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    Polycarbonate styrene copolymer blends with improved properties
    1.
    发明授权
    Polycarbonate styrene copolymer blends with improved properties 失效
    具有改进性能的聚碳酸酯苯乙烯共聚物共混物

    公开(公告)号：US07265172B2

    公开(公告)日：2007-09-04

    申请号：US10510478

    申请日：2003-04-08

    申请人： Martin Weber ,  Xaver Hopfenspirger ,  Reinhard Jakobi ,  Walter Heckmann

    发明人： Martin Weber ,  Xaver Hopfenspirger ,  Reinhard Jakobi ,  Walter Heckmann

    IPC分类号： C08L69/00 ,  C08L51/04

    CPC分类号： C08L55/02 ,  C08F265/04 ,  C08L25/12 ,  C08L51/04 ,  C08L69/00 ,  C08L2205/035 ,  C08L2666/02 ,  C08L2666/14 ,  C08L2666/04

    摘要： Thermoplastic molding composition comprising components A, B, C and D and, if appropriate, E, F, G and H, A) from 1 to 97.5% by weight of at least one aromatic polycarbonate A, B) from 1 to 97.5% by weight of at least one graft polymer B made from b1) from 40 to 80% by weight of a graft base made from an elastomeric polymer B1, b2) from 20 to 60% by weight of a graft B2 made from b21) from 60 to 95% by weight of styrene or of substituted styrenes B21 and b22) from 5 to 40% by weight of at least one unsaturated nitrile B22, C) from 1 to 97.5% by weight of at least one thermoplastic copolymer C made from c1) from 60 to 85% by weight of styrene or of substituted styrenes C1 or mixtures thereof and c2) from 15 to 40% by weight of at least one unsaturated nitrile C2, D) from 0.5 to 50% by weight of at least one copolymer D, obtainable via reaction of d1) from 5 to 95% by weight of at least one thermoplastic methacrylate polymer D1 containing at least one type of functional groups selected from epoxy, carboxy, hydroxy, anhydride and oxazoline, with d2) from 5 to 95% by weight of at least one thermoplastic polyester D2, E) from 0 to 40% by weight of at least one filler E, F) from 0 to 2% by weight of at least one organic acid F, G) from 0 to 25% by weight of at least one halogen-free phosphorus compound G, H) from 0 to 45% by weight of other additives H.

    摘要翻译： 包含组分A，B，C和D以及如果合适的话，E，F，G和H的热塑性模塑组合物，A）1至97.5重量％的至少一种芳族聚碳酸酯A，B）1至97.5％ 由b1）制成的至少一种接枝聚合物B的重量为40〜80重量％的由弹性体聚合物B1制成的接枝基料，b2）20〜60重量％的由b21制得的接枝体B2从60〜 95重量％的苯乙烯或取代的苯乙烯B21和b22）5至40重量％的至少一种不饱和腈B22，C）1至97.5重量％的至少一种由c1）制成的热塑性共聚物C 60至85重量％的苯乙烯或取代的苯乙烯或其混合物，c2）15至40重量％的至少一种不饱和腈C2，D）0.5至50重量％的至少一种共聚物D， 可通过d1）5至95重量％的至少一种含至少一种选自以下的官能团的热塑性甲基丙烯酸酯聚合物D1 环氧基，羧基，羟基，酸酐和恶唑啉，d2）5至95重量％的至少一种热塑性聚酯D2，E）0至40重量％的至少一种填料E，F）0至 2重量％的至少一种有机酸F，G）0至25重量％的至少一种无卤素磷化合物G，H）0至45重量％的其它添加剂H.

