THERMOPLASTIC MOULDING COMPOSITIONS WITH HIGH STIFFNESS
    1.
    发明申请
    THERMOPLASTIC MOULDING COMPOSITIONS WITH HIGH STIFFNESS 有权
    具有高硬度的热塑性成型组合物

    公开(公告)号:US20100019210A1

    公开(公告)日:2010-01-28

    申请号:US12374954

    申请日:2007-07-17

    IPC分类号: H01B1/24 H01B1/20

    摘要: Thermoplastic molding compositions comprising A) from 40 to 96.2% by weight of a semiaromatic polyamide, B) from 2 to 30% by weight of an impact-modifying polymer which comprises functional groups, C) from 1 to 50% by weight of fibrous or particulate fillers or a mixture of these, D) from 0.2 to 5% by weight of a lubricant, E) from 0.5 to 15% by weight of an electrically conductive additive, F) from 0 to 30% by weight of other added materials, where the total of the percentages by weight of components A) to F) is 100%.

    摘要翻译: 包含A)40至96.2重量%的半芳族聚酰胺B)2至30重量%的包含官能团的抗冲改性聚合物,C)1至50重量%的纤维或 颗粒填料或其混合物,D)0.2至5重量%的润滑剂,E)0.5至15重量%的导电添加剂,F)0至30重量%的其它添加材料, 其中组分A)至F)的重量百分比的总和为100%。

    Thermoplastic moulding compositions having improved ductility
    3.
    发明授权
    Thermoplastic moulding compositions having improved ductility 有权
    热塑性成型组合物具有改善的延展性

    公开(公告)号:US08197715B2

    公开(公告)日:2012-06-12

    申请号:US12519674

    申请日:2007-12-11

    摘要: Thermoplastic molding compositions comprising A) from 40 to 96% by weight of a semiaromatic polyamide, B) from 2 to 30% by weight of a copolymer composed of B1) from 35 to 89.9% by weight of ethylene, B2) from 10 to 60% by weight of 1-octene or 1-butene or propylene or a mixture of these, and B3) from 0.05 to 5% by weight of functional monomers, where the functional monomers have been selected from the group of the carboxylic acid groups, carboxylic anhydride groups, carboxylic ester groups, carboxamide groups, carboximide groups, amino groups, hydroxy groups, epoxy groups, urethane groups, or oxazoline groups, or a mixture of these, C) from 1 to 50% by weight of fibrous or particulate fillers, or a mixture of these, D) from 0.1 to 10% by weight of D1) at least one highly branched or hyperbranched polycarbonate with an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, part 2), or D2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, E) from 0 to 15% by weight of an electrically conductive additive, F) from 0 to 30% by weight of further additives, where the total of the percentages by weight of components A) to F) is 100%.

    摘要翻译: 热塑性成型组合物,其包含A)40至96重量%的半芳族聚酰胺,B)2至30重量%的共聚物,由B1组成,35至89.9重量%的乙烯,B2)10至60 重量%的1-辛烯或1-丁烯或丙烯或它们的混合物和B3)0.05至5重量%的官能单体,其中官能单体选自羧酸基团,羧酸基团 酸酐基,羧酸酯基,羧酰胺基,酰亚胺基,氨基,羟基,环氧基,氨基甲酸酯基或恶唑啉基,或它们的混合物,C)1至50重量%的纤维或颗粒填料, 或这些的混合物,D)0.1至10重量%的D1)至少一种高度支化或超支化的聚碳酸酯,其OH数为1至600mg KOH / g聚碳酸酯(根据DIN 53240,第2部分), 或D2)至少一种高度支化或超支化的AxBy型聚酯,其中x为l 东部1.1,y为至少2.1,或这些的混合物,E)0至15重量%的导电添加剂,F)0至30重量%的其它添加剂,其中通过 组分A)至F)的重量为100%。

    THERMOPLASTIC MOULDING COMPOSITIONS HAVING IMPROVED DUCTILITY
    4.
    发明申请
    THERMOPLASTIC MOULDING COMPOSITIONS HAVING IMPROVED DUCTILITY 有权
    具有改进粘稠度的热塑性成型组合物

