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公开(公告)号：US07855304B1
公开(公告)日：2010-12-21
申请号：US12807884
申请日：2010-09-16
IPC分类号： C07C67/02
CPC分类号： B01J37/0018 , B01J21/063 , B01J23/66 , B01J29/89 , B01J35/002 , B01J2229/42 , C04B35/46 , C04B35/62635 , C04B35/6265 , C04B35/62655 , C04B35/63424 , C04B35/63488 , C04B38/067 , C04B2103/006 , C04B2111/00129 , C04B2111/0081 , C04B2235/3289 , C04B2235/408 , C04B2235/6021 , C04B2235/6562 , C04B2235/721 , C04B2235/77 , C04B2235/80 , C04B2235/96 , C07C67/055 , C07D303/04 , C08F290/062 , C04B38/0054 , C04B38/0074 , C07C69/01 , C07C69/15
摘要： An extrudate comprising an inorganic oxide and a comb-branched polymer is disclosed. The calcined extrudates are useful catalysts or catalyst supports. A palladium-gold catalyst prepared with a calcined titania extrudate of the invention is useful in making vinyl acetate from ethylene, acetic acid, and oxygen or oxygen-containing gas. A calcined transition metal zeolite extrudate of the invention is used as a catalyst in oxidizing organic compounds with hydrogen peroxide. Incorporation of a comb-branched polymer improves the mechanical properties of inorganic oxide extrudates.
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公开(公告)号：US07825204B2
公开(公告)日：2010-11-02
申请号：US11641482
申请日：2006-12-19
CPC分类号： B01J37/0018 , B01J21/063 , B01J23/66 , B01J29/89 , B01J35/002 , B01J2229/42 , C04B35/46 , C04B35/62635 , C04B35/6265 , C04B35/62655 , C04B35/63424 , C04B35/63488 , C04B38/067 , C04B2103/006 , C04B2111/00129 , C04B2111/0081 , C04B2235/3289 , C04B2235/408 , C04B2235/6021 , C04B2235/6562 , C04B2235/721 , C04B2235/77 , C04B2235/80 , C04B2235/96 , C07C67/055 , C07D303/04 , C08F290/062 , C04B38/0054 , C04B38/0074 , C07C69/01 , C07C69/15
摘要： An extrudate comprising an inorganic oxide and a comb-branched polymer is disclosed. The calcined extrudates are useful catalysts or catalyst supports. A palladium-gold catalyst prepared with a calcined titania extrudate of the invention is useful in making vinyl acetate from ethylene, acetic acid, and oxygen or oxygen-containing gas. A calcined transition metal zeolite extrudate of the invention is used as a catalyst in oxidizing organic compounds with hydrogen peroxide. Incorporation of a comb-branched polymer improves the mechanical properties of inorganic oxide extrudates.
摘要翻译： 公开了一种包含无机氧化物和梳状支化聚合物的挤出物。 煅烧的挤出物是有用的催化剂或催化剂载体。 用本发明的煅烧二氧化钛挤出物制备的钯 - 金催化剂可用于制备乙烯，乙酸和氧或含氧气体的乙酸乙烯酯。 本发明的煅烧过渡金属沸石挤出物用作用过氧化氢氧化有机化合物的催化剂。 加入梳状支化聚合物改善了无机氧化物挤出物的机械性能。
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公开(公告)号：US20080146826A1
公开(公告)日：2008-06-19
申请号：US11641317
申请日：2006-12-19
IPC分类号： B01J29/068 , C07D301/03
CPC分类号： B01J37/0018 , B01J29/89 , B01J31/1616 , B01J2229/20 , B01J2229/42 , B01J2231/72 , B01J2531/821 , B01J2531/824 , B01J2531/825 , B01J2531/827 , B01J2531/828 , C08F290/062 , C08F290/142 , C08L51/08 , C08L2666/02
摘要： A catalyst comprising a transition metal zeolite and a noble metal is disclosed. The catalyst is prepared by an extrusion method using a comb-branched polymer as an extrusion aid. The catalyst is used in a reaction to produce epoxide from an olefin, hydrogen, and oxygen. The comb-branched polymer improves the mechanical properties of the extrudate.
