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公开(公告)号：US4403091A
公开(公告)日：1983-09-06
申请号：US425754
申请日：1982-09-28
IPC分类号： C08G18/10 , C08G18/32 , C09D175/04 , C08G63/44 , C08G69/44
CPC分类号： C08G18/10 , C08G18/3221 , C09D175/04
摘要： Ungelled hydroxyl-containing oligomers and their method of preparation are disclosed. The oligomers can be prepared by reacting an organic isocyanate with a half-ester formed from reacting a polyol with a 1,2-dicarboxylic acid anhydride followed by reaction with an epoxide. The oligomers are useful as resinous binders in high solids coating compositions. The coating compositions can be applied by spraying and do not result in a tacky overspray common with many high solids coating compositions.
摘要翻译： 公开了未凝胶的含羟基低聚物及其制备方法。 低聚物可以通过使有机异氰酸酯与由多元醇与1,2-二羧酸酐反应形成的半酯反应，随后与环氧化物反应而制备。 低聚物可用作高固体涂料组合物中的树脂粘合剂。 涂料组合物可以通过喷涂施用，并且不会导致许多高固体涂料组合物常见的粘性过度喷涂。
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公开(公告)号：US4403093A
公开(公告)日：1983-09-06
申请号：US425759
申请日：1982-09-28
CPC分类号： C08G18/3221 , C08G18/4294 , C08G18/6407 , C08G63/42
摘要： Ungelled polyester oligomers which are formed from reacting polyols, 1,2-dicarboxylic acid anhydrides and polyepoxides are disclosed. The polyesters are useful as resinous binders in high solids coating compositions. The coating compositions can be applied by spraying and do not result in a tacky overspray common with many high solids coating compositions.
摘要翻译： 公开了由多元醇，1,2-二羧酸酐和聚环氧化物反应形成的未凝胶聚酯低聚物。 聚酯可用作高固含量涂料组合物中的树脂粘合剂。 涂料组合物可以通过喷涂施用，并且不会导致许多高固体涂料组合物常见的粘性过度喷涂。
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3.发明授权Color plus clear coating method utilizing addition interpolymers containing alkoxy silane and/or acyloxy silane groups 失效使用含有烷氧基硅烷和/或酰氧基硅烷基团的加成互聚物的颜色加透明涂布方法
公开(公告)号：US4499151A
公开(公告)日：1985-02-12
申请号：US529469
申请日：1983-09-06
申请人： Rostyslaw Dowbenko , Raymond S. Stewart , Marvis E. Hartman , Barbara Gorman , Stephen J. Thomas
发明人： Rostyslaw Dowbenko , Raymond S. Stewart , Marvis E. Hartman , Barbara Gorman , Stephen J. Thomas
CPC分类号： B05D7/532 , B05D5/068 , Y10T428/31663
摘要： Disclosed is a method for coating a substrate comprising the steps of (a) forming a basecoat by coating the substrate with a pigmented basecoating composition; and (b) thereafter forming a topcoat by coating the basecoat with a clear topcoating composition; wherein at least one of the basecoating composition and topcoating composition contains an addition interpolymer having alkoxysilane and/or acyloxysilane moieties.
摘要翻译： 公开了一种涂布基材的方法，包括以下步骤：（a）通过用着色的底漆组合物涂布基材来形成底涂层; 和（b）然后通过用透明的表面涂层组合物涂覆底涂层形成面漆; 其中所述底漆组合物和表面涂层组合物中的至少一种含有具有烷氧基硅烷和/或酰氧基硅烷部分的加成互聚物。
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公开(公告)号：US4171413A
公开(公告)日：1979-10-16
申请号：US821686
申请日：1977-08-04
IPC分类号： C08F8/30
CPC分类号： C08F8/30 , C08F2800/20
摘要： Non-gelled acrylic-hydrazide resins are prepared by reacting hydrazine with a non-gelled acrylic polymer containing a functional group reactive with hydrazine to cause hydrazide formation.