    公开(公告)号:US20100090174A1

    公开(公告)日:2010-04-15

    申请号:US12519674

    申请日:2007-12-11

    IPC分类号: H01B1/20 C08L77/00

    摘要: Thermoplastic molding compositions comprising A) from 40 to 96% by weight of a semiaromatic polyamide, B) from 2 to 30% by weight of a copolymer composed of B1) from 35 to 89.9% by weight of ethylene, B2) from 10 to 60% by weight of 1-octene or 1-butene or propylene or a mixture of these, and B3) from 0.05 to 5% by weight of functional monomers, where the functional monomers have been selected from the group of the carboxylic acid groups, carboxylic anhydride groups, carboxylic ester groups, carboxamide groups, carboximide groups, amino groups, hydroxy groups, epoxy groups, urethane groups, or oxazoline groups, or a mixture of these, C) from 1 to 50% by weight of fibrous or particulate fillers, or a mixture of these, D) from 0.1 to 10% by weight of D1) at least one highly branched or hyperbranched polycarbonate with an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, part 2), or D2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, E) from 0 to 15% by weight of an electrically conductive additive, F) from 0 to 30% by weight of further additives, where the total of the percentages by weight of components A) to F) is 100%.

    摘要翻译: 热塑性成型组合物,其包含A)40至96重量%的半芳族聚酰胺,B)2至30重量%的共聚物,由B1组成,35至89.9重量%的乙烯,B2)10至60 重量%的1-辛烯或1-丁烯或丙烯或它们的混合物和B3)0.05至5重量%的官能单体,其中官能单体选自羧酸基团,羧酸基团 酸酐基,羧酸酯基,羧酰胺基,酰亚胺基,氨基,羟基,环氧基,氨基甲酸酯基或恶唑啉基,或它们的混合物,C)1至50重量%的纤维或颗粒填料, 或这些的混合物,D)0.1至10重量%的D1)至少一种高度支化或超支化的聚碳酸酯,其OH数为1至600mg KOH / g聚碳酸酯(根据DIN 53240,第2部分), 或D2)至少一种高度支化或超支化的AxBy型聚酯,其中x为l 东部1.1,y为至少2.1,或这些的混合物,E)0至15重量%的导电添加剂,F)0至30重量%的其它添加剂,其中通过 组分A)至F)的重量为100%。

    Polycarbonate styrene copolymer blends with improved properties
    5.
    发明授权
    Polycarbonate styrene copolymer blends with improved properties 失效
    具有改进性能的聚碳酸酯苯乙烯共聚物共混物

    公开(公告)号:US07265172B2

    公开(公告)日:2007-09-04

    申请号:US10510478

    申请日:2003-04-08

    IPC分类号: C08L69/00 C08L51/04

    摘要: Thermoplastic molding composition comprising components A, B, C and D and, if appropriate, E, F, G and H, A) from 1 to 97.5% by weight of at least one aromatic polycarbonate A, B) from 1 to 97.5% by weight of at least one graft polymer B made from b1) from 40 to 80% by weight of a graft base made from an elastomeric polymer B1, b2) from 20 to 60% by weight of a graft B2 made from b21) from 60 to 95% by weight of styrene or of substituted styrenes B21 and b22) from 5 to 40% by weight of at least one unsaturated nitrile B22, C) from 1 to 97.5% by weight of at least one thermoplastic copolymer C made from c1) from 60 to 85% by weight of styrene or of substituted styrenes C1 or mixtures thereof and c2) from 15 to 40% by weight of at least one unsaturated nitrile C2, D) from 0.5 to 50% by weight of at least one copolymer D, obtainable via reaction of d1) from 5 to 95% by weight of at least one thermoplastic methacrylate polymer D1 containing at least one type of functional groups selected from epoxy, carboxy, hydroxy, anhydride and oxazoline, with d2) from 5 to 95% by weight of at least one thermoplastic polyester D2, E) from 0 to 40% by weight of at least one filler E, F) from 0 to 2% by weight of at least one organic acid F, G) from 0 to 25% by weight of at least one halogen-free phosphorus compound G, H) from 0 to 45% by weight of other additives H.

