Cyclic compounds and the use thereof as light absorbers, light emitters, or complex ligands
    1.
    发明申请
    Cyclic compounds and the use thereof as light absorbers, light emitters, or complex ligands 审中-公开
    环化合物及其作为光吸收剂,光发射体或复合配体的用途

    公开(公告)号:US20050167637A1

    公开(公告)日:2005-08-04

    申请号:US10509944

    申请日:2003-04-04

    摘要: The use of cyclic compounds of the formula (I) where n is a number in the range from 1 to 7, X-Y-Z, in each case independently of one another, is O—C═N, N═C—O, NR5—C═N, N═C—NR5, N+R52—C═N, N═C—N+R52, O—C═N+R5, N+R5═C—O, S—C═N+R5, N+R5═C—S, S—C═N, N═C—S, R1, R2 and R3 each independently are, for example, H or a substituent or corresponding heterocyclic compounds in which at least one group —CR1═, —CR2═, CR3═ is replaced by —N, R5 in each case independently are, for example, H or a substituent R7, in each case independently of one another, are H, C1-12-alkyl or C6-12-aryl, or metal complexes of the cyclic compounds or complexes of the cyclic compounds with mineral acids, chloride, sulfate, bisulfate, phosphate, hydrogen phosphate, nitrate, BF4− or methanesulfonate being present as opposite ions X− in the case of cationic cyclic structures, as light absorbers, materials for hole injection layers in OLEDs, light-emitting compounds in OLED, phase-transfer catalysts or synergistic agents for the dispersing of pigments or for optical data storage, is described.

    摘要翻译: 使用式(I)的环状化合物,其中n为1至7的数,XYZ在每种情况下彼此独立地为OCN,NCO,NR 5 -CN ,NC-NR 5,N + 5,...,5,...,...,N N + > 5 5 2,...,... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... > 5-CO,SCN +,...,5,...,...,...,... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ,NCS,R 1,R 2和R 3各自独立地为例如H或取代基或相应的杂环化合物,其中在 至少一个基团-CR 1, - CR 2 - , - CR 3 - 被-N,R 5, 在每种情况下,各自独立地是H或取代基R 7,在每种情况下彼此独立地为H,C 1-12 - 烷基或 C 6-12芳基或环状化合物的金属络合物或环状化合物与无机酸,氯化物,硫酸盐,硫酸氢盐,磷酸盐的络合物 在阳离子环状结构的情况下,作为阳离子环状结构存在,作为相反离子存在的磷酸根,硝酸根,BF 4 - 或 - 甲磺酸盐作为光 吸收剂,OLED中的空穴注入层的材料,OLED中的发光化合物,相转移催化剂或用于颜料分散或光学数据存储的协同剂。

