公开(公告)号：US06218482B1

公开(公告)日：2001-04-17

申请号：US09004907

申请日：1998-01-09

申请人： Masahiko Yamanaka ,  Harutomo Nomoto ,  Tomio Nobe ,  Shigeo Takatsuji

发明人： Masahiko Yamanaka ,  Harutomo Nomoto ,  Tomio Nobe ,  Shigeo Takatsuji

IPC分类号： C08F248

CPC分类号： G03F7/038 ,  C08G59/04 ,  C08G59/20 ,  C08G59/3218 ,  C08G59/68 ,  C09D163/00

摘要： An epoxy resin containing group(s) of formula (1) and having a number average molecular weight of 400-10,000, an epoxy equivalent of 100-5,000 and an average number of glycidyl ether groups per molecule of 2-50 wherein A is a group (wherein R3 is a saturated aliphatic polyhydric alcohol residue having 2 to 30 carbon atoms, D is oxyalkylene group, a, b, c and d are 0-25, e and f are 0-4, e+f equals 0-4 and a+b+c×e+d×f equals 0-50), and B is (g, h are 0-18), etc. and R1 and R2 are H, glycidyl or a group of the formula wherein A and B are as defined above, and R7, R8 and R9 are H or glycidyl group; its preparation, and photo-curable and powder coating resin compositions containing the same.

摘要翻译： 包含式（1）基团并且数均分子量为400-10,000，环氧当量为100-5,000的环氧树脂和每分子2-50的缩水甘油醚基团的平均数，其中A为基团 （其中R3是碳原子数2〜30的饱和脂肪族多元醇残基，D为氧化烯基，a，b，c和d为0〜25，e和f分别为0-4，e + f为0-4， a + b + cxe + dxf等于0-50），B为（g，h为0-18）等，R 1和R 2为H，缩水甘油基或一组甲醛和A如上所定义， 并且R 7，R 8和R 9为H或缩水甘油基; 其制备方法和含有该组合物的光固化和粉末涂料树脂组合物。

公开(公告)号：US5034493A

公开(公告)日：1991-07-23

申请号：US450344

申请日：1989-12-13

申请人： Shoji Tani ,  Masahiko Yamanaka ,  Tomio Nobe ,  Shigeo Takatsuji

发明人： Shoji Tani ,  Masahiko Yamanaka ,  Tomio Nobe ,  Shigeo Takatsuji

IPC分类号： C08G59/42 ,  C08G59/68

CPC分类号： C08G59/685 ,  C08G59/42 ,  C08G59/4284

摘要： Disclosed is a curing agent composition for epoxy resin, prepared by mixing together the following components (i), (ii) and (iii) and heating the mixture for modification:(i) at least one organic carboxylic acid zinc salt,(ii) at least one acid anhydride, and(iii) either (a) at least one phenol compound or (b) at least one glycidyl ester or glycidyl ether compound.

摘要翻译： 公开了一种用于环氧树脂的固化剂组合物，其通过将以下组分（i），（ii）和（iii）混合在一起并加热混合物进行改性而制备：（i）至少一种有机羧酸锌盐，（ii） 至少一种酸酐，和（iii）（a）至少一种酚化合物或（b）至少一种缩水甘油酯或缩水甘油醚化合物。

公开(公告)号：US20090131588A1

公开(公告)日：2009-05-21

申请号：US12065383

申请日：2006-08-24

申请人： Kohzo Ito ,  Jun Araki ,  Tatsuya Suzuki ,  Masahiko Yamanaka ,  Kentarou Watanabe

发明人： Kohzo Ito ,  Jun Araki ,  Tatsuya Suzuki ,  Masahiko Yamanaka ,  Kentarou Watanabe

IPC分类号： C08G63/91

CPC分类号： C08B37/0015 ,  C08G83/007

摘要： [Object] To provide a modified hydrophilic polyrotaxane which is soluble in water or a water-like solvent, a cross-linked polyrotaxane using this, and a solvent for dissolving the modified hydrophilic polyrotaxane. [Solving Means] A modified hydrophilic polyrotaxane has a cyclic molecule, a linear molecule including the cyclic molecule with piercing through the cyclic molecule, and blocking groups which are placed at both end terminals of the linear molecule to prevent the cyclic molecule from leaving from the linear molecule. The cyclic molecule is cyclodextrin, and each of all or a part of the hydroxyl groups in the cyclodextrin is modified with a hydrophilic modification group. A cross-linked polyrotaxane is formed by combining this modified hydrophilic polyrotaxane and a polymer through the cyclic molecule.A solvent for dissolving this modified hydrophilic polyrotaxane contains at least one of water and a water-like solvent.