    Polycarbonate styrene copolymer blends with improved properties
    2.
    发明申请
    Polycarbonate styrene copolymer blends with improved properties 失效
    具有改进性能的聚碳酸酯苯乙烯共聚物共混

    公开(公告)号：US20050159546A1

    公开(公告)日：2005-07-21

    申请号：US10510478

    申请日：2003-04-08

    申请人： Martin Weber ,  Xaver Hopfenspirger ,  Reinhard Jakobi ,  Walter Heckmann

    发明人： Martin Weber ,  Xaver Hopfenspirger ,  Reinhard Jakobi ,  Walter Heckmann

    IPC分类号： C08F265/04 ,  C08L25/12 ,  C08L51/04 ,  C08L55/02 ,  C08L69/00 ,  C08L51/00

    CPC分类号： C08L55/02 ,  C08F265/04 ,  C08L25/12 ,  C08L51/04 ,  C08L69/00 ,  C08L2205/035 ,  C08L2666/02 ,  C08L2666/14 ,  C08L2666/04

    摘要： The invention relates to thermoplastic moulding materials containing the components A, B, C and D, in addition to optional components E, F, G and H, said components being composed as follows: A) between 1 and 97.5 wt. % of at least one aromatic polycarbonate A; B) between 1 and 97.5 wt. % of at least one graft polymer B consisting of b1) between 40 and 80 wt. % of a graft base obtained from a rubber elastic polymer B1, b2) between 20 and 60 wt. % of a graft support B2 consisting of b21) between 60 and 95 wt. % styrene or substituted styrenes B21 and b22) between 5 and 40 wt. % of at least one unsaturated nitrile B22; C) between 1 and 97.5 wt. % of at least one thermoplastic copolymer C consisting of c1) between 60 and 85 wt. % styrene or substituted styrenes C1 or mixtures thereof and c2) between 15 and 40 wt. % of at least one unsaturated nitrile C2; D) between 0.5 and 50 wt. % of at least one copolymer D, obtained by reacting d1) between 5 and 95 wt % of at least one thermoplastic methacrylate polymer D1 containing at least one type of functional group, selected from epoxy, carboxyl, hydroxyl, anhydride and oxazoline, with d2) between 5 and 95 wt. % of at least one thermoplastic polyester D2; E) between 0 and 40 wt. % of at least one filler E; F) between 0 and 2 wt. % of at least one organic acid F; G) between 0 and 25 wt. % of at least one phosphorus compound G that is devoid of halogen; H) between 0 and 45 wt. % of additional additives H.

    摘要翻译： 本发明涉及除了任选的组分E，F，G和H之外，还含有组分A，B，C和D的热塑性模塑材料，所述组分如下组成：A）1至97.5wt。 ％的至少一种芳族聚碳酸酯A; B）1〜97.5重量％ ％的至少一种接枝聚合物B，其由b1）40至80wt。 从橡胶弹性聚合物B1获得的接枝基质的％，b2）为20〜60重量％ ％由b21组成的接枝支撑物B2的60至95重量％ ％苯乙烯或取代的苯乙烯B21和b22）为5〜40wt。 ％至少一种不饱和腈B22; C）1至97.5wt。 ％的至少一种由c1）组成的热塑性共聚物C为60至85重量％ ％苯乙烯或取代苯乙烯C1或其混合物，和c2）15至40wt。 ％的至少一种不饱和腈C2; D）0.5〜50wt。 ％的至少一种共聚物D，通过使d1）5至95重量％的至少一种含有至少一种选自环氧，羧基，羟基，酸酐和恶唑啉的官能团的至少一种热塑性甲基丙烯酸酯聚合物D1与d2反应获得，其中d2 ）在5和95重量％之间。 ％的至少一种热塑性聚酯D2; E）0〜40wt。 ％至少一种填料E; F）0至2wt。 ％至少一种有机酸F; G）0至25wt。 ％的至少一种不含卤素的磷化合物G; H）0至45wt。 ％的其他添加剂

    THERMOPLASTIC MOULDING COMPOSITIONS WITH HIGH STIFFNESS
    3.
    发明申请
    THERMOPLASTIC MOULDING COMPOSITIONS WITH HIGH STIFFNESS 有权
    具有高硬度的热塑性成型组合物

