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公开(公告)号：US07671149B2
公开(公告)日：2010-03-02
申请号：US12157353
申请日：2008-06-10
IPC分类号： C08F4/42
CPC分类号： C08F210/16 , Y10S526/913 , C08F4/025 , C08F4/651 , C08F4/6555
摘要： The present invention provides a process for preparing a catalyst useful in gas phase polymerization of olefins wherein the hydrogen response of the catalyst can be improved by using a ketone as the electron donor in the catalyst. The catalyst consists of compounds of Ti, Mg, Al and a ketone preferably supported on an amorphous support.
摘要翻译： 本发明提供了一种制备可用于烯烃气相聚合的催化剂的方法，其中可以通过在催化剂中使用酮作为电子给体来改善催化剂的氢响应。 该催化剂由Ti，Mg，Al和优选负载在无定形载体上的酮的化合物组成。
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公开(公告)号：US20080312391A1
公开(公告)日：2008-12-18
申请号：US12157353
申请日：2008-06-10
CPC分类号： C08F210/16 , Y10S526/913 , C08F4/025 , C08F4/651 , C08F4/6555
摘要： The present invention provides a process for preparing a catalyst useful in gas phase polymerization of olefins wherein the hydrogen response of the catalyst can be improved by using a ketone as the electron donor in the catalyst. The catalyst consists of compounds of Ti, Mg, Al and a ketone preferably supported on an amorphous support.
摘要翻译： 本发明提供了一种制备可用于烯烃气相聚合的催化剂的方法，其中可以通过在催化剂中使用酮作为电子给体来改善催化剂的氢响应。 该催化剂由Ti，Mg，Al和优选负载在无定形载体上的酮的化合物组成。
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公开(公告)号：US07211535B2
公开(公告)日：2007-05-01
申请号：US10977949
申请日：2004-10-29
申请人： Mark Kelly , Shivendra Kumar Goyal , Victoria Ker , Perry Montyn de Wit , Brian Stephen Kimberley , Peter Phung Ming Hoang
发明人： Mark Kelly , Shivendra Kumar Goyal , Victoria Ker , Perry Montyn de Wit , Brian Stephen Kimberley , Peter Phung Ming Hoang
IPC分类号： C08F4/642 , C08F4/649 , C08F210/02
CPC分类号： C08F10/00 , C08F210/16 , C08F4/651 , C08F4/6555 , C08F4/025 , C08F210/14 , C08F2500/12
摘要： The present invention provides a novel process for preparing a catalyst useful in gas phase polymerization of olefins wherein the physical properties of the polymer and the productivity of the catalyst can be altered depending on the sequence of addition of the catalyst components. The catalyst consists of compounds of Ti, Mg, Al and optionally an electron donor supported on an amorphous support.
摘要翻译： 本发明提供了一种制备可用于烯烃气相聚合的催化剂的新方法，其中聚合物的物理性质和催化剂的生产率可以根据催化剂组分的添加顺序而改变。 催化剂由Ti，Mg，Al的化合物和任选的负载在非晶形载体上的电子给体组成。
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公开(公告)号：US07528090B2
公开(公告)日：2009-05-05
申请号：US10568822
申请日：2004-08-04
IPC分类号： C08F4/02 , C08F4/6592 , B01J31/22
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65916 , C08F4/6592 , C08F2420/02 , C08F4/65912 , C08F210/14
摘要： A supported polymerisation catalyst system comprises a porous support, a polymerisation catalyst and a cocatalyst wherein the support has been treated with an inert material such as polyisobutene. The support is preferably silica and is preferably treated with the inert material prior to contact with the other components. Preferably the polymerisation catalyst is a metallocene and the polymerisation catalyst system reduces the initial peak isotherm allowing for a smoother activity increase in particular for polymerisations carried out in the gas phase.
摘要翻译： 负载型聚合催化剂体系包括多孔载体，聚合催化剂和助催化剂，其中载体已用惰性材料如聚异丁烯处理。 载体优选为二氧化硅，并且优选在与其它组分接触之前用惰性材料处理。 优选地，聚合催化剂是茂金属，并且聚合催化剂体系降低了初始峰值等温线，从而允许更平滑的活性增加，特别是对于在气相中进行的聚合反应。
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公开(公告)号：US07442750B2
公开(公告)日：2008-10-28
申请号：US10539557
申请日：2003-12-03
申请人： Grant Berent Jacobsen , Brian Stephen Kimberley , Claudine Viviane Lalanne-Magne , Sergio Mastroianni
发明人： Grant Berent Jacobsen , Brian Stephen Kimberley , Claudine Viviane Lalanne-Magne , Sergio Mastroianni
IPC分类号： C08F4/613 , C08F4/64 , C08F4/643 , C08F4/6592
CPC分类号： C08F10/02 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F210/16 , C08F4/025 , C08F4/65916 , C08F210/14 , C08F2500/12
摘要： Supported catalyst systems are provided comprising (a) a transition metal compound, (b) an activator comprising (iii) an aluminoxane or (iv) a Group lilA metal or metalloid compound, and (c) a support material comprising an inorganic metal oxide, inorganic metal halide or polymeric material or mixtures thereof characterised in that the support material has been pretreated with a source of a transition metal atom. The preferred transition metal compounds are metallocenes and the source of the transition metal atom is typically a ferrous or cupric metal salt. The supported catalyst systems show improved activity and also may reduce fouling in gas phase fluidised bed processes.