摘要翻译： 非胶凝丙烯酸酰肼树脂通过肼与含有与肼反应的官能团的非凝胶型丙烯酸聚合物反应以制备酰肼来制备。
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5.发明授权Coating compositions composed of hydroxyfunctional polymers or copolymers and alkoxysilanes 失效由羟基官能聚合物或共聚物和烷氧基硅烷组成的涂料组合物
公开(公告)号：US4093673A
公开(公告)日：1978-06-06
申请号：US523781
申请日：1974-11-14
CPC分类号： C08G18/837 , C08K5/54 , C09D133/14
摘要： Resinous compositions useful as coating compositions comprise blends of hydroxyfunctional polymers; organoalkoxy silane crosslinking agents represented by the formula: R.sub.n Si(OR').sub.4-n wherein R is an aryl, alkaryl, aralkyl, alkyl having 1 to 8 carbon atoms, XR .sub.4 -- or ##STR1## RADICAL, WHEREIN R.sub.1 is hydrogen or an alkyl radical of 1 to 6 carbon atoms, R.sub.2 is a member selected from the group consisting of alkylene radicals of 1 to 7 carbon atoms and carbonyloxy radicals represented by the formula: ##STR2## wherein R.sub.3 is an alkylene radical of 1 to 6 carbon atoms, wherein R.sub.4 is an alkylene radical of 1 to 6 carbon atoms, a cycloalkylene radical, or an arylene radical and X is a functional group selected from the group consisting of --OH, --SH, ##STR3## halogen, NH.sub.2 --, ##STR4## and NH.sub.2 --CH.sub.2 --CH.sub.2 --NH--, and wherein R' is methyl, ethyl, 2-methoxyethoxy, 2-ethoxyethoxy, m is 0 or 1 and n is 0, 1 or 2; and cure accelerating catalysts. Hydroxyfunctional polymers such as hydroxyfunctional acrylic polymers, polyesters and polyurethanes are particularly useful. Organic acids, metallic salts of organic acids and organic bases are useful cure accelerating catalysts.
摘要翻译： 可用作涂料组合物的树脂组合物包含羟基官能聚合物的共混物; 由下式表示的有机烷氧基硅烷交联剂：
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6.发明授权Reaction products of a polyepoxide with a thiol having a group hydroyzable to carboxyl, and aqueous solubilized products 失效聚环氧化物与具有可水解羧基的硫醇的反应产物和水溶性产物
公开(公告)号：US4029621A
公开(公告)日：1977-06-14
申请号：US680935
申请日：1976-04-28
CPC分类号： C08G59/66 , C08G59/1483 , C08G59/4207
摘要： Aqueous coating compositions which may be applied by conventional coating techniques as well as by electrodeposition are provided by reacting an epoxy-containing organic material with a compound containing a mercaptan group and at least one group hydrolyzable to a carboxyl group. Examples of such hydrolyzable groups include ester groups, amide groups and nitrile groups. The resultant product is then hydrolyzed and solubilized using hydrolyzing agents such as aqueous alkali metal hydroxides and aqueous solutions of various amines.
摘要翻译： 可以通过常规涂布技术和电沉积施用的水性涂料组合物通过使含环氧基的有机材料与含有硫醇基团的化合物和至少一个可水解成羧基的基团反应来提供。 这些可水解基团的实例包括酯基，酰胺基和腈基。 然后使用水解剂如碱金属氢氧化物水溶液和各种胺的水溶液将所得产物水解和溶解。
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7.发明授权Color plus clear coating method utilizing addition interpolymers containing alkoxy silane and/or acyloxy silane groups 失效使用含有烷氧基硅烷和/或酰氧基硅烷基团的加成互聚物的颜色加透明涂布方法
公开(公告)号：US4499150A
公开(公告)日：1985-02-12
申请号：US480152
申请日：1983-03-29
申请人： Rostyslaw Dowbenko , Raymond S. Stewart , Marvis E. Hartman , Barbara Gorman , Stephen J. Thomas
发明人： Rostyslaw Dowbenko , Raymond S. Stewart , Marvis E. Hartman , Barbara Gorman , Stephen J. Thomas
CPC分类号： B05D7/532 , B05D5/068 , Y10T428/31663
摘要： Disclosed is a method for coating a substrate comprising the steps of (a) forming a basecoat by coating the substrate with a pigmented basecoating composition; and (b) thereafter forming a topcoat by coating the basecoat with a clear topcoating composition; wherein at least one of the basecoating composition and topcoating composition contains an addition interpolymer having alkoxysilane and/or acyloxysilane moieties, a peak molecular weight of from about 2,000 to about 20,000, and a calculated glass transition temperature of at least about 25.degree. Celsius.
