公开(公告)号：US08497024B2

公开(公告)日：2013-07-30

申请号：US12860682

申请日：2010-08-20

申请人： Manabu Ueno ,  Toshio Shiobara ,  Tsutomu Kashiwagi

发明人： Manabu Ueno ,  Toshio Shiobara ,  Tsutomu Kashiwagi

IPC分类号： B32B9/04

CPC分类号： C08G77/50 ,  C08G77/16 ,  C08G77/18 ,  C08G77/24 ,  C08L83/14 ,  Y10T428/31663 ,  C08L83/00

摘要： Organopolysilmethylene-siloxane of the formula (1): wherein each R1 is, independently of one another, an unsubstituted or substituted monovalent hydrocarbon group having 1 to 10 carbon atoms other than an alkenyl group, an alkoxy group, a hydroxy group, and a halogen atom; each R2 is, independently of one another, an unsubstituted or substituted monovalent hydrocarbon group having 1 to 10 carbon atoms other than an alkenyl group, an alkoxy group, a hydroxy group, a halogen atom, and (R1)3SiCH2—, wherein each R3 is, independently of one another, a hydrogen atom and an alkyl group having 1 to 4 carbon atoms; k is an integer of 1 to 100; and n is an integer of 1 to 1000; said organopolysilmethylene-siloxane having, in a molecule, at least two out of alkoxy groups, hydroxy groups, and halogen atoms bonded to one or more silicon atoms.

摘要翻译： 式（1）的有机聚硅氧烷 - 硅氧烷：其中每个R 1彼此独立地是除烯基，烷氧基，羟基和卤素以外的未取代或取代的碳原子数1〜10的一价烃基 原子; 每个R 2彼此独立地是除烯基，烷氧基，羟基，卤素原子和（R 1）3 SiCH 2 - 以外具有1至10个碳原子的未取代或取代的一价烃基，其中每个R 3 彼此独立地是氢原子和具有1至4个碳原子的烷基; k为1〜100的整数， n为1〜1000的整数。 所述有机聚硅氧烷 - 硅氧烷在分子中具有至少两个烷氧基，羟基和与一个或多个硅原子键合的卤素原子。

公开(公告)号：US07985806B2

公开(公告)日：2011-07-26

申请号：US12360652

申请日：2009-01-27

申请人： Toshio Shiobara ,  Tsutomu Kashiwagi ,  Miyuki Wakao ,  Manabu Ueno

发明人： Toshio Shiobara ,  Tsutomu Kashiwagi ,  Miyuki Wakao ,  Manabu Ueno

IPC分类号： C08G77/14 ,  C08L83/06

CPC分类号： C08G77/388 ,  C08L83/08

摘要： An organopolysiloxane represented by formula (1) shown below and having (3,5-diglycidylisocyanuryl)alkyl groups represented by formula (2) at least at both terminals of the main chain: wherein, each R1 represents, independently, a substituted or unsubstituted monovalent hydrocarbon group of 1 to 20 carbon atoms, R2 is a group represented by formula (2) shown below, X is a group represented by formula (3) shown below, a represents an integer of 0 to 100 and b represents an integer of 0 to 30, provided that 1≦a+b, and c represents an integer of 0 to 10 wherein, R3 represents an alkylene group of 2 to 12 carbon atoms wherein, R1 and R2 are as defined above, d represents an integer of 0 to 30, and e represents an integer of 0 to 30.

摘要翻译： 由式（1）表示的由下述式（1）表示的有机聚硅氧烷和至少在主链的两个末端具有由式（2）表示的（3,5-二缩水甘油基异氰脲基）烷基：其中，每个R 1独立地表示取代或未取代的一价 1〜20个碳原子的烃基，R2为下述式（2）所示的基团，X为下述式（3）表示的基团，a表示0〜100的整数，b表示0以下的整数 至30，条件是1＆nlE; a + b和c表示0至10的整数，其中R 3表示2至12个碳原子的亚烷基，其中R 1和R 2如上所定义，d表示0至 30，e表示0〜30的整数。