摘要翻译： 本发明提供可溶于水或水溶性溶剂的改性亲水性聚轮烷，使用其的交联聚轮烷和溶解改性亲水性聚轮烷的溶剂。 [解决方案]改性亲水性聚轮烷具有环状分子，包含穿过环状分子的环状分子的直链状分子，以及位于直链状分子的两端末端的阻断基，以防止环状分子离开 线性分子。 环状分子是环糊精，并且环糊精中的全部或一部分羟基中的每一个都用亲水性改性基团修饰。 通过将该改性的亲水性聚轮烷与通过环状分子的聚合物结合而形成交联聚轮烷。 用于溶解该改性亲水性聚轮烷的溶剂含有水和水状溶剂中的至少一种。

公开(公告)号：US20050214549A1

公开(公告)日：2005-09-29

申请号：US10637870

申请日：2003-08-08

申请人： Tatsuya Ishihara ,  Masahiko Yamanaka ,  Tetsuji Mizuno ,  Takashi Moriwake ,  Hisaki Tanabe ,  Goro Nagao

发明人： Tatsuya Ishihara ,  Masahiko Yamanaka ,  Tetsuji Mizuno ,  Takashi Moriwake ,  Hisaki Tanabe ,  Goro Nagao

IPC分类号： B05D7/00 ,  C09D7/12 ,  B32B25/20

CPC分类号： B05D7/532 ,  C09D7/65 ,  Y10T428/31663

摘要： It is an object of the invention to provide a clear coating composition, which can give coating films showing good water repellency, in other words a factor giving a care-free and deluxe feeling to car owners, and which are excellent in non-sanding recoating dirtied coatings after due repair, as well as a method of forming a coating film and a multilayered coating film. The invention provides a clear coating composition which comprises (A) 100 parts by mass of the sum of a crosslinkable coating film-forming resin and a crosslinking agent on a solid basis and (B) 0.01 to 2 parts by mass of a ladder silicone copolymer obtainable by copolymerizing (b-1) a (meth)acryloxyalkyl-containing ladder silicone oligomer, (b-2) a crosslinkable functional group-containing ethylenically unsaturated monomer and optionally (b-3) another ethylenically unsaturated monomer.

摘要翻译： 本发明的目的是提供一种透明的涂料组合物，其可以赋予具有良好防水性的涂膜，换句话说，对汽车所有者给予无忧和豪华的感觉的因素，并且非着色重涂 正确修复后的污垢涂层，以及形成涂膜和多层涂膜的方法。 本发明提供了一种透明的涂料组合物，其包含（A）100质量份的可交联成膜树脂和交联剂的总量为固体，（B）0.01〜2质量份梯状硅氧烷共聚物 可通过（b-1）含（甲基）丙烯酰氧基烷基的梯状硅氧烷低聚物，（b-2）含交联性官能团的烯属不饱和单体和任选的（b-3）另外的烯键式不饱和单体共聚得到。

公开(公告)号：US06577446B2

公开(公告)日：2003-06-10

申请号：US09870727

申请日：2001-06-01

申请人： Kinya Kumazawa ,  Hiroshi Tabata ,  Masahiko Yamanaka ,  Toshihiko Sada

发明人： Kinya Kumazawa ,  Hiroshi Tabata ,  Masahiko Yamanaka ,  Toshihiko Sada

IPC分类号： G02B110

CPC分类号： B32B7/02 ,  Y10T428/24901

摘要： A coloring structure includes a light-reflecting base, a brilliant layer placed on the base, and transparent brilliant units contained in the brilliant layer, each brilliant unit including an alternate lamination of at least two polymers having different refractive indexes, the lamination producing interfered light resulting from reflection and interference of light and transmitted light resulting from transmission of light, each brilliant unit controlling interfered and transmitted lights. The coloring structure is provided with a coloring mechanism for producing at least an interference color resulting from interfered light, a first object color resulting from reflection of transmitted light produced by the base, and a second object color resulting from reflection of incident light produced by the base without striking any brilliant units.