摘要翻译： 公开了一种涂布基材的方法，包括以下步骤：（a）通过用着色的底漆组合物涂布基材来形成底涂层; 和（b）然后通过用透明的表面涂层组合物涂覆底涂层形成面漆; 其中底涂层组合物和表面涂层组合物中的至少一种含有具有烷氧基硅烷和/或酰氧基硅烷部分的加成互聚物，峰值分子量为约2,000至约20,000，计算出的玻璃化转变温度为至少约25℃。
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公开(公告)号：US4409376A
公开(公告)日：1983-10-11
申请号：US448168
申请日：1982-12-10
IPC分类号： C08G75/04 , C09D4/00 , C09D123/00 , C08G8/28 , C08L61/32
CPC分类号： C07C323/00 , C08G75/045 , C09D4/00
摘要： There are herein provided reaction products of a compound containing an ethylenically unsaturated group and a compound containing at least two reactive groups of varying reactivity. One of the reactive groups such as a mercapto group reacts through the ethylenically unsaturated group. The resulting products are useful as reactive diluents or as film-formers.
摘要翻译： 本文提供了含有烯属不饱和基团的化合物和含有至少两个不同反应活性基团的化合物的反应产物。 反应性基团之一如巯基通过烯属不饱和基团反应。 所得产物可用作反应性稀释剂或成膜剂。
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9.发明授权Ambient temperature, moisture curable coating compositions which form films having excellent gloss 失效环境温度，湿气固化涂料组合物，其形成具有优异光泽度的膜
公开(公告)号：US3997485A
公开(公告)日：1976-12-14
申请号：US549122
申请日：1975-02-11
IPC分类号： C08L51/08 , C09D143/04 , C09D167/08 , C08G63/48 , C08L67/08 , C08L83/10
CPC分类号： C09D143/04 , C09D167/08 , C08L51/08
摘要： An ambient temperature, moisture curable coating composition which dries to form films having excellent gloss characteristics comprises a blend of (1) a silicon-containing acrylic interpolymer; (2) a graft copolymer having an alkyd resin backbone and a polymeric side chain segment of polymerized acrylic and organoalkoxysilane monomers; and (3) a cure accelerating catalyst.
摘要翻译： 干燥以形成具有优异光泽特性的膜的环境温度可湿固化涂料组合物包括（1）含硅丙烯酸互聚物的共混物; （2）具有醇酸树脂主链和聚合的丙烯酸和有机烷氧基硅烷单体的聚合物侧链链段的接枝共聚物; 和（3）固化促进催化剂。
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10.发明授权Coating compositions having improved scratch resistance, coated substrates and methods related thereto 有权涂层组合物具有改进的耐刮擦性，涂覆的基材和与其有关的方法公开(公告)号：US07053149B2
公开(公告)日：2006-05-30
申请号：US10795216
申请日：2004-03-09
申请人： Lawrence G. Anderson , Karen A. Barkac , Shawn A. DeSaw , Marvis E. Hartman , Deborah E. Hayes , Thomas R. Hockswender , Kymarie L. Kuster , Masayuki Nakajima , Kurt G. Olson , Richard J. Sadvary , Dennis A. Simpson , Shiryn Tyebjee , Truman F. Wilt
发明人： Lawrence G. Anderson , Karen A. Barkac , Shawn A. DeSaw , Marvis E. Hartman , Deborah E. Hayes , Thomas R. Hockswender , Kymarie L. Kuster , Masayuki Nakajima , Kurt G. Olson , Richard J. Sadvary , Dennis A. Simpson , Shiryn Tyebjee , Truman F. Wilt
CPC分类号： B82Y30/00 , C08J3/20 , C08K3/01 , C08K3/22 , C08K3/36 , C08K2201/011 , C09D7/00 , C09D7/61 , C09D7/67 , C09D7/68 , C09D7/69 , C09D183/04 , C08L2666/14 , C08L2666/54 , C08L2666/04
摘要： Compositions are provided which contain (a) one or more polysiloxanes comprising at least one reactive functional group; a plurality of particles; and optionally, one or more curing agents comprising at least one functional group that is reactive with any reactive functional group of polysiloxane (a). Additionally, a process for applying the multi-component composite coatings described above to a substrate and coated substrates are provided. A process for preparing the coating compositions also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.
摘要翻译： 提供了包含（a）一种或多种包含至少一个反应性官能团的聚硅氧烷的组合物; 多个颗粒; 和任选的一种或多种包含至少一种与聚硅氧烷（a）的任何反应性官能团反应的官能团的固化剂。 另外，提供了将上述多组分复合涂层施加到基底和涂覆的基底上的方法。 还提供了制备涂料组合物的方法。 本发明的多组分复合涂料组合物提供了耐风化后能够保持耐刮擦性的高耐划伤性的彩色 - 透明涂层。
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