摘要翻译： 公开了一种包含过渡金属沸石和贵金属的催化剂。 催化剂通过使用梳状支化聚合物作为挤出助剂的挤出方法制备。 催化剂用于从烯烃，氢气和氧气中产生环氧化物的反应中。 梳状支化聚合物改善了挤出物的机械性能。
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公开(公告)号：US20080146721A1
公开(公告)日：2008-06-19
申请号：US11641482
申请日：2006-12-19
CPC分类号： B01J37/0018 , B01J21/063 , B01J23/66 , B01J29/89 , B01J35/002 , B01J2229/42 , C04B35/46 , C04B35/62635 , C04B35/6265 , C04B35/62655 , C04B35/63424 , C04B35/63488 , C04B38/067 , C04B2103/006 , C04B2111/00129 , C04B2111/0081 , C04B2235/3289 , C04B2235/408 , C04B2235/6021 , C04B2235/6562 , C04B2235/721 , C04B2235/77 , C04B2235/80 , C04B2235/96 , C07C67/055 , C07D303/04 , C08F290/062 , C04B38/0054 , C04B38/0074 , C07C69/01 , C07C69/15
摘要： An extrudate comprising an inorganic oxide and a comb-branched polymer is disclosed. The calcined extrudates are useful catalysts or catalyst supports. A palladium-gold catalyst prepared with a calcined titania extrudate of the invention is useful in making vinyl acetate from ethylene, acetic acid, and oxygen or oxygen-containing gas. A calcined transition metal zeolite extrudate of the invention is used as a catalyst in oxidizing organic compounds with hydrogen peroxide. Incorporation of a comb-branched polymer improves the mechanical properties of inorganic oxide extrudates.
摘要翻译： 公开了一种包含无机氧化物和梳状支化聚合物的挤出物。 煅烧的挤出物是有用的催化剂或催化剂载体。 用本发明的煅烧二氧化钛挤出物制备的钯 - 金催化剂可用于制备乙烯，乙酸和氧或含氧气体的乙酸乙烯酯。 本发明的煅烧过渡金属沸石挤出物用作用过氧化氢氧化有机化合物的催化剂。 加入梳状支化聚合物改善了无机氧化物挤出物的机械性能。
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公开(公告)号：US07563740B2
公开(公告)日：2009-07-21
申请号：US11641317
申请日：2006-12-19
IPC分类号： B01J37/08 , B01J29/068 , C07D301/06
CPC分类号： B01J37/0018 , B01J29/89 , B01J31/1616 , B01J2229/20 , B01J2229/42 , B01J2231/72 , B01J2531/821 , B01J2531/824 , B01J2531/825 , B01J2531/827 , B01J2531/828 , C08F290/062 , C08F290/142 , C08L51/08 , C08L2666/02
摘要： A catalyst comprising a transition metal zeolite and a noble metal is disclosed. The catalyst is prepared by an extrusion method using a comb-branched polymer as an extrusion aid. The catalyst is used in a reaction to produce epoxide from an olefin, hydrogen, and oxygen. The comb-branched polymer improves the mechanical properties of the extrudate.
摘要翻译： 公开了一种包含过渡金属沸石和贵金属的催化剂。 催化剂通过使用梳状支化聚合物作为挤出助剂的挤出方法制备。 催化剂用于从烯烃，氢气和氧气中产生环氧化物的反应中。 梳状支化聚合物改善了挤出物的机械性能。
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公开(公告)号：US07175918B2
公开(公告)日：2007-02-13
申请号：US10832752
申请日：2004-04-27
IPC分类号： C08L51/00
CPC分类号： C08L51/003 , C08F283/06 , C08F290/00 , C08F290/142 , C08L23/0815 , C08L23/10 , C08L33/14 , C08L51/08 , C08L53/00 , Y10T428/31855 , C08L2666/04 , C08L2666/24 , C08L2666/02
摘要： The present invention relates to polyolefin compositions that incorporate an acrylic/polyether comb-branched copolymer, articles made from the compositions, such as polyolefin films and polyolefin fibers, and methods for making the compositions and the articles.
