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1.发明申请PROCESS FOR THE PREPARATION OF ETHYLENE POLYMERS WITH NARROW MOLECULAR WEIGHT DISTRIBUTION 审中-公开制备具有窄分子量分布的乙烯聚合物的方法公开(公告)号：US20120130031A1
公开(公告)日：2012-05-24
申请号：US13387106
申请日：2010-08-02
申请人： Masaki Fushimi , Dario Liguori , Tiziano Dall'Occo , Giampiero Morini , Joachim T.M. Pater , Gianni Vitale
发明人： Masaki Fushimi , Dario Liguori , Tiziano Dall'Occo , Giampiero Morini , Joachim T.M. Pater , Gianni Vitale
IPC分类号： C08F4/76
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , C08F4/6494 , C08F2500/12 , C08F2500/04 , C08F210/06
摘要： Process for the preparation of ethylene polymers having narrow MWD characterized by a F/E ratio lower than 35 carried out in the presence of a catalyst system comprising (a) a solid catalyst component comprising Ti atoms that are substantially in the +4 oxidation state, Mg, Cl, and optionally OR groups and internal donors in which R is a C1-C20 hydrocarbon group, in which the OR/Ti molar ratio is equal to or lower than 0.35 and the internal donor/Ti ratio is lower than 1, (b) an aluminum alkyl compound and (c) a compound selected from alkoxybenzenes of specified formula.
摘要翻译： 制备具有窄MWD的乙烯聚合物的方法，其特征在于在催化剂体系存在下进行F / E比低于35的乙烯聚合物，其包含（a）包含基本上处于+4氧化态的Ti原子的固体催化剂组分， Mg，Cl和任选的OR基团和其中R是C1-C20烃基的内给体，其中OR / Ti摩尔比等于或低于0.35，内给体/ Ti比低于1（ b）烷基铝化合物和（c）选自具有规定式的烷氧基苯的化合物。
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公开(公告)号：US20140094576A1
公开(公告)日：2014-04-03
申请号：US14123794
申请日：2012-06-01
IPC分类号： C08F10/02
CPC分类号： C08F10/02 , C08F10/00 , C08F110/02 , C08F110/06 , C08F4/6492 , C08F2500/24
摘要： A pre-polymerized catalyst component for the polymerization of olefins CH2═CHR, wherein R is hydrogen or a C1-C12 hydrocarbon group, characterized by comprising a non-stereospecific solid catalyst component, comprising Ti, Mg and a halogen, said pre-polymerized catalyst component containing an amount of a (co)polymer of a monomer having formula CH2═CHA, where A is a C6 aliphatic or aromatic ring, optionally substituted, up to 5 g per g of said solid catalyst component. Said prepolymerized catalyst shows an excellent balance in terms of activity, morphological stability, reduced tendency to agglomeration and hydrogen response.
摘要翻译： 用于烯烃CH 2 = CHR聚合的预聚合催化剂组分，其中R是氢或C1-C12烃基，其特征在于包含非立体特异性固体催化剂组分，其包含Ti，Mg和卤素，所述预聚合 催化剂组分含有一定量的具有式CH 2 = CAB的单体（（共））聚合物，其中A是任选取代的C 6脂族或芳环，每克所述固体催化剂组分最多达5克。 所述预聚合催化剂在活性，形态稳定性，凝聚趋势和氢反应方面表现出极好的平衡。
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3.发明申请Catalyst components for the polymerization of olefins and catalysts therefrom obtained 审中-公开用于烯烃聚合的催化剂组分及其催化剂公开(公告)号：US20100029869A1
公开(公告)日：2010-02-04
申请号：US12448288
申请日：2007-12-10
IPC分类号： C08F4/52 , B01J27/138 , B01J27/135
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , C08F4/6555 , C08F4/6543 , C08F2500/12 , C08F2500/18
摘要： A catalyst component comprising Ti, Mg, Cl, and optionally ORI groups in which RI is a C1-C20 hydrocarbon group up to an amount such as to give a molar ORI/Ti ratio lower than 0.5, characterized by the following properties: surface area, determined by BET method, of lower than 80 m2/g, a total porosity (PT), measured by the mercury method, in the range of 0.60-1.50 cm3/g a difference (PT−PF) of higher than 0.1 in which PT is the total porosity and PF is the porosity due to pore with radius equal to or less than 1 μm; an amount of Ti in the catalyst component of less that 10% wt based on the total weight of catalyst component. The said catalyst components show high morphological stability under the low molecular weight ethylene polymerization conditions while at the same time maintaining characteristics of high activity.