    公开(公告)号：US20100019210A1

    公开(公告)日：2010-01-28

    申请号：US12374954

    申请日：2007-07-17

    申请人： Martin Weber ,  Xaver Hopfenspirger ,  Steffen Funkhauser ,  Walter Heckmann ,  Jörg Schnorr

    发明人： Martin Weber ,  Xaver Hopfenspirger ,  Steffen Funkhauser ,  Walter Heckmann ,  Jörg Schnorr

    IPC分类号： H01B1/24 ,  H01B1/20

    CPC分类号： C08L77/00 ,  C08L51/06 ,  C08L77/06 ,  C08L2666/24

    摘要： Thermoplastic molding compositions comprising A) from 40 to 96.2% by weight of a semiaromatic polyamide, B) from 2 to 30% by weight of an impact-modifying polymer which comprises functional groups, C) from 1 to 50% by weight of fibrous or particulate fillers or a mixture of these, D) from 0.2 to 5% by weight of a lubricant, E) from 0.5 to 15% by weight of an electrically conductive additive, F) from 0 to 30% by weight of other added materials, where the total of the percentages by weight of components A) to F) is 100%.

    摘要翻译： 包含A）40至96.2重量％的半芳族聚酰胺B）2至30重量％的包含官能团的抗冲改性聚合物，C）1至50重量％的纤维或 颗粒填料或其混合物，D）0.2至5重量％的润滑剂，E）0.5至15重量％的导电添加剂，F）0至30重量％的其它添加材料， 其中组分A）至F）的重量百分比的总和为100％。

    Thermoplastic moulding compositions having improved ductility
    4.
    发明授权
    Thermoplastic moulding compositions having improved ductility 有权
    热塑性成型组合物具有改善的延展性

    公开(公告)号：US08197715B2

    公开(公告)日：2012-06-12

    申请号：US12519674

    申请日：2007-12-11

    申请人： Martin Weber ,  Xaver Hopfenspirger ,  Steffen Funkhauser ,  Walter Heckmann ,  Jörg Schnorr ,  Raquel Fernandez Rodiles ,  Rainer Klenz ,  Hagen Stawitzki ,  Bernd Bruchmann

    发明人： Martin Weber ,  Xaver Hopfenspirger ,  Steffen Funkhauser ,  Walter Heckmann ,  Jörg Schnorr ,  Raquel Fernandez Rodiles ,  Rainer Klenz ,  Hagen Stawitzki ,  Bernd Bruchmann

    IPC分类号： H01B1/06 ,  A61K9/16 ,  C08L31/00 ,  C08L27/00

    CPC分类号： C08L77/06 ,  C08L51/06 ,  C08L67/00 ,  C08L69/00 ,  C08L77/00 ,  C08L2205/03 ,  C08L2666/18 ,  C08L2666/02 ,  C08L2666/24

    摘要： Thermoplastic molding compositions comprising A) from 40 to 96% by weight of a semiaromatic polyamide, B) from 2 to 30% by weight of a copolymer composed of B1) from 35 to 89.9% by weight of ethylene, B2) from 10 to 60% by weight of 1-octene or 1-butene or propylene or a mixture of these, and B3) from 0.05 to 5% by weight of functional monomers, where the functional monomers have been selected from the group of the carboxylic acid groups, carboxylic anhydride groups, carboxylic ester groups, carboxamide groups, carboximide groups, amino groups, hydroxy groups, epoxy groups, urethane groups, or oxazoline groups, or a mixture of these, C) from 1 to 50% by weight of fibrous or particulate fillers, or a mixture of these, D) from 0.1 to 10% by weight of D1) at least one highly branched or hyperbranched polycarbonate with an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, part 2), or D2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, E) from 0 to 15% by weight of an electrically conductive additive, F) from 0 to 30% by weight of further additives, where the total of the percentages by weight of components A) to F) is 100%.