公开(公告)号：US20110046319A1

公开(公告)日：2011-02-24

申请号：US12860682

申请日：2010-08-20

申请人： Manabu Ueno ,  Toshio Shiobara ,  Tsutomu Kashiwagi

发明人： Manabu Ueno ,  Toshio Shiobara ,  Tsutomu Kashiwagi

IPC分类号： C08L83/06 ,  C08G77/16

CPC分类号： C08G77/50 ,  C08G77/16 ,  C08G77/18 ,  C08G77/24 ,  C08L83/14 ,  Y10T428/31663 ,  C08L83/00

摘要： The present invention provides an organopolysilmethylene represented by the following general formula (1): wherein R1 is, independently of each other, a group selected from the group consisting of an unsubstituted or substituted monovalent hydrocarbon group having 1 to 10 carbon atoms other than an alkenyl group, an alkoxy group, a hydroxy group and a halogen atom; R2 is, independently of each other, a group selected from the group consisting of an unsubstituted or substituted monovalent hydrocarbon group having 1 to 10 carbon atoms other than an alkenyl group, an alkoxy group, a hydroxy group, a halogen atom and (R1)3SiCH2—, wherein R3 is, independently of each other, a group selected from the group consisting of a hydrogen atom and an alkyl group having 1 to 4 carbon atoms; k is an integer of 1 to 100; and n is an integer of 1 to 1000; and having, in a molecule, at least two out of alkoxy groups, hydroxy groups and halogen atoms bonded to one or more silicon atoms.

摘要翻译： 本发明提供由以下通式（1）表示的有机聚亚甲硅烷基：其中R 1彼此独立地为选自除烯基以外的未取代或取代的碳原子数1〜10的一价烃基 基团，烷氧基，羟基和卤素原子; R2彼此独立地选自除烯基，烷氧基，羟基，卤素原子以外的未取代或取代的碳原子数1〜10的一价烃基和（R1） 3SiCH 2 - ，其中R 3彼此独立地为选自氢原子和具有1至4个碳原子的烷基的基团; k为1〜100的整数， n为1〜1000的整数。 并且在一个分子中具有与一个或多个硅原子键合的烷氧基，羟基和卤素原子中的至少两个。

公开(公告)号：US08710158B2

公开(公告)日：2014-04-29

申请号：US13080730

申请日：2011-04-06

申请人： Manabu Ueno ,  Miyuki Wakao ,  Tsutomu Kashiwagi

发明人： Manabu Ueno ,  Miyuki Wakao ,  Tsutomu Kashiwagi

IPC分类号： C08G59/20 ,  C08G59/42 ,  C08G59/62 ,  C08L63/00 ,  C08L83/08 ,  C08L83/10 ,  H01L21/56

CPC分类号： H01L33/56 ,  C08G59/306 ,  C08G59/3254 ,  C08G59/42

摘要： The present invention has a purpose of providing an epoxy composition for encapsulating an optical semiconductor element which composition provides a cured product having a low gas permeability and excellent curability in a form of a thin film together with good light transmission and crack resistance. The present invention provides a composition comprising (A) a silicone-modified epoxy compound represented by the formula (1), (B) a curing agent and (C) a polyhydric alcohol. The present invention further provides a composition comprising a composition prepared by reacting (A) the silicone-modified epoxy compound, (B) the curing agent and (C) the polyhydric alcohol and (D) a curing catalyst, and a cured product thereof.

摘要翻译： 本发明的目的是提供一种用于封装光学半导体元件的环氧组合物，该组合物提供具有低透气性的固化产物和薄膜形式的优异的固化性以及良好的透光性和抗裂纹性。 本发明提供一种组合物，其包含（A）由式（1）表示的硅氧烷改性的环氧化合物，（B）固化剂和（C）多元醇。 本发明还提供一种组合物，其包含通过（A）硅氧烷改性的环氧化合物，（B）固化剂和（C）多元醇和（D）固化催化剂及其固化产物反应制备的组合物。

公开(公告)号：US20110251305A1

公开(公告)日：2011-10-13

申请号：US13080730

申请日：2011-04-06

申请人： Manabu Ueno ,  Miyuki Wakao ,  Tsutomu Kashiwagi

发明人： Manabu Ueno ,  Miyuki Wakao ,  Tsutomu Kashiwagi

IPC分类号： C08L63/00 ,  C08G77/26

CPC分类号： H01L33/56 ,  C08G59/306 ,  C08G59/3254 ,  C08G59/42

摘要： The present invention has a purpose of providing an epoxy composition for encapsulating an optical semiconductor element which composition provides a cured product having a low gas permeability and excellent curability in a form of a thin film together with good light transmission and crack resistance. The present invention provides a composition comprising (A) a silicone-modified epoxy compound represented by the formula (1), (B) a curing agent and (C) a polyhydric alcohol. The present invention further provides a composition comprising a composition prepared by reacting (A) the silicone-modified epoxy compound, (B) the curing agent and (C) the polyhydric alcohol and (D) a curing catalyst, and a cured product thereof.