摘要翻译： 一种催化剂组分，其包含Ti，Mg，Cl和任选的ORI基团，其中RI是C1-C20烃基，直到其摩尔ORI / Ti比低于0.5，其特征在于以下性质：表面积 通过BET法测定，低于80m2 / g，通过汞法测量的总孔隙率（PT）在0.60-1.50cm 3 / ga差异（PT-PF）的范围内高于0.1的PT，其中PT 是总孔隙率，PF是由于具有等于或小于1um的孔的孔隙度; 基于催化剂组分的总重量，催化剂组分中Ti的量小于10％wt。 所述催化剂组分在低分子量乙烯聚合条件下显示出高的形态稳定性，同时保持高活性的特性。
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4.发明申请CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS AND CATALYSTS THEREFROM OBTAINED 审中-公开用于获得烯烃和催化剂聚合的催化剂组分公开(公告)号：US20140148564A1
公开(公告)日：2014-05-29
申请号：US14009270
申请日：2012-03-14
申请人： Dario Liguori , Gianni Vitale , Joachim T.M. Pater , Giampiero Morini , Simona Guidotti , Tiziano Dall'occo
发明人： Dario Liguori , Gianni Vitale , Joachim T.M. Pater , Giampiero Morini , Simona Guidotti , Tiziano Dall'occo
CPC分类号： C08F4/76 , B01J31/0202 , B01J2531/22 , B01J2531/46 , C08F4/10 , C08F4/52 , C08F110/02 , C08F210/16 , C08F2500/12 , C08F2500/18 , C08F4/651 , C08F4/6555
摘要： Catalyst components for the polymerization of olefins CH2=CHR wherein R is hydrogen or a hydrocarbon radical having 1-12 carbon atoms, comprising Mg, Ti, Cl and a diol or a derivative thereof. A process for the use of catalyst components for the polymerization of olefins CH2=CHR wherein R is hydrogen or a hydrocarbon radical having 1-12 carbon atoms, comprising Mg, Ti, Cl and a diol or a derivative thereof.
摘要翻译： 用于烯烃CH 2 = CHR的聚合的催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，Cl和二元醇或其衍生物。 使用催化剂组分进行烯烃CH 2 = CHR聚合的方法，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，Cl和二元醇或其衍生物。
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公开(公告)号：US20130158214A1
公开(公告)日：2013-06-20
申请号：US13818626
申请日：2011-08-10
申请人： Joachim T.M. Pater , Dario Liguori , Gianni Vitale , Gianni Collina , Diego Brita , Tiziano Dall'Occo , Giampiero Morini
发明人： Joachim T.M. Pater , Dario Liguori , Gianni Vitale , Gianni Collina , Diego Brita , Tiziano Dall'Occo , Giampiero Morini
IPC分类号： C08F4/46
CPC分类号： C08F4/46 , C08F4/6494 , C08F10/00 , C08F210/16 , C08F210/08 , C08F2500/12 , C08F2500/18 , C08F4/651 , C08F4/6543
摘要： A solid catalyst component for olefin polymerization, and in particular for the preparation of LLDPE, comprising Mg, Ti, halogen and an electron donor compound (ID) belonging to cyclic ethers having 3-6 carbon atoms, characterized by having the molar ratio Mg/Ti higher than 5, the molar ratio Mg/ID lower than 3, and by a specific X-ray diffraction spectrum.