    摘要翻译: 包含组分A,B,C和D以及如果合适的话,E,F,G和H的热塑性模塑组合物,A)1至97.5重量%的至少一种芳族聚碳酸酯A,B)1至97.5% 由b1)制成的至少一种接枝聚合物B的重量为40〜80重量%的由弹性体聚合物B1制成的接枝基料,b2)20〜60重量%的由b21制得的接枝体B2从60〜 95重量%的苯乙烯或取代的苯乙烯B21和b22)5至40重量%的至少一种不饱和腈B22,C)1至97.5重量%的至少一种由c1)制成的热塑性共聚物C 60至85重量%的苯乙烯或取代的苯乙烯或其混合物,c2)15至40重量%的至少一种不饱和腈C2,D)0.5至50重量%的至少一种共聚物D, 可通过d1)5至95重量%的至少一种含至少一种选自以下的官能团的热塑性甲基丙烯酸酯聚合物D1 环氧基,羧基,羟基,酸酐和恶唑啉,d2)5至95重量%的至少一种热塑性聚酯D2,E)0至40重量%的至少一种填料E,F)0至 2重量%的至少一种有机酸F,G)0至25重量%的至少一种无卤素磷化合物G,H)0至45重量%的其它添加剂H.

    Polycarbonate styrene copolymer blends with improved properties
    6.
    发明申请
    Polycarbonate styrene copolymer blends with improved properties 失效
    具有改进性能的聚碳酸酯苯乙烯共聚物共混

    公开(公告)号:US20050159546A1

    公开(公告)日:2005-07-21

    申请号:US10510478

    申请日:2003-04-08

    摘要: The invention relates to thermoplastic moulding materials containing the components A, B, C and D, in addition to optional components E, F, G and H, said components being composed as follows: A) between 1 and 97.5 wt. % of at least one aromatic polycarbonate A; B) between 1 and 97.5 wt. % of at least one graft polymer B consisting of b1) between 40 and 80 wt. % of a graft base obtained from a rubber elastic polymer B1, b2) between 20 and 60 wt. % of a graft support B2 consisting of b21) between 60 and 95 wt. % styrene or substituted styrenes B21 and b22) between 5 and 40 wt. % of at least one unsaturated nitrile B22; C) between 1 and 97.5 wt. % of at least one thermoplastic copolymer C consisting of c1) between 60 and 85 wt. % styrene or substituted styrenes C1 or mixtures thereof and c2) between 15 and 40 wt. % of at least one unsaturated nitrile C2; D) between 0.5 and 50 wt. % of at least one copolymer D, obtained by reacting d1) between 5 and 95 wt % of at least one thermoplastic methacrylate polymer D1 containing at least one type of functional group, selected from epoxy, carboxyl, hydroxyl, anhydride and oxazoline, with d2) between 5 and 95 wt. % of at least one thermoplastic polyester D2; E) between 0 and 40 wt. % of at least one filler E; F) between 0 and 2 wt. % of at least one organic acid F; G) between 0 and 25 wt. % of at least one phosphorus compound G that is devoid of halogen; H) between 0 and 45 wt. % of additional additives H.

    摘要翻译: 本发明涉及除了任选的组分E,F,G和H之外,还含有组分A,B,C和D的热塑性模塑材料,所述组分如下组成:A)1至97.5wt。 %的至少一种芳族聚碳酸酯A; B)1〜97.5重量% %的至少一种接枝聚合物B,其由b1)40至80wt。 从橡胶弹性聚合物B1获得的接枝基质的%,b2)为20〜60重量% %由b21组成的接枝支撑物B2的60至95重量% %苯乙烯或取代的苯乙烯B21和b22)为5〜40wt。 %至少一种不饱和腈B22; C)1至97.5wt。 %的至少一种由c1)组成的热塑性共聚物C为60至85重量% %苯乙烯或取代苯乙烯C1或其混合物,和c2)15至40wt。 %的至少一种不饱和腈C2; D)0.5〜50wt。 %的至少一种共聚物D,通过使d1)5至95重量%的至少一种含有至少一种选自环氧,羧基,羟基,酸酐和恶唑啉的官能团的至少一种热塑性甲基丙烯酸酯聚合物D1与d2反应获得,其中d2 )在5和95重量%之间。 %的至少一种热塑性聚酯D2; E)0〜40wt。 %至少一种填料E; F)0至2wt。 %至少一种有机酸F; G)0至25wt。 %的至少一种不含卤素的磷化合物G; H)0至45wt。 %的其他添加剂