摘要翻译： 本发明的目的是提供一种用于封装光学半导体元件的环氧组合物，该组合物提供具有低透气性的固化产物和薄膜形式的优异的固化性以及良好的透光性和抗裂纹性。 本发明提供一种组合物，其包含（A）由式（1）表示的硅氧烷改性的环氧化合物，（B）固化剂和（C）多元醇。 本发明还提供一种组合物，其包含通过（A）硅氧烷改性的环氧化合物，（B）固化剂和（C）多元醇和（D）固化催化剂及其固化产物反应制备的组合物。

公开(公告)号：US09306133B2

公开(公告)日：2016-04-05

申请号：US13584426

申请日：2012-08-13

申请人： Yoshihira Hamamoto ,  Manabu Ueno ,  Tsutomu Kashiwagi

发明人： Yoshihira Hamamoto ,  Manabu Ueno ,  Tsutomu Kashiwagi

IPC分类号： C08G77/08 ,  H01L33/56 ,  C08L83/04 ,  H01L33/46

CPC分类号： H01L33/56 ,  C08G77/12 ,  C08G77/14 ,  C08G77/20 ,  C08G77/80 ,  C08K5/56 ,  C08L83/00 ,  C08L83/04 ,  H01L33/46 ,  H01L2224/16245 ,  H01L2224/32245 ,  H01L2224/45144 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/73265 ,  H01L2924/12044 ,  H01L2924/00014 ,  H01L2924/00

摘要： An optical semiconductor device in which an optical semiconductor element connected to a silver-plated copper lead frame is sealed with an addition curing silicone resin composition, the addition curing silicone resin composition having (A) organopolysiloxane that contains an aryl group and an alkenyl group and does not contain an epoxy group; (B) organohydrogenpolysiloxane that has at least two hydrosilyl groups per molecule and an aryl group, the organohydrogenpolysiloxane that contains 30 mol % or more of an HR2SiO0.5 unit in a constituent unit having an amount that a molar ratio of the hydrosilyl group in the component (B) with respect to the alkenyl group in the component (A) is 0.70 to 1.00; and (C) a hydrosilylation catalyst having a catalytic amount.

摘要翻译： 一种光学半导体器件，其中连接到镀银铜引线框架的光学半导体元件用加成固化硅树脂组合物密封，所述加成固化有机硅树脂组合物具有（A）含有芳基和烯基的有机聚硅氧烷，和 不含环氧基; （B）每分子具有至少两个氢化甲硅烷基和芳基的有机氢聚硅氧烷，所述有机氢聚硅氧烷在构成单元中含有30摩尔％以上的HR2SiO0.5单元，其含量为所述氢甲硅烷基的摩尔比 组分（B）相对于组分（A）中的烯基为0.70至1.00; 和（C）具有催化量的氢化硅烷化催化剂。

公开(公告)号：US5991360A

公开(公告)日：1999-11-23

申请号：US18316

申请日：1998-02-03

申请人： Tetsuya Matsui ,  Kimio Yamada ,  Masatsugu Nishi ,  Manabu Ueno ,  Masahiro Tooma

发明人： Tetsuya Matsui ,  Kimio Yamada ,  Masatsugu Nishi ,  Manabu Ueno ,  Masahiro Tooma

IPC分类号： G21K5/02 ,  G03F7/20 ,  H01J35/00 ,  H01L21/027 ,  H05G2/00 ,  H05H1/24 ,  H01J35/08

CPC分类号： H05G2/003 ,  B82Y10/00 ,  G03F7/70033 ,  G03F7/70916 ,  H05G2/008

摘要： A laser plasma X-ray source has an improved X-ray conversion efficiency and a minimized occurrence of debris, and a semiconductor lithography apparatus using the same and a method therefor are provided. An X-ray generation unit has a vacuum chamber 5 which encases the target; target supply unit 110 which supplies a fine particle mixture gas target into the vacuum chamber 5; a laser irradiation unit 120 which irradiates a laser beam 2 on the particle mixture gas target 10; and a target recovery unit 130 which recovers unused particle mixture gas target from the vacuum chamber 5.

摘要翻译： 激光等离子体X射线源具有改善的X射线转换效率和最小化碎屑的出现，并且提供了使用其的半导体光刻设备及其方法。 X射线产生单元具有包围靶的真空室5; 目标供给单元110，其将微粒混合气体目标供给到真空室5中; 将激光束2照射在粒子混合气体靶10上的激光照射部120; 以及从真空室5回收未使用的混合气体目标的目标恢复单元130。