    Compounds Comprising 2,6-Naphthyl Groups

    公开(公告)号:US20080221289A1

    公开(公告)日:2008-09-11

    申请号:US11914365

    申请日:2006-05-10

    CPC分类号: C09K19/322

    摘要: The present invention relates to compounds of the general formula I in which the variables are each defined as follows: Z1, Z2 are each independently hydrogen, optionally substituted C1-C20-alkyl in which the carbon chain may be interrupted by oxygen atoms in ether function, sulfur atoms in thioether function or by nonadjacent imino or C1-C4-alkylimino groups, or reactive radicals by means of which polymerization can be brought about, A1, A2 are each independently spacers having from 1 to 30 carbon atoms, in which the carbon chain may be interrupted by oxygen atoms in ether function, sulfur atoms in thioether function or by nonadjacent imino or C1-C4-alkylimino groups, Y1, Y2 are each independently a chemical single bond, oxygen, sulfur, —CO—, —O—CO—, —CO—O—, —S—CO—, —CO—S—, —NR—CO— or —CO—NR—, Y3, Y4 are each independently a chemical single bond, oxygen, sulfur, —CR═CR—, —C≡C—, —CR═CR—CO—O—, —O—CO—CR═CR—, —C≡C—O—, —O—C≡C—, —CH2—CH2—, —CH2—O—, —O—CH2—, —CH2—S—, —S—CH2—, —CO—, —O—CO—, —CO—O—, —S—CO—, —CO—S—, —NR—CO—, —CO—NR—, —O—CO—O—, —O—CO—NR— or —NR—CO—O—, R is hydrogen or C1-C4-alkyl, Y5 independently of Y1 and Y2, is as defined therefor above or is —O—COO—, T1, T2 are divalent saturated or unsaturated, optionally substituted iso- or heterocyclic radicals, r, t are each independently 0 or 1  and s is 0, 1, 2 or 3, where the particular variables T2 and Y3, in the case that s>1, may be the same as one another or different from one another and both the hydrogen atoms in the 2,6-naphthyl radical and the hydrogen atoms bonded to carbon atoms in the variables Z1, Z2, A1, A2, Y3, Y4, R, T1 and T2 may be substituted partly or fully by halogen atoms. The invention further relates to a polymerizable or nonpolymerizable liquid-crystalline composition comprising one or more of the inventive compounds, to an oligomer or polymer obtainable by oligomerization or polymerization of a polymerizable inventive liquid-crystalline composition, to a process for printing or coating a substrate by applying a polymerizable inventive liquid-crystalline composition to the substrate and subsequent polymerization, to the use of the inventive liquid-crystalline composition or of the inventive oligomer or polymer for producing optical or electrooptical components, to a process for preparing selected inventive compounds, and to intermediates which are particularly suitable for preparing the selected inventive compounds.

    Method for Determining the Identity, Absence and Concentration of a Chemical Compound in a Medium

    公开(公告)号:US20090006004A1

    公开(公告)日:2009-01-01

    申请号:US12159005

    申请日:2006-12-27

    IPC分类号: G01N21/00

    摘要: A method is proposed for detecting at least one chemical compound V contained in a medium (312). The method comprises a verification step (420) which is used to determine whether V is contained in the medium (312). The method furthermore comprises an analysis step (424) in which a concentration c of the at least one chemical compound V is determined.The verification step comprises the following substeps: (a1) the medium (312) is exposed to a first analysis radiation (316) of a variable wavelength λ, the wavelength λ assuming at least two different values; (a2) at least one spectral response function A(λ) is generated with the aid of the radiation (324) absorbed and/or emitted and/or reflected and/or scattered by the medium (312) in response to the first analysis radiation (316); (a3) at least one spectral correlation function K(δλ) is formed by spectral comparison of the at least one spectral response function A(λ) with at least one pattern function R(λ+δλ), the at least one pattern function R(λ) representing a spectral measurement function of a medium (312) containing the chemical compound V and δλ being a coordinate shift; (a4) the at least one spectral correlation function K(δλ) is examined in a pattern recognition step (418), and a conclusion is made as to whether the at least one chemical compound V is contained in the medium (312); The analysis step (424) comprises the following substeps: (b1) the medium (312) is exposed to at least one second analysis radiation (318) having at least one excitation wavelength λEX; (b2) at least one spectral analysis function B(λEX,λRES) is generated with the aid of the radiation (326) of the response wavelength λRES absorbed and/or emitted and/or reflected and/or scattered by the medium (312) in response to the second analysis radiation (318) of the wavelength λEX and the concentration c is deduced therefrom.

    Pyridone colorants
    7.
    发明授权
    Pyridone colorants 失效
    吡啶酮着色剂

    公开(公告)号:US6143898A

    公开(公告)日:2000-11-07

    申请号:US147277

    申请日:1998-11-18

    摘要: Pyridone dyes useful for thermal transfer and for dyeing or printing synthetic materials have the formula ##STR1## where X is CH or nitrogen,R.sup.1 is substituted or unsubstituted C.sub.1 -C.sub.20 -alkyl or substituted or unsubstituted phenyl,R.sup.2 is a carbocyclic or heterocyclic radical,R.sup.3 is hydrogen or C.sub.1 -C.sub.4 -alkyl,R.sup.4 is hydrogen or C.sub.1 -C.sub.4 -alkyl,R.sup.5 is substituted or unsubstituted C.sub.1 -C.sub.8 -alkyl or substituted or unsubstituted phenyl, andR.sup.6 is cyano, carbamoyl, carboxyl, C.sub.1 -C.sub.4 -alkoxycarbonyl or C.sub.1 -C.sub.4 -alkanoyl.

