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公开(公告)号：US20090143613A1
公开(公告)日：2009-06-04
申请号：US12063132
申请日：2006-09-29
IPC分类号： C07C309/06
CPC分类号： C25B3/08 , C07C309/06
摘要： This method for producing a potassium perfluoroalkanesulfonate includes an electrochemical fluorination step in which an alkanesulfonyl halide compound is subjected to electrochemical fluorination in anhydrous hydrogen fluoride, thereby to generate a production gas containing perfluoroalkanesulfonyl fluoride as the main component. In addition, for example, the methods may include a gas absorption step in which the production gas is reacted with an aqueous solution of potassium hydroxide, thereby to generate a gas absorbed solution containing potassium perfluoroalkanesulfonate, a purification step in which impurities such as potassium fluoride, potassium hydroxide, and potassium sulfate, are removed, and a concentration and collection step in which the aqueous solution from which the impurities are removed is concentrated and dried. In the electrochemical fluorination, for example, it is possible that the proton concentration in the reaction solution is maintained in the range of 150 to 1,500 ppm to suppress the formation of byproducts.
摘要翻译： 这种生产全氟烷基磺酸钾的方法包括电化学氟化步骤，其中烷基磺酰卤化合物在无水氟化氢中进行电化学氟化，从而产生以全氟烷基磺酰氟为主要成分的生产气体。 此外，例如，可以举出气体吸收工序，其中生产气体与氢氧化钾水溶液反应，从而产生含有全氟烷基磺酸钾的气体吸收溶液，纯化步骤，其中杂质如氟化钾 ，氢氧化钾和硫酸钾，并且浓缩和干燥除去杂质的水溶液的浓缩和收集步骤。 在电化学氟化中，例如，反应溶液中的质子浓度可能保持在150〜1500ppm的范围内，以抑制副产物的形成。
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公开(公告)号：US08026391B2
公开(公告)日：2011-09-27
申请号：US12063132
申请日：2006-09-29
IPC分类号： C07C309/06
CPC分类号： C25B3/08 , C07C309/06
摘要： This method for producing a potassium perfluoroalkanesulfonate includes an electrochemical fluorination step in which an alkanesulfonyl halide compound is subjected to electrochemical fluorination in anhydrous hydrogen fluoride, thereby to generate a production gas containing perfluoroalkanesulfonyl fluoride as the main component. In addition, for example, the methods may include a gas absorption step in which the production gas is reacted with an aqueous solution of potassium hydroxide, thereby to generate a gas absorbed solution containing potassium perfluoroalkanesulfonate, a purification step in which impurities such as potassium fluoride, potassium hydroxide, and potassium sulfate, are removed, and a concentration and collection step in which the aqueous solution from which the impurities are removed is concentrated and dried. In the electrochemical fluorination, for example, it is possible that the proton concentration in the reaction solution is maintained in the range of 150 to 1,500 ppm to suppress the formation of byproducts.
摘要翻译： 这种生产全氟烷基磺酸钾的方法包括电化学氟化步骤，其中烷基磺酰卤化合物在无水氟化氢中进行电化学氟化，从而产生以全氟烷基磺酰氟为主要成分的生产气体。 此外，例如，可以举出气体吸收工序，其中生产气体与氢氧化钾水溶液反应，从而产生含有全氟烷基磺酸钾的气体吸收溶液，纯化步骤，其中杂质如氟化钾 ，氢氧化钾和硫酸钾，并且浓缩和干燥除去杂质的水溶液的浓缩和收集步骤。 在电化学氟化中，例如，反应溶液中的质子浓度可能保持在150〜1500ppm的范围内，以抑制副产物的形成。
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公开(公告)号：US20120302787A1
公开(公告)日：2012-11-29
申请号：US13575412
申请日：2011-01-27
IPC分类号： C25B3/08 , C07C309/06
CPC分类号： C25B3/08 , C07C303/32 , C07C309/06
摘要： A process for producing a perfluorobutanesulfonic acid salt (PFBS salt) is provided. By the process, the yield is improved and PFOS salt content is reduced. Electrochemical fluorination is conducted in a reaction solution comprising anhydrous hydrogen fluoride to generate perfluorobutanesulfonyl fluoride, and the fluoride is hydrolyzed to produce a perfluorobutanesulfonic acid salt. The process for producing a perfluorobutanesulfonic acid salt includes: a step in which liquid phase components generated in the electrochemical fluorination cell are withdrawn and a first a perfluorobutanesulfonic acid salt fraction is prepared therefrom; and a step in which gaseous phase components discharged from the electrochemical fluorination cell are collected and a second perfluorobutanesulfonic acid salt fraction is prepared therefrom. The reaction solution in the electrochemical fluorination cell is regulated so as to have a perfluorooctanesulfonyl fluoride content of 500 ppm or lower by withdrawing the liquid phase components from the electrochemical fluorination cell.