摘要翻译： 提供了负载催化剂体系，其包含（a）过渡金属化合物，（b）活化剂，其包含（iii）铝氧烷或（iv）组合的LiAl金属或准金属化合物，和（c）包含无机金属氧化物的载体材料， 无机金属卤化物或聚合物材料或其混合物，其特征在于支撑材料已用过渡金属原子源预处理。 优选的过渡金属化合物是金属茂，过渡金属原子的来源通常是亚铁或二价金属盐。 负载型催化剂体系显示出改善的活性，并且还可以减少气相流化床方法中的结垢。
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公开(公告)号：US07148304B2
公开(公告)日：2006-12-12
申请号：US10667859
申请日：2003-09-23
IPC分类号： C08F210/02
CPC分类号： C07D213/53 , C07F13/005 , C07F15/0053 , C07F15/025 , C07F15/065 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2410/04 , Y10S526/943 , C08F4/61904 , C08F4/60089 , C08F4/6541 , C08F4/025 , C08F2500/04 , C08F2500/07 , C08F2500/12 , C08F210/14 , C08F2500/10 , C08F2500/26 , C08F2500/03 , C08F4/7042
摘要： A catalyst for the polymerization of 1-olefins is disclosed, which comprises (1) a compound of Formula B wherein M is Fe[II], Fe[III], Co[I], Co[II], Co[III], Mn[I], Mn[II], Mn[III], Mn[IV], Ru[II], Ru[III] or Ru[IV]; X represents an atom or group covalently or ionically bonded to the transition metal M; T is the oxidation state of the transition metal M and b is the valency of the atom or group X; R1, R2, R3, R4, R5, R6 and R7 are independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl; and when any two or more of R1–R7 are hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl, said two or more can be linked to form one or more cyclic substituents; and (2) a further catalyst. Copolymers made using the catalyst having specific physical properties are also disclosed
摘要翻译： 公开了用于1-烯烃聚合的催化剂，其包括（1）式B化合物，其中M为Fe [II]，Fe [III]，Co [I]，Co [II]，Co [III] Mn [I]，Mn [II]，Mn [III]，Mn [IV]，Ru [II]，Ru [III]或Ru [IV] X表示与过渡金属M共价或离子键合的原子或基团; T是过渡金属M的氧化态，b是原子或基团X的化合价; R 1，R 2，R 3，R 4，R 5， R 6和R 7独立地选自氢，卤素，烃基，取代的烃基，杂烃基或取代的杂烃基; 当R 1〜R 2中的任意两个以上为烃基，取代烃基，杂烃基或取代的杂烃基时，所述两个或多个可以连接形成一个或多个环状 取代基; 和（2）另外的催化剂。 还公开了使用具有特定物理性质的催化剂制备的共聚物
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公开(公告)号：US06657026B1
公开(公告)日：2003-12-02
申请号：US09659589
申请日：2000-09-11
IPC分类号： C08F442
CPC分类号： C07D213/53 , C07F13/005 , C07F15/0053 , C07F15/025 , C07F15/065 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2410/04 , Y10S526/943 , C08F4/61904 , C08F4/60089 , C08F4/6541 , C08F4/025 , C08F2500/04 , C08F2500/07 , C08F2500/12 , C08F210/14 , C08F2500/10 , C08F2500/26 , C08F2500/03 , C08F4/7042
摘要： A catalyst for the polymerization of 1-olefins which includes (1) a compound of Formula B wherein M is Fe[II], Fe[III], Co[I], Co[II], Co[III], Man[I], Man[II], Mn[III], Mn[IV], Ru[II], Ru[III] or Ru[IV]; X represents an atom or group covalently or ionically bonded to the transition metal M; T is the oxidation state of the transition metal M and b is the valency of the atom or group X; R1, R2, R3, R4, R5, R6 and R7 are independently selected form hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl; and when any two ore more of R1-R7 are hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl, said two or more can be linked to form one or more cyclic substituents; and (2) a further catalyst.