摘要翻译： 着色结构包括光反射基体，放置在基底上的辉光层和包含在亮晶层中的透明辉光单元，每个亮晶单元包括具有不同折射率的至少两种聚合物的交替叠层，层压产生受干扰的光 由于光的反射和干扰以及由透射光产生的透射光，每个辉煌的单元控制干涉和透射的光。 着色结构设置有着色机构，用于产生至少由干涉光产生的干涉色，由基底产生的透射光的反射产生的第一物体颜色和由反射光产生的入射光的反射产生的第二物体颜色 基地没有任何辉煌的单位。

公开(公告)号：US5102944A

公开(公告)日：1992-04-07

申请号：US515060

申请日：1990-04-26

申请人： Hiroyoshi Ohmika ,  Masahiko Yamanaka ,  Masashi Ohno

发明人： Hiroyoshi Ohmika ,  Masahiko Yamanaka ,  Masashi Ohno

IPC分类号： C08J7/04 ,  C09D123/26 ,  C09D151/00 ,  C09D151/04 ,  C09D151/06

CPC分类号： C09D151/04 ,  C09D151/003 ,  C09D151/06

摘要： An aqueous primer composition for use in applying to polyolefin resin substrates which is excellent in adhesiveness to polyolefin resin substrates, water resistance and gasoline resistance and which is free from the problems of fire and environments pollution. The primer composition comprises a resin component (a) of 100 parts by weight of modified polyolefin which is prepared by modifying polyolefin with an .alpha., .beta.-unsaturated carboxylic acids and which contains 0.05 to 0.5 equivalent of free carboxylic acid groups per 100 g, with the other resin component (b) of 5 to 500 parts by weight of modified resin having both ethylenically unsaturated double bonds and free carboxylic acid groups, which modified resin is prepared by adding an .alpha., .beta.-unsaturated dicarboxylic anhydride to a drying oil or a conjugated diene polymer or conjugated diene copolymer and then opening the ring of the acid anhydride group; and is prepared by neutralizing at least a part of free carboxylic acid groups of said modified polyolefin of component (a) and/or said modified resin of component (b) with a base and then dissolving or dispersing them in water.

公开(公告)号：US08007911B2

公开(公告)日：2011-08-30

申请号：US12083099

申请日：2006-10-05

申请人： Kohzo Ito ,  Jun Araki ,  Tatsuya Suzuki ,  Masahiko Yamanaka ,  Kentarou Watanabe

发明人： Kohzo Ito ,  Jun Araki ,  Tatsuya Suzuki ,  Masahiko Yamanaka ,  Kentarou Watanabe

IPC分类号： C08B37/16

CPC分类号： C09D105/16 ,  B05D7/53 ,  B05D7/57 ,  C08B37/0015 ,  C08G83/007 ,  Y10T428/31511 ,  Y10T428/31786 ,  Y10T428/31935 ,  Y10T428/31971

摘要： To provide a coating material for a room temperature curable solvent-borne overcoating material having chipping resistance and not allowing occurrence of cracks, and a room temperature curable solvent-borne overcoating material using the same, the room temperature curable solvent-borne overcoating material being excellent in abrasion resistance and in performance such as weather resistance, contamination resistance and adhesion.A coating material is formed of a lipophilic polyrotaxane including a cyclic molecule, a linear molecule piercing through the cyclic molecule to include it, and blocking groups disposed at both end terminals of the linear molecule to prevent departure of the cyclic molecule. In the lipophilic polyrotaxane, at least one of the linear molecule and the cyclic molecule has a hydrophobic modification group. A room temperature curable solvent-borne overcoating material is formed to contain the coating material preferably within a range of from 60 to 100% by mass relative to a film-forming component.

摘要翻译： 为了提供具有耐崩裂性并且不产生裂纹的室温可固化溶剂型外涂层材料的涂料和使用其的室温固化型溶剂型外涂层材料，室温固化型溶剂型外涂层材料是优异的 耐磨性和耐候性，耐污染性和附着性等性能。 涂层材料由包括环状分子的亲脂性聚轮烷，穿过环状分子的直链状分子包括在内的亲油性聚轮烷，以及设置在该直链状分子两端的封闭基团形成，以防止环状分子脱离。 在亲油性聚轮烷中，直链状分子和环状分子中的至少一种具有疏水性改性基团。 形成室温固化型溶剂型外涂层材料，以相对于成膜成分优选为60〜100质量％的范围。

公开(公告)号：US07893168B2

公开(公告)日：2011-02-22

申请号：US12065368

申请日：2006-08-23

申请人： Kohzo Ito ,  Jun Araki ,  Tatsuya Suzuki ,  Masahiko Yamanaka ,  Kentarou Watanabe