摘要翻译： 提供了一种制备全氟丁烷磺酸盐（PFBS盐）的方法。 通过该过程，产率提高，PFOS盐含量降低。 电化学氟化在含有无水氟化氢的反应溶液中进行，生成全氟丁烷磺酰氟，氟化物水解生成全氟丁烷磺酸盐。 制备全氟丁烷磺酸盐的方法包括：取出在电化学氟化池中产生的液相成分并从中制备全氟丁烷磺酸盐部分的步骤; 收集从电化学氟化池排出的气相成分并从其中制备第二全氟丁烷磺酸盐部分的工序。 通过从电化学氟化电池取出液相成分，调节电化学氟化电池中的反应溶液以使全氟辛基磺酰氟含量为500ppm以下。
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公开(公告)号：US20110269990A1
公开(公告)日：2011-11-03
申请号：US13138046
申请日：2010-01-05
IPC分类号： C07C303/32 , C07C303/44
CPC分类号： C07C303/44 , C25B3/08 , C07C309/06
摘要： In this method for producing a perfluoroalkylsulfonic acid salt, there is provided a method for producing a perfluoroalkylsulfonic acid salt with a low fluorine content, which is a simple method to achieve a high yield,wherein a solution is formed by adding, to at least one compound selected from perfluoroalkylsulfonic acid salts represented by a general formula RfSO3.M (wherein Rf represents a perfluoroalkyl group of 1 to 4 carbon atoms, and M represents Li, Na or K), an organic solvent which is capable of dissolving the compound, and an adsorbent having a capacity to adsorb fluorine ions is added to the solution.
摘要翻译： 在该全氟烷基磺酸盐的制造方法中，提供了氟含量低的全氟烷基磺酸盐的制造方法，其是获得高产率的简单方法，其中通过将至少一种 选自由通式RfSO3M（其中Rf表示1至4个碳原子的全氟烷基，M表示Li，Na或K）的全氟烷基磺酸盐的化合物，能够溶解化合物的有机溶剂，以及 将具有吸附氟离子能力的吸附剂加入到溶液中。
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5.发明申请公开(公告)号：US20120022269A1
公开(公告)日：2012-01-26
申请号：US13138742
申请日：2010-03-31
IPC分类号： C07C311/48 , C07C303/40 , C07D233/58
CPC分类号： C07D233/58 , C07C311/48
摘要： According to the method for producing fluorine-containing N-alkylsulfonylimide compound, the fluorine-containing N-alkylsulfonylimide compound can be produced safely with a high recovery rate by alkylating fluorine-containing sulfonylimide acid or fluorine-containing sulfonylimide acid salt with dialkylsulfuric acid or dialkylcarbonic acid.
摘要翻译： 根据制造含氟N-烷基磺酰亚胺化合物的方法，可以通过用二烷基硫酸或二烷基碳酸烷基化含氟磺酰亚胺酸或含氟磺酰亚胺酸盐，以高回收率安全地制备含氟N-烷基磺酰亚胺化合物 酸。
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公开(公告)号：US20090118543A1
公开(公告)日：2009-05-07
申请号：US12064113
申请日：2006-10-24
IPC分类号： C07C303/00
CPC分类号： C07C303/00 , C07C309/00
摘要： This method for producing trifluoromethanesulfonic anhydride reacting trifluoromethanesulfonic acid with phosphorus pentoxide to produce trifluoromethanesulfonic anhydride, wherein hardening of the reaction solution due to polyphosphoric acid, which is produced as a byproduct, is prevented by using an excess amount of trifluoromethanesulfonic acid with respect to the phosphorus pentoxide.
摘要翻译： 这种三氟甲磺酸酐与五氧化二磷反应生成三氟甲磺酸酐的方法，其中通过使用过量的三氟甲磺酸相对于磷来防止作为副产物产生的由多磷酸引起的反应溶液的硬化 五氧化物。
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7.发明授权Fluorine-containing n-alkylsulfonylimide compound, manufacturing method therefor, and method of manufacturing an ionic compound 有权含氟的正烷基磺酰亚胺化合物及其制造方法以及离子化合物的制造方法公开(公告)号：US08436198B2
公开(公告)日：2013-05-07
申请号：US13138742
申请日：2010-03-31
IPC分类号： C07C309/05
CPC分类号： C07D233/58 , C07C311/48
摘要： According to the method for producing fluorine-containing N-alkylsulfonylimide compound, the fluorine-containing N-alkylsulfonylimide compound can be produced safely with a high recovery rate by alkylating fluorine-containing sulfonylimide acid or fluorine-containing sulfonylimide acid salt with dialkylsulfuric acid or dialkylcarbonic acid.
