层的表面处或附近。 当迁移成像构件成像和显影时,它特别适合用作干印母版,并且还可以用于观看或存储数据。

    Processes for preparing copolymers
    3.
    发明授权
    Processes for preparing copolymers 失效
    制备共聚物的方法

    公开(公告)号:US6124409A

    公开(公告)日:2000-09-26

    申请号:US929457

    申请日:1992-08-12

    摘要: Disclosed is a process for preparing copolymers which comprises, in the order stated: (1) adding monomers containing unsaturated carbon-to-carbon bonds, a first polymerization initiator, a second polymerization initiator, and a solvent to a reaction vessel; (2) purging the resulting solution with an inert gas; (3) sealing the reaction vessel and pressurizing it by addition of an inert gas to a pressure of from about 20 to about 600 kilopascals over ambient atmospheric pressure; (4) maintaining the temperature within the pressurized reaction vessel at a temperature of from about 50 to about 100.degree. C. for a period of from about 60 to about 300 minutes; (5) thereafter maintaining the temperature within the pressurized reaction vessel at a temperature of from about 80 to about 115.degree. C. for a period of from about 30 to about 300 minutes, wherein the temperature in step (5) is higher than the temperature in step (4); and (6) subsequently maintaining the temperature within the pressurized reaction vessel at a temperature of from about 115 to about 160.degree. C. for a period of from about 30 to about 180 minutes, wherein the temperature in step (6) is higher than the temperature in step (5). Polymers prepared according to the process of the present invention can be particularly useful in migration imaging members.

    摘要翻译: 公开了一种制备共聚物的方法,其顺序包括:(1)向反应容器中加入含有不饱和碳 - 碳键的单体,第一聚合引发剂,第二聚合引发剂和溶剂; (2)用惰性气体吹扫所得溶液; (3)密封反应容器并通过在环境大气压下加入约20至约600千帕斯卡的惰性气体对其加压; (4)将加压反应容器内的温度维持在约50至约100℃的温度下约60至约300分钟; (5)之后将加压反应容器内的温度保持在约80至约115℃的温度下约30至约300分钟的时间,其中步骤(5)中的温度高于温度 在步骤(4)中; 和(6)随后将加压反应容器内的温度保持在约115至约160℃的温度下约30至约180分钟的时间,其中步骤(6)中的温度高于 步骤(5)中的温度。 根据本发明的方法制备的聚合物可以在迁移成像构件中特别有用。

    Xeroprinting process with improved contrast potential
    5.
    发明授权
    Xeroprinting process with improved contrast potential 失效
    Xeroprinting过程具有改善的对比度潜力

    公开(公告)号:US4970130A

    公开(公告)日:1990-11-13

    申请号:US444343

    申请日:1989-12-01

    CPC分类号: G03G17/10 G03G5/026

    摘要: Disclosed is a xeroprinting process which comprises(1) providing a xeroprinting master comprising(a) a substrate; and(b) a softenable layer comprising a softenable material, a charge transport material capable of transporting charges of one polarity, and migration marking material situated contiguous to the surface of the softenable layer spaced from the substrate, wherein a portion of the migration marking material has migrated through the softenable layer toward the substrate in imagewise fashion;(2) uniformly charging the xeroprinting master to a polarity opposite to the polarity of the charges that the charge transport material in the softenable layer is capable of transporting;(3) uniformly exposing the charged master to activating radiation, thereby discharging those areas of the master wherein the migration marking material has migrated toward the substrate and forming an electrostatic latent image;(4) developing the electrostatic latent image; and(5) transferring the developed image to a receiver sheet.The process results in greatly enhanced contrast potentials or contrast voltages between the charged and uncharged areas of the master subsequent to exposure to activating radiation, and the charged master can be developed with either liquid developers or dry developers.

    Image bar with electrochromic switching system
    6.
    发明授权
    Image bar with electrochromic switching system 失效
    具有电致变色开关系统的图像条

    公开(公告)号:US4916470A

    公开(公告)日:1990-04-10

    申请号:US272040

    申请日:1988-11-16

    摘要: Disclosed is an image bar for use in an imaging apparatus, comprising a linear light valve array with a plurality of discrete, independently addressable pixel portions activatable between light transmitting, partially transmitting, and non-transmitting wavelengths by selective application of an electrical field. The pixel portions comprise, in the order stated, a first transparent substrate; a transparent electrode in contact with the first transparent substrate; a thin film comprising an electrochromic material in contact with the transparent electrode; a transparent electrolytic material in contact with the thin film; a counterelectrode in contact with the transparent electrolytic material; and a second substrate.

    摘要翻译: 公开了一种用于成像装置的图像条,包括具有多个独立可寻址的像素部分的线性光阀阵列,其可通过选择性施加电场在光透射,部分透射和非透射波长之间激活。 像素部分按照所述顺序包括第一透明衬底; 与第一透明基板接触的透明电极; 包括与所述透明电极接触的电致变色材料的薄膜; 与薄膜接触的透明电解质材料; 与透明电解质材料接触的反电极; 和第二基板。

    Overcoated migration imaging system
    7.
    发明授权
    Overcoated migration imaging system 失效
    涂覆移植成像系统

    公开(公告)号:US4496642A

    公开(公告)日:1985-01-29

    申请号:US493914

    申请日:1983-05-12

    CPC分类号: G03G17/10 G03G16/00

    摘要: An imaging member comprising a substrate, an electrically insulating swellable, softenable layer on the substrate, the softenable layer having particulate migration marking material located at least at or near the surface of the softenable layer spaced from the substrate, and a protective overcoating comprising a film-forming resin, a portion of which extends beneath the surface of the softenable layer. This migration imaging member may be prepared with the aid of a material which swells at least the surface of the softenable layer to allow the film-forming resin to penetrate beneath the surface of the softenable layer.

    摘要翻译: 一种成像构件,包括基底,在基底上的电绝缘的可溶胀的可软化层,所述可软化层具有至少位于或接近与所述基底隔开的可软化层的表面或附近的颗粒迁移标记材料,以及保护性外涂层, 形成树脂,其一部分在可软化层的表面下方延伸。 该迁移成像构件可以借助于至少溶胀可软化层的表面的材料来制备,以允许成膜树脂穿透在可软化层的表面之下。