    摘要翻译： 热塑性成型组合物，其包含A）40至96重量％的半芳族聚酰胺，B）2至30重量％的共聚物，由B1组成，35至89.9重量％的乙烯，B2）10至60 重量％的1-辛烯或1-丁烯或丙烯或它们的混合物和B3）0.05至5重量％的官能单体，其中官能单体选自羧酸基团，羧酸基团 酸酐基，羧酸酯基，羧酰胺基，酰亚胺基，氨基，羟基，环氧基，氨基甲酸酯基或恶唑啉基，或它们的混合物，C）1至50重量％的纤维或颗粒填料， 或这些的混合物，D）0.1至10重量％的D1）至少一种高度支化或超支化的聚碳酸酯，其OH数为1至600mg KOH / g聚碳酸酯（根据DIN 53240，第2部分）， 或D2）至少一种高度支化或超支化的AxBy型聚酯，其中x为l 东部1.1，y为至少2.1，或这些的混合物，E）0至15重量％的导电添加剂，F）0至30重量％的其它添加剂，其中通过 组分A）至F）的重量为100％。

    THERMOPLASTIC MOULDING COMPOSITIONS HAVING IMPROVED DUCTILITY
    5.
    发明申请
    THERMOPLASTIC MOULDING COMPOSITIONS HAVING IMPROVED DUCTILITY 有权
    具有改进粘稠度的热塑性成型组合物

    公开(公告)号：US20100090174A1

    公开(公告)日：2010-04-15

    申请号：US12519674

    申请日：2007-12-11

    申请人： Martin Weber ,  Xaver Hopfenspirger ,  Steffen Funkhauser ,  Walter Heckmann ,  Jörg Schnorr ,  Raquel Fernandez Rodiles ,  Rainer Klenz ,  Hagen Stawitzki ,  Bernd Bruchmann

    发明人： Martin Weber ,  Xaver Hopfenspirger ,  Steffen Funkhauser ,  Walter Heckmann ,  Jörg Schnorr ,  Raquel Fernandez Rodiles ,  Rainer Klenz ,  Hagen Stawitzki ,  Bernd Bruchmann

    IPC分类号： H01B1/20 ,  C08L77/00

    CPC分类号： C08L77/06 ,  C08L51/06 ,  C08L67/00 ,  C08L69/00 ,  C08L77/00 ,  C08L2205/03 ,  C08L2666/18 ,  C08L2666/02 ,  C08L2666/24

    摘要： Thermoplastic molding compositions comprising A) from 40 to 96% by weight of a semiaromatic polyamide, B) from 2 to 30% by weight of a copolymer composed of B1) from 35 to 89.9% by weight of ethylene, B2) from 10 to 60% by weight of 1-octene or 1-butene or propylene or a mixture of these, and B3) from 0.05 to 5% by weight of functional monomers, where the functional monomers have been selected from the group of the carboxylic acid groups, carboxylic anhydride groups, carboxylic ester groups, carboxamide groups, carboximide groups, amino groups, hydroxy groups, epoxy groups, urethane groups, or oxazoline groups, or a mixture of these, C) from 1 to 50% by weight of fibrous or particulate fillers, or a mixture of these, D) from 0.1 to 10% by weight of D1) at least one highly branched or hyperbranched polycarbonate with an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, part 2), or D2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, E) from 0 to 15% by weight of an electrically conductive additive, F) from 0 to 30% by weight of further additives, where the total of the percentages by weight of components A) to F) is 100%.