摘要翻译： 用于烯烃聚合的固体催化剂组分，特别是制备包含Mg，Ti，卤素和属于3-6个碳原子的环醚的电子给体化合物（ID）的LLDPE的固体催化剂组分，其特征在于具有摩尔比Mg / Ti高于5，摩尔比Mg / ID低于3，并通过特定的X射线衍射光谱。
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6.发明申请CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS AND CATALYSTS THEREFROM OBTAINED 有权用于获得烯烃和催化剂聚合的催化剂组分公开(公告)号：US20090306316A1
公开(公告)日：2009-12-10
申请号：US12448289
申请日：2007-12-11
IPC分类号： C08F4/42 , B01J31/12 , B01J27/135 , B01J27/138
CPC分类号： C08F10/02 , C08F110/06 , C08F210/06 , C08F4/6557 , C08F4/6555 , C08F2500/12 , C08F2500/18 , C08F210/16
摘要： A catalyst component comprising Ti, Mg, Al, Cl, and optionally OR1 groups in which R1 is a C1-C20 hydrocarbon group, optionally containing heteroatoms, up to an amount such as to give a molar OR1/Ti ratio lower than 0.5, characterized by the fact that substantially all the titanium atoms are in valence state of 4, that the porosity (PF), measured by the mercury method and due to pores with radius equal to or lower than 1 μm, is at least 0.3 cm3/g, and by the fact that the Cl/Ti molar ratio is lower than 29.The said catalysts are characterized by high morphological stability under the low molecular weight ethylene polymerization conditions while at the same time maintaining characteristics of high activity.
摘要翻译： 包含Ti，Mg，Al，Cl和任选的OR 1基团的催化剂组分，其中R 1是任选含有杂原子的C 1 -C 20烃基，直到一定量使OR 1 / Ti比摩尔比低于0.5，表征 通过基本上所有的钛原子都处于4价态的事实，通过汞法测量的孔隙率（PF）和半径等于或小于1um的孔隙至少为0.3cm 3 / g， 以及Cl / Ti摩尔比低于29的事实。所述催化剂的特征在于在低分子量乙烯聚合条件下的高形态稳定性，同时保持高活性的特性。
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公开(公告)号：US07879959B2
公开(公告)日：2011-02-01
申请号：US11887528
申请日：2006-03-15
IPC分类号： C08F4/50
CPC分类号： C08F110/02 , C08F210/16 , C08F4/6565 , C08F4/6548 , C08F2500/12 , C08F210/08
摘要： Catalyst components for the (co)polymerization of ethylene comprising Ti, Mg, halogen, ORI groups, where RI is a C1-C12 hydrocarbon group optionally containing heteroatoms, having ORI/Ti molar ratio in the range 0.1-1.5, a Mg/Ti molar ratio of less than 8, an amount of titanium, with respect to the total weight of said solid catalyst component, higher than 4% by weight characterized by a specific SS-NMR pattern are particularly useful for preparing narrow MWD crystalline ethylene polymers.
摘要翻译： 含有Ti，Mg，卤素，ORI基团的乙烯（共）聚合的催化剂组分，其中RI是任选含有杂原子的C 1 -C 12烃基，ORI / Ti摩尔比在0.1-1.5范围内，Mg / Ti 摩尔比小于8，相对于所述固体催化剂组分的总重量，钛的量高于4重量％，其特征在于特定的SS-NMR图案，特别适用于制备窄MWD晶体乙烯聚合物。
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公开(公告)号：US07834117B2
公开(公告)日：2010-11-16
申请号：US11887527
申请日：2006-03-15
IPC分类号： C08F110/02
CPC分类号： C08F10/00 , C08F210/16 , C08F4/6543 , C08F4/6565 , C08F210/08 , C08F2500/12
摘要： A process for preparing crystalline ethylene (co)polymers comprising (co)polymerizing ethylene in the presence of carried out in the presence catalyst system comprising (a) a solid catalyst component comprising Ti, Mg, halogen, ORI groups, where RI is a C1-C12 hydrocarbon group optionally containing heteroatoms, having ORI/Ti molar ratio of at least 0.5, an amount of titanium, with respect to the total weight of said solid catalyst component, higher than 4% by weight, and showing a specific pattern of the SS-NMR; and (b) an aluminum alkyl compound as a cocatalyst. The process allows to obtain in good yields ethylene polymers with narrow MWD.
