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1.发明申请Polymer composite formed article, printed wiring board using the formed article, and methods of producing them 审中-公开高分子复合成型体，使用成形体的印刷线路板及其制造方法公开(公告)号：US20070116938A1
公开(公告)日：2007-05-24
申请号：US10582558
申请日：2005-02-18
申请人： Masayuki Tobita , Toru Kimura , Hisashi Aoki , Naoyuki Shimoyama , Tsukasa Ishigaki , Mitsukazu Ochi , Miyuki Harada
发明人： Masayuki Tobita , Toru Kimura , Hisashi Aoki , Naoyuki Shimoyama , Tsukasa Ishigaki , Mitsukazu Ochi , Miyuki Harada
IPC分类号： D04H13/00
CPC分类号： C08G59/28 , B32B15/08 , B32B15/092 , B32B15/20 , B32B27/04 , B32B27/18 , B32B27/38 , B32B2250/03 , B32B2250/40 , B32B2274/00 , B32B2307/202 , B32B2307/206 , B32B2457/08 , C08G59/5033 , C08J5/24 , C08J2363/00 , C08K7/02 , H05K1/0366 , H05K2201/0129 , H05K2201/0141 , H05K2201/0287 , H05K2201/029 , H05K2201/068 , Y10T428/249924 , C08L63/00
摘要： A thermoplastic polymer composite formed article or a thermoplastic polymer composite formed article formed from a thermoplastic polymer or a thermoplastic polymer and a fiber, wherein the fiber is arranged along a first plane and the molecular chains of the thermoplastic polymer or thermoplastic polymer is oriented in the direction intersecting with the first plane, and the molecular chains of the thermoplastic polymer or thermoplastic polymer has a degree (a) of orientation in a range of 0.5 or more and less than 1.0, and wherein the thermal expansion coefficients of said formed article in the direction along the first plane and in the direction intersecting with the first plane are both 5×10−6 to 50×10−6 (/K), and the difference between the thermal expansion coefficient in the direction along the first plane and the thermal expansion coefficient in the direction intersecting with the first plane is 30×10−6 (/K) or less.
摘要翻译： 由热塑性聚合物或热塑性聚合物和纤维形成的热塑性聚合物复合成型制品或热塑性聚合物复合成型制品，其中纤维沿着第一平面布置，热塑性聚合物或热塑性聚合物的分子链定向于 方向与第一平面相交，并且热塑性聚合物或热塑性聚合物的分子链具有在0.5以上且小于1.0的范围内的取向度（a），并且其中所述成型制品的热膨胀系数在 沿着第一平面和与第一平面相交的方向的方向均为5×10 -6〜50×10 -6（/ K），热膨胀系数 沿着第一平面的方向和与第一平面相交的方向的热膨胀系数为30×10 -6（/ K）以下。
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公开(公告)号：US07347955B2
公开(公告)日：2008-03-25
申请号：US10686384
申请日：2003-10-14
申请人： Masayuki Tobita , Naoyuki Shimoyama , Tsukasa Ishigaki , Hisashi Aoki , Toru Kimura , Tsunehisa Kimura , Masafumi Yamato
发明人： Masayuki Tobita , Naoyuki Shimoyama , Tsukasa Ishigaki , Hisashi Aoki , Toru Kimura , Tsunehisa Kimura , Masafumi Yamato
CPC分类号： C09K19/3809 , C09K19/38 , C09K19/3838 , C09K19/52 , Y10T428/24994 , Y10T428/249942
摘要： A mold product comprising liquid crystal composition for conducting heat. The liquid crystal composition contains liquid crystal polymer having an orientation degree α obtained by equation 1 below: Orientation degree α=(180−Δβ)/180 equation 1 In equation 1, Δβ is a half width in the intensity distribution obtained by fixing peak scattering angle in X-ray diffraction measurement and by varying the azimuth angle from 0 to 360 degrees, and orientation degree α is in a range between 0.5 and 1.0.
摘要翻译： 一种包含用于传导热量的液晶组合物的模具产品。 该液晶组合物含有具有以下等式1得到的取向度α的液晶聚合物：<？in-line-formula description =“In-line formula”end =“lead”？>取向度α=（180-Deltabeta） 方程式1 <？in-line-formula description =“In-line Formulas”end =“tail”？>在等式1中，Deltabeta是通过固定X射线衍射中的峰值散射角得到的强度分布的半宽度 并且通过将方位角从0变化到360度，并且取向度α在0.5和1.0之间的范围内。
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3.发明授权公开(公告)号：US07079405B2
公开(公告)日：2006-07-18
申请号：US10617517
申请日：2003-07-11
IPC分类号： H02M3/335
CPC分类号： C09K19/3809 , B29C70/88 , B29C71/00 , B29C71/0081 , B29K2077/00 , B29K2077/10 , B29K2105/0079 , B29K2995/0013
摘要： A thermal conductive polymer molded article is formed by molding a thermotropic liquid crystalline composition comprised mainly of a thermotropic liquid crystalline polymer, wherein the thermal conductive polymer molded article is formed by applying a magnetic field or an electric field to the thermotropic liquid crystalline composition melted by heating so that the thermal conductive polymer molded article has a first thermal conductivity (λ1) higher than a second thermal conductivity (λ2) of a molded article formed by molding the thermotropic liquid crystalline polymer without the application of the field. The thermal conductive polymer molded article preferably has a first thermal conductivity (λ1) of between 0.7 and 20 W/(m·K). Preferably, the thermotropic liquid crystalline polymer comprises at least one polymer selected from (A) a wholly aromatic polyester and (B) a wholly aromatic polyester amide.