摘要翻译： 本发明涉及包含丙烯酸/聚醚梳状支化共聚物的聚烯烃组合物，由组合物制成的制品，如聚烯烃薄膜和聚烯烃纤维，以及制备组合物和制品的方法。
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公开(公告)号：US5938835A
公开(公告)日：1999-08-17
申请号：US950582
申请日：1997-10-15
IPC分类号： C04B20060101 , C04B24/00 , C04B24/02 , C04B24/32 , C04B28/02 , C04B103/30 , C04B103/60
CPC分类号： C04B24/023 , C04B24/32 , C04B28/02 , C04B2111/34
摘要： A cement admixture comprised of a mixture of certain alkyl ether oxyalkylene adducts with certain oxyalkylene glycols to provide cement compositions of mortar and concrete which inhibit drying shrinkage while permitting substantial air entrainment and enhanced compressive strength.
摘要翻译： 由某些烷基醚氧化烯加成物与某种氧化烯二醇的混合物组成的水泥混合物，以提供砂浆和混凝土的水泥组合物，其抑制干燥收缩同时允许显着的空气夹带和增强的抗压强度。
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公开(公告)号：US5614017A
公开(公告)日：1997-03-25
申请号：US621669
申请日：1996-03-26
申请人： Edward T. Shawl
发明人： Edward T. Shawl
CPC分类号： C04B24/2647 , C04B24/267 , C08F8/14 , C08G81/025 , C04B2103/302 , C04B2103/32
摘要： Substances useful as water reducing and superplasticizer additives for cement compositions are formed by reaction of carboxylic acid polymers with polyethers of C.sub.2 -C.sub.4 epoxides wherein partial cleavage of the polyether and esterification of the polyether and the cleavage products thereof by the other reactant are achieved. In one embodiment, a sulfonic acid is used to catalyze the reaction of poly(acrylic acid) and a monofunctional ethylene oxide-propylene oxide copolymer at a temperature in excess of 140.degree. C.
摘要翻译： 用作水泥组合物的减水剂和超增塑剂添加剂的物质是通过羧酸聚合物与C 2 -C 4环氧化物的聚醚的反应形成的，其中聚醚的部分裂解和聚醚的酯化以及其它反应物的裂解产物。 在一个实施方案中，磺酸用于在超过140℃的温度下催化聚（丙烯酸）和单官能环氧乙烷 - 环氧丙烷共聚物的反应。
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9.发明授权
公开(公告)号：US5220061A
公开(公告)日：1993-06-15
申请号：US963167
申请日：1992-10-19
IPC分类号： C07C263/04 , C07C269/06 , C07C273/18
CPC分类号： C07C273/1854
摘要： A selective process for the preparation of diphenylmethane bis(dialkylureas) is disclosed. An alkyl phenylcarbamate or an N,N-dialkyl-N'-phenylurea is reacted with a methylene bis(alkyl carbamate) in the presence of an acid catalyst. The use of a staged addition of phenylcarbamate or phenylurea to the methylene bis(carbamate) and the use of a ramped temperature program are the keys to good selectivity to MDI dimer products.
摘要翻译： 公开了制备二苯基甲烷双（二烷基脲）的选择性方法。 在酸催化剂存在下，将烷基苯基氨基甲酸酯或N，N-二烷基-N'-苯基脲与亚甲基双（烷基氨基甲酸酯）反应。 使用分段加成苯基氨基甲酸酯或苯脲至亚甲基双（氨基甲酸酯）和使用斜坡温度程序是对MDI二聚体产物具有良好选择性的关键。
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10.发明授权
公开(公告)号：US4055629A
公开(公告)日：1977-10-25
申请号：US750109
申请日：1976-12-13
申请人： Rudolph Rosenthal , Edward T. Shawl
发明人： Rudolph Rosenthal , Edward T. Shawl
摘要： A process for the recovery of selenium from a urethane solution containing selenium compounds which comprises contacting the selenium-containing urethane solution at a suitable temperature with copper (I) chloride, oxygen or an oxygen-containing gas such as air, and a complexing solvent such as an amine or nitrile to form an insoluble precipitate of copper-selenium compounds or complexes. The selenium and copper may be recovered from the resulting precipitate in a form suitable for reuse in the preparation of urethanes and selenium removal respectively.
摘要翻译： 一种从含有硒化合物的氨基甲酸酯溶液中回收硒的方法，其包括使合适的温度下的含硒氨基甲酸酯溶液与氯化铜（I），氧气或含氧气体如空气接触，以及络合溶剂如 作为胺或腈形成铜 - 硒化合物或络合物的不溶性沉淀物。 可以从生成的沉淀物中回收硒和铜，其形式适合分别用于制备氨基甲酸酯和除去硒。
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