摘要翻译： 一种用于1-烯烃聚合的催化剂，其包括（1）式B化合物，其中M是Fe [II]，Fe [III]，Co [I]，Co [II]，Co [III]，Mn [I ]，Mn [II]，Mn [III]，Mn [IV]，Ru [II]，Ru [III]或Ru [IV] X表示与过渡金属M共价或离子键合的原子或基团; T是过渡金属M的氧化态，b是原子或基团X的化合价; R 1，R 2，R 3，R 4，R 5，R 6和R 7独立地选自氢，卤素，烃基，取代的烃基，杂烃基或取代的 杂烃基; 并且当R 1 -R 7中的任何两个或更多个是烃基，取代的烃基，杂烃基或取代的杂烃基时，所述两个或更多个可以连接形成一个或多个环状取代基; 和（2）另外的催化剂。
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公开(公告)号：US07811956B2
公开(公告)日：2010-10-12
申请号：US12216323
申请日：2008-07-02
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65916 , C08F210/14 , C08F2500/12 , C08F2500/04
摘要： A supported catalyst system comprises (a) a dehydrated support material, (b) a transition metal compound, and (c) an activator and is characterised in that the support material has been pretreated with at least two different organoaluminum compounds prior to content with either or both the transition metal-compound or the activator. The prefer transition metal compound is a metallocene and the supported catalyst systems are suitable for the preparation of polymers having broad molecular weight distributions and improved melt strength.
摘要翻译： 负载催化剂体系包括（a）脱水的载体材料，（b）过渡金属化合物和（c）活化剂，其特征在于，所述载体材料在含量之前用至少两种不同的有机铝化合物预处理 或过渡金属化合物或活化剂两者。 优选的过渡金属化合物是茂金属，并且负载型催化剂体系适用于制备具有宽分子量分布和改进的熔体强度的聚合物。
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公开(公告)号：US07335710B2
公开(公告)日：2008-02-26
申请号：US11347237
申请日：2006-02-06
IPC分类号： C08F4/6392 , C08F4/6592
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65908 , C08F2/34
摘要： A process for the polymerisation of olefins is described involving the use of a catalyst system comprising a supported transition metal compound and an activator based on an organoborane and an aluminoxane. Preferably the transition metal compound is a metallocene complex. The support is pretreated with an organoaluminium compound and the process is particularly suitable for the gas phase preparation of copolymers of ethylene and alpha-olefins having a molecular weight distribution in the range 2.5-7.0 and a melt strength in the range 3-12 cN.
摘要翻译： 描述了用于烯烃聚合的方法，涉及使用包含负载的过渡金属化合物和基于有机硼烷和铝氧烷的活化剂的催化剂体系。 优选地，过渡金属化合物是茂金属络合物。 该载体用有机铝化合物预处理，该方法特别适用于分子量分布范围为2.5-7.0，熔体强度在3-12cN范围内的乙烯和α-烯烃共聚物的气相制备。
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公开(公告)号：US07271226B2
公开(公告)日：2007-09-18
申请号：US10525730
申请日：2003-08-06
IPC分类号： C08F4/6392 , C08F4/632
CPC分类号： C08F210/16 , C08F4/65916 , C08F4/6592 , C08F110/06 , C08F4/65908 , C08F4/65912 , C08F210/14
摘要： A process for the homopolymerisation of ethylene or the copolymerisation of ethylene and (a-olefins in a polymeristation reactor, said process carried out in the presence of a catalyst system comprising (a) a polymerisation catalyst and (b) an ionic activator is characterised in that an organometallic compound of a Group IIIB metal having at least one unit of formula: Mç0çR or Mç0çM where M is the Group IIIB metal and R is a hydrocarbyl group is added to the reactor. Preferred organometallic compounds include aluminoxanes and the process results in improved poison scavenging as well as advantages in activity profiles, catalyst activity and product characteristics. The process is particularly suitable for use with supported metallocene catalyst systems in the slurry or gas phase.
摘要翻译： 乙烯均聚或乙烯与（a-烯烃在聚合反应器中的共聚）的方法，所述方法是在包含（a）聚合催化剂和（b）离子活化剂的催化剂体系存在下进行的，其特征在于 具有至少一个式：Mç0çR或Mç0çM的单元的IIIB族金属的有机金属化合物，其中M是IIIB族金属，R是烃基，优选的有机金属化合物包括铝氧烷，并且该方法得到改进 毒物清除以及活性特性，催化剂活性和产品特性的优点，该方法特别适用于在浆液或气相中负载的茂金属催化剂体系。
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