Olefin polymerization process
    1.
    发明申请
    Olefin polymerization process 有权
    烯烃聚合工艺

    公开(公告)号:US20060160962A1

    公开(公告)日:2006-07-20

    申请号:US10563497

    申请日:2004-06-29

    IPC分类号: C08F2/00

    摘要: A process for polymerizing one or more alpha-olefins of formula CH2═CHT wherein T is a hydrogen atom or a C1-C20 alkyl radical comprising the following steps: a) contacting in a continuous way one or more of said alpha olefins with a metallocene based catalyst system in a loop reactor, wherein: (i) the reaction is carried out in a liquid medium; (ii) the average residence time of the metallocene-based catalyst system is not more than 30 minutes; (iii) the temperature of the loop ranges from 25° to 70° C.; in to obtain a polymerization degree ranging from 60 to 500 g per gram of catalyst system; b) feeding in continuous the prepolymerized metallocene-based catalyst system obtained in step a) into a polymerization reactor C) polymerizing one or more alpha-olefins, the same or different from the alpha olefins used in step a), in the presence of said prepolymerized metallocene-based catalyst system.

    摘要翻译: 用于聚合一种或多种式CH 2 -CHT的α-烯烃的方法,其中T是氢原子或C 1 -C 20 - 烷基,其包括以下步骤:a)在环流反应器中以连续方式使一种或多种所述α-烯烃与茂金属基催化剂体系接触,其中:(i)反应在液体介质中进行; (ii)金属茂系催化剂体系的平均停留时间不超过30分钟; (iii)环路温度为25°至70°C; 以获得每克催化剂体系60至500克的聚合度; b)将在步骤a)中获得的预聚合的茂金属基催化剂体系连续进料到聚合反应器中C)使所述α-烯烃在所述 预聚金属茂系催化剂体系。

    Olefin polymerization process
    2.
    发明授权
    Olefin polymerization process 有权
    烯烃聚合工艺

    公开(公告)号:US07122606B2

    公开(公告)日:2006-10-17

    申请号:US10563497

    申请日:2004-06-29

    IPC分类号: C08F2/38

    摘要: A process for polymerizing one or more alpha-olefins of formula CH2═CHT wherein T is a hydrogen atom or a C1–C20 alkyl radical comprising the following steps: a) contacting in a continuous way one or more of said alpha olefins with a metallocene based catalyst system in a loop reactor, wherein: (i) the reaction is carried out in a liquid medium; (ii) the average residence time of the metallocene-based catalyst system is not more than 30 minutes; (iii) the temperature of the loop ranges from 25° to 70° C.; in order to obtain a polymerization degree ranging from 60 to 500 g per gram of catalyst system; b) feeding in continuous the prepolymerized metallocene-based catalyst system obtained in step a) into a polymerization reactor C) polymerizing one or more alpha-olefins, the same or different from the alpha olefins used in step a), in the presence of said prepolymerized metallocene-based catalyst system.

    摘要翻译: 用于聚合一种或多种式CH 2 -CHT的α-烯烃的方法,其中T是氢原子或C 1 -C 20 - 烷基,其包括以下步骤:a)在环流反应器中以连续方式使一种或多种所述α-烯烃与茂金属基催化剂体系接触,其中:(i)反应在液体介质中进行; (ii)金属茂系催化剂体系的平均停留时间不超过30分钟; (iii)环路温度为25°至70°C; 以获得每克催化剂体系60至500g的聚合度; b)将在步骤a)中获得的预聚合的茂金属基催化剂体系连续进料到聚合反应器中C)使所述α-烯烃在所述 预聚金属茂系催化剂体系。