    Thermoplastic Molding Materials Based on Polyesters and Styrene Copolymers
    7.
    发明申请
    Thermoplastic Molding Materials Based on Polyesters and Styrene Copolymers 有权
    基于聚酯和苯乙烯共聚物的热塑性成型材料

    公开(公告)号:US20080227920A1

    公开(公告)日:2008-09-18

    申请号:US11997797

    申请日:2006-07-31

    IPC分类号: C08F265/04

    摘要: Thermoplastic molding compositions, comprising A) from 10 to 97.5% by weight of at least one thermoplastic polyester A, B) from 1 to 97.5% by weight of at least one graft polymer B composed of b1) from 40 to 80% by weight of a graft base composed of an elastomeric polymer B1 based on alkyl acrylates having from 1 to 8 carbon atoms in the alkyl radical, on ethylene/propylene, on dienes, or on siloxanes, and with a glass transition temperature below 0° C., b2) from 20 to 60% by weight of a graft B2 composed of b21) from 60 to 95% by weight of styrene or of substituted styrenes B21 of the general formula I  where R is a C1-8-alkyl radical or hydrogen and R1 is a C1-8-alkyl radical and n is 1, 2, or 3, or a mixture of these, and b22) from 5 to 40% by weight of at least one unsaturated nitrile B22, C) from 1 to 97.5% by weight of at least one thermoplastic copolymer C composed of c1) from 60 to 85% by weight of styrene or of substituted styrenes C1 of the general formula 1, or a mixture thereof, and c2) from 15 to 40% by weight of at least one unsaturated nitrile C2, D) from 0.5 to 50% by weight of at least one copolymer D, obtainable via reaction of d1) from 5 to 95% by weight of at least one thermoplastic methacrylate polymer D1 comprising at least one type of functional groups, selected from epoxy, carboxy, hydroxy, anhydride, and oxazoline, with d2) from 5 to 95% by weight of at least one thermoplastic polyester D2, E) from 0 to 40% by weight of at least one filler E, F) from 0 to 2% by weight of at least one organic acid F, G) from 0 to 25% by weight of at least one halogen-free phosphorus compound G, H) from 0 to 45% by weight of other additives H, where the entirety of components A to H always gives 100%.

    摘要翻译: 热塑性成型组合物,其包含A)10至97.5重量%的至少一种热塑性聚酯A,B)1至97.5重量%的至少一种接枝聚合物B,其由以下组分组成:b1)40至80重量% 由基于丙烯酸烷基酯在烷基上具有1至8个碳原子的烷基丙烯酸酯,乙烯/丙烯,二烯或硅氧烷上的玻璃化转变温度低于0℃的弹性体聚合物B1,b2 )20〜60重量%的由b21组成的接枝物B2)60〜95重量%的苯乙烯或通式I的取代苯乙烯B21,其中R为C 1-8烷基, - 烷基或氢,R 1是C 1-8 - 烷基,n是1,2或3,或它们的混合物,和b22) 5至40重量%的至少一种不饱和腈B22,C)1至97.5重量%的至少一种由c1组成的热塑性共聚物C,60至85重量%的苯乙烯或取代苯乙烯的C1 ge 1)或其混合物,c2)15-40%(重量)的至少一种不饱和腈C2,D)0.5-50%重量的至少一种共聚物D,可通过d1) 5至95重量%的至少一种包含至少一种选自环氧基,羧基,羟基,酸酐和恶唑啉的官能团的热塑性甲基丙烯酸酯聚合物D1,其中d2)5至95重量%的至少一种 热塑性聚酯D2,E)0至40重量%的至少一种填料E,F)0至2重量%的至少一种有机酸F,G)0至25重量%的至少一种 无卤磷化合物G,H)0〜45重量%的其他添加剂H,其中组分A至H的总量总是给出100%。