摘要翻译： 在包含（a）包含Ti，Mg，卤素，ORI基团的固体催化剂组分的情况下，在存在催化剂体系的情况下，制备结晶乙烯（共）聚合物的方法，包括（共）聚合乙烯，其中RI是C1 -C12烃基，任选地含有杂原子，ORI / Ti摩尔比至少为0.5，相对于所述固体催化剂组分的总重量，钛的量高于4重量％，并且显示了 SS-NMR; 和（b）作为助催化剂的烷基铝化合物。 该方法允许以良好的产率获得具有窄MWD的乙烯聚合物。
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9.发明申请公开(公告)号：US20120077944A1
公开(公告)日：2012-03-29
申请号：US13376000
申请日：2010-06-16
IPC分类号： C08F4/646
CPC分类号： C08F10/00 , C08F110/06 , C08F4/6543 , C08F4/6555 , C08F4/651 , C08F2500/12 , C08F2500/18 , C08F2500/24
摘要： Catalyst components for the polymerization of olefins CH2═CHR wherein R is hydrogen or a hydrocarbon radical having 1-12 carbon atoms, comprising Mg, Ti, Cl and a compound (L) or its derivatives, selected from condensed cyclic structures which are formed by at least an aromatic ring and which are substituted with at least two hydroxy groups, said Cl and Ti atoms being in an amount such as to have a molar ratio ranging from 5 to 50.
摘要翻译： 用于烯烃CH 2 = CHR聚合的催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，Cl和化合物（L）或其衍生物，其选自稠合的环状结构，其由 至少一个芳环，并被至少两个羟基取代，所述Cl和Ti原子的量为使其摩尔比为5-50。
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10.发明授权公开(公告)号：US08071499B2
公开(公告)日：2011-12-06
申请号：US12448289
申请日：2007-12-11
CPC分类号： C08F10/02 , C08F110/06 , C08F210/06 , C08F4/6557 , C08F4/6555 , C08F2500/12 , C08F2500/18 , C08F210/16
摘要： A catalyst component comprising Ti, Mg, Al, Cl, and optionally ORI groups in which RI is a C1-C20 hydrocarbon group, optionally containing heteroatoms, up to an amount such as to give a molar ORI/Ti ratio lower than 0.5, characterized by the fact that substantially all the titanium atoms are in valence state of 4, that the porosity (PF), measured by the mercury method and due to pores with radius equal to or lower than 1 μm, is at least 0.3 cm3/g, and by the fact that the Cl/Ti molar ratio is lower than 29.The said catalysts are characterized by high morphological stability under the low molecular weight ethylene polymerization conditions while at the same time maintaining characteristics of high activity.
摘要翻译： 包含Ti，Mg，Al，Cl和任选的ORI基团的催化剂组分，其中RI是任选含有杂原子的C 1 -C 20烃基，直到一定量使ORI / Ti摩尔比低于0.5，表征 通过基本上所有的钛原子都处于4的价态，由汞法测量并且由于半径等于或小于1μm的孔的孔隙率（PF）至少为0.3cm 3 / g， 以及Cl / Ti摩尔比低于29的事实。所述催化剂的特征在于在低分子量乙烯聚合条件下的高形态稳定性，同时保持高活性的特性。
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