发明人： Kohzo Ito ,  Jun Araki ,  Tatsuya Suzuki ,  Masahiko Yamanaka ,  Kentarou Watanabe

IPC分类号： C08F283/02

CPC分类号： C08G83/007 ,  C08B37/0015 ,  C08G65/20 ,  C08G65/331 ,  C08L71/02 ,  C08L2666/26

摘要： To provide a hydrophobic linear polyrotaxane molecule which is soluble in an organic solvent, and a crosslinked polyrotaxane using the same.A hydrophobic linear polyrotaxane molecule has a cyclic molecule, a linear molecule including the cyclic molecule with piercing through the cyclic molecule, and blocking groups placed at both end terminals of the linear molecule to prevent the cyclic molecule from leaving from the linear molecule. The linear molecule is hydrophobic. The linear molecule is polycaprolactone and has a molecular weight ranging from 5,000 to 100,000. The cyclic molecule is α-cyclodextrin, β-cyclodextrin or γ-cyclodextrin.A crosslinked polyrotaxane is formed by combining the hydrophobic linear polyrotaxane molecule and a polymer through the cyclic molecule.

摘要翻译： 提供可溶于有机溶剂的疏水性线性聚轮烷分子和使用其的交联聚轮烷。 疏水性线性聚轮烷分子具有环状分子，包括穿过环状分子的环状分子的直链状分子，以及配置在线性分子的两端末端的阻断基，以防止环状分子离开线性分子。 线性分子是疏水性的。 线性分子是聚己内酯，分子量为5,000至100,000。 环状分子是α-环糊精，β-环糊精或γ-环糊精。 交联聚轮烷通过环状分子结合疏水性线性聚轮烷分子和聚合物而形成。

公开(公告)号：US20100159278A1

公开(公告)日：2010-06-24

申请号：US12089325

申请日：2006-10-05

申请人： Kohzo Ito ,  Jun Araki ,  Tatsuya Suzuki ,  Masahiko Yamanaka ,  Kentarou Watanabe

发明人： Kohzo Ito ,  Jun Araki ,  Tatsuya Suzuki ,  Masahiko Yamanaka ,  Kentarou Watanabe

IPC分类号： B32B27/00 ,  C09D179/00

CPC分类号： C08G83/007 ,  B05D7/14 ,  B05D7/57 ,  B05D2202/10 ,  C08B37/0015 ,  C09D105/16

摘要： There is provided a room-temperature drying aqueous overcoating medium containing 1 to 100 mass % of hydrophilic polyrotaxane with respect to the coating film forming component, where the hydrophilic polyrotaxane has a cyclic molecule, a linear molecule included in the cyclic molecule in a skewered manner and blocking groups arranged on opposite ends of the linear molecule to prevent elimination of the cyclic molecule from the linear molecule and at least one of the linear molecule and the cyclic molecule has a hydrophilic modifying group.

摘要翻译： 提供了相对于涂膜形成成分含有1〜100质量％的亲水性聚轮烷的室温干燥水性外涂层介质，其中亲水性聚轮烷具有环状分子，以串列方式包含在环状分子中的直链状分子 以及排列在所述线性分子的相对端上的阻断基团，以防止所述环状分子从所述线性分子中消除，并且所述直链状分子和所述环状分子中的至少一种具有亲水性改性基团。

公开(公告)号：US20060084100A1

公开(公告)日：2006-04-20

申请号：US11239465

申请日：2005-09-30

申请人： Hiroshi Yokoyama ,  Masahiko Yamanaka ,  Kentarou Watanabe ,  Tsunehiko Higuchi ,  Hidetoshi Hayashi

发明人： Hiroshi Yokoyama ,  Masahiko Yamanaka ,  Kentarou Watanabe ,  Tsunehiko Higuchi ,  Hidetoshi Hayashi

IPC分类号： C12Q1/68 ,  C07H21/04

CPC分类号： C12N15/1003 ,  C12N15/10

摘要： An information nucleic acid includes a base sequence portion having an arbitrary and known base sequence. The information nucleic acid is mixed with an additive such as a fat solubilizing agent, a heat stabilizer, a light stabilizer, a nucleic acid hydrolase inhibitor and/or a dispersing agent so as to form an information nucleic acid composition.

摘要翻译： 信息核酸包含具有任意和已知碱基序列的碱基序列部分。 将信息核酸与脂肪增溶剂，热稳定剂，光稳定剂，核酸水解酶抑制剂和/或分散剂等添加剂混合，形成信息核酸组合物。