    Polycarbonate moulding materials
    8.
    发明授权
    Polycarbonate moulding materials 失效
    聚碳酸酯成型材料

    公开(公告)号:US06423767B1

    公开(公告)日:2002-07-23

    申请号:US09555597

    申请日:2000-05-31

    IPC分类号: C08K5092

    摘要: A) at least one polycarbonate, B) at least one graft polymer based on an elastomer having a glass transition point below 10° C., C) at least one copolymer containing vinylaromatic monomers, D) at least one filler, E) at least one low molecular weight halogen-free acid and, if desired, additionally F) at least one polyalkyl acrylate and G) at least one flame retardant and H) at least one additive, and which are characterized by the fact that they contain I) at least one aromatic or partially aromatic polyester or a mixture thereof. Shaped articles, films or fibers, particularly external autobody parts, made of said molding compositions.

    摘要翻译: A)至少一种聚碳酸酯,B)至少一种基于玻璃化转变点低于10℃的弹性体的接枝聚合物,C)至少一种含有乙烯基芳族单体的共聚物,D)至少一种填料,E)至少 一种低分子量无卤酸,如果需要另外F)至少一种丙烯酸烷基酯和G)至少一种阻燃剂和H)至少一种添加剂,其特征在于它们包含I)至少一种芳族或部分 芳族聚酯或其混合物。由所述模塑组合物制成的成型制品,膜或纤维,特别是外部自身体部分。

    Thermoplastic molding materials based on polyesters and styrene copolymers
    9.
    发明授权
    Thermoplastic molding materials based on polyesters and styrene copolymers 有权
    基于聚酯和苯乙烯共聚物的热塑性成型材料

    公开(公告)号:US07863377B2

    公开(公告)日:2011-01-04

    申请号:US11997797

    申请日:2006-07-31

    摘要: Thermoplastic molding compositions, comprising A) at least one thermoplastic polyester A, B) at least one graft polymer B of b1) a graft base of an elastomeric polymer B1 based on alkyl acrylates, ethylene/propylene, dienes, or on siloxanes, and with a glass transition temperature below 0° C., b2) a graft B2 composed of b21) styrene or of substituted styrenes B21 of formula I  where R is alkyl or hydrogen and R1 is alkyl radical and n is 1, 2, or 3, or mixture, and b22) at least one unsaturated nitrile B22, C) at least one thermoplastic copolymer C of c1) styrene and/or of substituted styrenes C1 of formula I, and c2) at least one unsaturated nitrile C2, D) at least one copolymer D, obtainable via reaction of d1) at least one thermoplastic methacrylate polymer D1 comprising at least one of epoxy, carboxy, hydroxy, anhydride, or oxazoline, with d2) at least one thermoplastic polyester D2.

    摘要翻译: 热塑性模塑组合物,包括A)至少一种热塑性聚酯A,B)至少一种接枝聚合物B,b1)基于丙烯酸烷基酯,乙烯/丙烯,二烯或硅氧烷的弹性体聚合物B1的接枝基, 玻璃化转变温度低于0℃,b2)由b21)苯乙烯或式I的取代苯乙烯B21构成的接枝B2,其中R是烷基或氢,R1是烷基,n是1,2或3,或 混合物和b22)至少一种不饱和腈B22,C)c1)苯乙烯和/或式I的取代苯乙烯C1的至少一种热塑性共聚物C,和c2)至少一种不饱和腈C2,D)至少一种 共聚物D,其通过d1)至少一种包含环氧基,羧基,羟基,酸酐或恶唑啉中的至少一种的热塑性甲基丙烯酸酯聚合物D1与d2)至少一种热塑性聚酯D2反应获得。