    摘要翻译： 热塑性成型组合物，其包含A）40至96重量％的半芳族聚酰胺，B）2至30重量％的共聚物，由B1组成，35至89.9重量％的乙烯，B2）10至60 重量％的1-辛烯或1-丁烯或丙烯或它们的混合物和B3）0.05至5重量％的官能单体，其中官能单体选自羧酸基团，羧酸基团 酸酐基，羧酸酯基，羧酰胺基，酰亚胺基，氨基，羟基，环氧基，氨基甲酸酯基或恶唑啉基，或它们的混合物，C）1至50重量％的纤维或颗粒填料， 或这些的混合物，D）0.1至10重量％的D1）至少一种高度支化或超支化的聚碳酸酯，其OH数为1至600mg KOH / g聚碳酸酯（根据DIN 53240，第2部分）， 或D2）至少一种高度支化或超支化的AxBy型聚酯，其中x为l 东部1.1，y为至少2.1，或这些的混合物，E）0至15重量％的导电添加剂，F）0至30重量％的其它添加剂，其中通过 组分A）至F）的重量为100％。

    Impact-modified thermoplastic molding compositions based on vinyl aromatic copolymers and polyamide
    10.
    发明授权
    Impact-modified thermoplastic molding compositions based on vinyl aromatic copolymers and polyamide 失效
    基于乙烯基芳族共聚物和聚酰胺的冲击改性热塑性模塑组合物

    公开(公告)号：US07671127B2

    公开(公告)日：2010-03-02

    申请号：US11721261

    申请日：2005-12-03

    申请人： Martin Weber ,  Frank Rittig ,  Werner Haensel ,  Walter Heckmann ,  Hans Hönl ,  Peter Ittemann ,  Bangaru Sampath

    发明人： Martin Weber ,  Frank Rittig ,  Werner Haensel ,  Walter Heckmann ,  Hans Hönl ,  Peter Ittemann ,  Bangaru Sampath

    IPC分类号： C08L51/04

    CPC分类号： C08L77/00 ,  C08L33/00 ,  C08L25/00

    摘要： The invention relates to thermoplastic molding compositions, comprising A) from 35 to 95% by weight of at least one graft copolymer A), which is obtainable via reaction of A1) from 5 to 95% by weight of a polymer A1), which is obtained from at least one dicarboxylic anhydride a11) and from at least one vinylaromatic comonomer a12), and A2) from 5 to 95% by weight of a polyamide A2), B) from 5 to 40% by weight of at least one ungrafted or grafted, non-particulate rubber without core-shell structure B), which has functional groups which can react with the end groups of component A), C) from 0 to 50% by weight of at least one particulate or fibrous filler or particulate or fibrous reinforcing material C), D) from 0 to 60% by weight of at least one copolymer D) composed of vinyl aromatic monomers d1) and of comonomers d2), and E) from 0 to 40% by weight of at least one other additive E), where the entirety of components A) to E) gives 100% by weight, and also to processes for preparation of the thermoplastic molding compositions, to the use of the thermoplastic molding compositions for production of moldings, of foils, of fibers, or of foams, and finally to the moldings, foils, fibers, and foams obtainable from the thermoplastic molding compositions.

    摘要翻译： 本发明涉及热塑性模塑组合物，其包含A）35至95重量％的至少一种接枝共聚物A），其可通过A1）5至95重量％的聚合物A1）的反应获得，其为 由至少一种二羧酸酐a11）和至少一种乙烯基芳族共聚单体a12）和A2）5至95重量％的聚酰胺A2），B）5至40重量％的至少一种未接枝或 接枝的，不含核 - 壳结构的非颗粒橡胶B），其具有可与组分A）的端基反应的官能团，C）0至50重量％的至少一种颗粒或纤维填料或颗粒或 纤维增强材料C），D）0至60重量％的由乙烯基芳族单体d1）和共聚单体d2）组成的至少一种共聚物D），和E）0至40重量％的至少一种其它 添加剂E），其中组分A）至E）的总量为100重量％，以及制备方法o 热塑性模塑组合物，热塑性模塑组合物用于生产模制品，箔，纤维或泡沫塑料的使用，最后是由热塑性模塑组合物获得的模制品，箔，纤维和泡沫。