摘要翻译： 根据制造含氟N-烷基磺酰亚胺化合物的方法，可以通过用二烷基硫酸或二烷基碳酸烷基化含氟磺酰亚胺酸或含氟磺酰亚胺酸盐，以高回收率安全地制备含氟N-烷基磺酰亚胺化合物 酸。
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公开(公告)号：US07741518B2
公开(公告)日：2010-06-22
申请号：US12064113
申请日：2006-10-24
IPC分类号： C07C303/00
CPC分类号： C07C303/00 , C07C309/00
摘要： This method for producing trifluoromethanesulfonic anhydride reacting trifluoromethanesulfonic acid with phosphorus pentoxide to produce trifluoromethanesulfonic anhydride, wherein hardening of the reaction solution due to polyphosphoric acid, which is produced as a byproduct, is prevented by using an excess amount of trifluoromethanesulfonic acid with respect to the phosphorus pentoxide.
摘要翻译： 这种三氟甲磺酸酐与五氧化二磷反应生成三氟甲磺酸酐的方法，其中通过使用过量的三氟甲磺酸相对于磷来防止作为副产物产生的由多磷酸引起的反应溶液的硬化 五氧化物。
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9.发明申请METHOD FOR PRODUCING PERFLUOROSULFONIC ACID HAVING ETHER STRUCTURE AND DERIVATIVE THEREOF, AND SURFACTANT CONTAINING FLUORINE-CONTAINING ETHER SULFONIC ACID COMPOUND AND DERIVATIVE THEREOF 审中-公开生产具有其结构和衍生物的全氟代酸的方法，以及含有含氟的含硫磺酸化合物及其衍生物的表面活性剂公开(公告)号：US20120184763A1
公开(公告)日：2012-07-19
申请号：US13498710
申请日：2010-09-29
申请人： Mitsuo Kurumaya , Tsunetoshi Honda , Kota Omori
发明人： Mitsuo Kurumaya , Tsunetoshi Honda , Kota Omori
IPC分类号： C07C303/28 , C07C303/02 , C25B3/08 , C07C309/68 , C07C309/10 , C07C303/22 , C07C309/82
CPC分类号： C07C303/22 , C07C303/02 , C07C303/28 , C07C303/32 , C07C303/44 , C25B3/08 , C07C309/82 , C07C309/10 , C07C309/68
摘要： In this method, RH2ORH1SO2F is added to hydrofluoric acid so as to form a thick solution (hydrogen bonded complex), and the solution is directly supplied to a liquid phase reaction system in which an F2 gas is used. Alternatively, RH2ORH1SO2Cl is added to hydrofluoric acid so as to be converted into RH1ORH2SO2F by discharging HCl, and the RH1ORH2SO2F is directly supplied to a liquid phase reaction system in which an F2 gas is used. Consequently, fluorination can be carried out safely and a compound having an objective structure can be produced at low cost without causing isomerization or the like.
摘要翻译： 在该方法中，将RH2ORH1SO2F加入到氢氟酸中以形成稠溶液（氢键合复合物），并将溶液直接供给到使用F2气体的液相反应体系中。 或者，将RH2ORH1SO2Cl加入氢氟酸中，通过排出HCl转化为RH1ORH2SO2F，将RH1ORH2SO2F直接供给到使用F2气体的液相反应体系中。 因此，可以安全地进行氟化，可以以低成本制造具有目标结构的化合物，而不会引起异构化等。
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公开(公告)号：US08580220B2
公开(公告)日：2013-11-12
申请号：US13258628
申请日：2010-03-30
申请人： Tsunetoshi Honda , Takeshi Kamiya
发明人： Tsunetoshi Honda , Takeshi Kamiya
IPC分类号： C01B21/083 , C01B17/45 , C07C303/00
CPC分类号： C01B21/093 , C01B17/45 , C01B21/083 , C01P2002/86 , C01P2006/35 , C01P2006/80 , C07C303/22
摘要： According to the method for producing bis(fluorosulfonyl)imide salt of the present invention, the method for producing fluorosulfate, and the method for producing bis(fluorosulfonyl)imide onium salt, first, an aqueous solution is prepared by dissolving a mixed liquid containing bis(fluorosulfonyl)imide and fluorosulfonic acid in water. Then, the aqueous solution is neutralized with an alkaline compound, producing bis(fluorosulfonyl)imide salt and fluorosulfate. In the methods, bis(fluorosulfonyl)imide salt, fluorosulfate, and bis(fluorosulfonyl)imide onium salt can be obtained safely and easily.
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