    摘要翻译: PCT No.PCT / EP97 / 02392 Sec。 371日期:1998年11月18日 102(e)1998年11月18日日期PCT提交1997年5月9日PCT公布。 公开号WO97 / 45491 日期1997年12月4日可用于热转印和染色或印刷合成材料的吡啶酮染料具有下式,其中X为CH或氮,R 1为取代或未取代的C 1 -C 20 - 烷基或取代或未取代的苯基,R 2为碳环或杂环 基团,R 3是氢或C 1 -C 4烷基,R 4是氢或C 1 -C 4烷基,R 5是取代或未取代的C 1 -C 8 - 烷基或取代或未取代的苯基,R 6是氰基,氨基甲酰基,羧基,C 1 -C 4 - 烷氧基羰基或C 1 -C 4 - 烷酰基。

    Naphtholactam dyes
    10.
    发明授权
    Naphtholactam dyes 失效
    萘酚内酰胺染料

    公开(公告)号:US5929245A

    公开(公告)日:1999-07-27

    申请号:US776596

    申请日:1997-02-18

    摘要: The invention concerns naphtholactam derivatives of formula (I), in which: R.sup.1 represents hydrogen, optionally substituted C.sub.1 -C.sub.6 alkyl C.sub.5 -C.sub.6 cycloalkcyl or substituted phenyl; R.sup.2 and R.sup.3 represent hydrogen, C.sub.1 -C.sub.8 alkanoyl, optionally substituted benzoyl, optionally substituted C.sub.2 -C.sub.4 alkyl, optionally substituted C.sub.2 -C.sub.4 alkenyl, optionally substituted C.sub.2 -C.sub.4 alkinyl, a halogen, nitro, sulphamoyl, optionally substituted hydroxy, optionally substituted mercapto, C.sub.1 -C.sub.6 alkysulphonyl or optionally substituted phenylsulphonyl; R.sup.4 represents hydrogen or, with R.sup.3, a group of formula (II); R.sup.5 represents hydrogen or C.sub.1 -C.sub.6 alkyl; R.sup.6 represents cyano, carbamoyl, C.sub.1 -C.sub.4 mono- or dialkylcarbamoyl carboxyl or C.sub.1 -C.sub.4 alkoxycarbonyl; and R.sup.7 represents substituted C.sub.1 -C.sub.4 alkyl, optionally substituted C.sub.5 -C.sub.13 alkyl or benzoyl. Also disclosed is the use of these derivatives for dyeing or printing textiles.

    摘要翻译: PCT No.PCT / EP95 / 03112 Sec。 371日期1997年2月18日 102(e)日期1997年2月18日PCT提交1995年8月4日PCT公布。 公开号WO96 / 06137 日期:1996年2月29日本发明涉及式(I)的萘内酰胺衍生物,其中:R 1表示氢,任选取代的C 1 -C 6烷基C 5 -C 6环烷基或取代的苯基; R 2和R 3表示氢,C 1 -C 8烷酰基,任选取代的苯甲酰基,任选取代的C 2 -C 4烷基,任选取代的C 2 -C 4烯基,任选取代的C 2 -C 4炔基,卤素,硝基,氨磺酰基,任选取代的羟基,任选取代的巯基 ,C 1 -C 6烷磺酰基或任选取代的苯基磺酰基; R4表示氢,或与R3表示式(Ⅱ)的基团。 R5表示氢或C1-C6烷基; R6表示氰基,氨基甲酰基,C1-C4单或二烷基氨基甲酰基羧基或C1-C4烷氧基羰基; 并且R 7表示取代的C 1 -C 4烷基,任选取代的C 5 -C 13烷基或苯甲酰基。 还公开了这些衍生物用于染色或印花纺织品的用途。