摘要翻译： 导热聚合物模制品通过模制一种主要由热致液晶聚合物组成的热致液晶组合物而形成，其中通过向由热致液晶组合物熔化的热致变液晶组合物施加磁场或电场而形成导热聚合物模塑制品 加热，使得导热聚合物模塑制品具有比通过模塑成型制成的模塑制品的第二热导率（λ/ 2> 2）高的第一热导率（λ<1/2） 热致液晶聚合物无应用领域。 导热聚合物模塑制品优选具有0.7至20W /（m.K）之间的第一热导率（λ<1/2）。 优选地，热致液晶聚合物包含至少一种选自（A）全芳族聚酯和（B）全芳族聚酯酰胺的聚合物。
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4.发明授权公开(公告)号：US07189778B2
公开(公告)日：2007-03-13
申请号：US10623860
申请日：2003-07-21
CPC分类号： B29C55/00 , B29C70/62 , B29C70/88 , B29K2105/18 , B29K2995/0013 , C09K19/3809 , C09K2019/521 , Y10T428/1352 , Y10T428/24994 , Y10T428/249945
摘要： A thermally conductive polymer molded article formed by molding a thermally conductive composition which comprises a liquid crystalline polymer and thermally conductive filler having magnetic anisotropy, wherein the liquid crystalline polymer and the thermally conductive filler are oriented in a predetermined direction by a magnetic field. The thermally conductive composition contains 100 parts by weight of the liquid crystalline polymer and 5 to 800 parts by weight of the thermally conductive filler having magnetic anisotropy. The thermally conductive filler has a thermal conductivity in at least one direction higher than the thermal conductivity of the liquid crystalline polymer.
摘要翻译： 一种导热聚合物模制品，其通过模制包含液晶聚合物和具有磁各向异性的导热填料的导热组合物而形成，其中液晶聚合物和导热填料通过磁场沿预定方向取向。 导热组合物含有100重量份液晶聚合物和5至800重量份具有磁各向异性的导热填料。 导热填料在比液晶聚合物的热导率高至少一个方向上具有导热性。
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5.发明授权Ion conductive polymer electrolyte membrane and production method for the same 失效离子导电聚合物电解质膜及其制备方法相同公开(公告)号：US07540991B2
公开(公告)日：2009-06-02
申请号：US11173721
申请日：2005-07-01
申请人： Naoyuki Shimoyama , Fumio Saitoh , Toru Kimura , Masayuki Tobita
发明人： Naoyuki Shimoyama , Fumio Saitoh , Toru Kimura , Masayuki Tobita
IPC分类号： H05B6/00
CPC分类号： H01M10/0565 , C08J5/2256 , C08J2379/06 , H01M8/1027 , H01M8/103 , H01M8/1081 , H01M8/1086 , H01M10/0525 , H01M2300/0082 , Y02P70/56
摘要： The present invention provides an electrolyte membrane formed of an ion conductive composition. Said composition contains a liquid crystalline polymer having an ionic dissociative group. Molecular chains of the liquid crystalline polymer are orientated in a specific direction. The degree of orientation α of the liquid crystalline polymer is in a range of 0.45 or more and less than 1, as defined by equation (1) as follows, Degree of orientation α=(180−Δβ)/180 (1), wherein Δβ is a full width at half maximum of a peak in an X-ray diffraction intensity distribution pattern obtained by measuring an intensity distribution from 0 to 360 degrees in the azimuthal angle direction, at a peak scattering angle, in an X-ray diffraction image of the electrolyte membrane. Ionic conductivity in a thickness direction of the membrane is higher than the ionic conductivity in a direction parallel to a surface of the membrane. The present invention also provides a method for manufacturing an electrolyte membrane formed of an ion conductive composition.
摘要翻译： 本发明提供由离子导电组合物形成的电解质膜。 所述组合物含有具有离子解离基团的液晶聚合物。 液晶聚合物的分子链沿特定方向取向。 如式（1）所定义，液晶聚合物的取向度α在0.45以上且小于1的范围内，<？在线式说明=“在线式”末端= “lead”？>取向度α=（180-Deltabeta）/ 180（1），<？in-line-formula description =“In-line formula”end =“tail”？>其中Deltabeta是 在电解质膜的X射线衍射图像中，以峰值散射角测量方位角方向的0〜360度的强度分布而得到的X射线衍射强度分布图案中的峰的半值最大值。 膜的厚度方向上的离子传导率在平行于膜的表面的方向上高于离子导电率。 本发明还提供一种由离子导电组合物形成的电解质膜的制造方法。
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公开(公告)号：US20050058805A1
公开(公告)日：2005-03-17
申请号：US10664988
申请日：2003-09-17
申请人： Toru Kimura , Naoyuki Shimoyama , Masayuki Tobita
发明人： Toru Kimura , Naoyuki Shimoyama , Masayuki Tobita
CPC分类号： B29C70/14 , B29C70/081 , Y10T428/24124 , Y10T428/24994 , Y10T442/20 , Y10T442/3715 , Y10T442/643 , Y10T442/659
摘要： A polymer composite molded body contains a fiber and at least one sheet of fiber cloth in a polymer matrix. The fiber cloth is disposed in the polymer composite molded body along a surface thereof. A polymer composition containing the fiber and polymer matrix is impregnated into the fiber cloth. Then a magnetic field is applied to the polymer composition to orient the fibers in the composition in a direction crossing with the fiber cloth. Then the polymer composition is solidified to obtain the polymer composite molded body.
摘要翻译： 聚合物复合成型体在聚合物基体中含有纤维和至少一层纤维布。 纤维布沿其表面设置在聚合物复合成型体中。 将含有纤维和聚合物基质的聚合物组合物浸渍到纤维布中。 然后将磁场施加到聚合物组合物上以使纤维在与纤维布交叉的方向上定向组合物中的纤维。 然后将聚合物组合物固化，得到聚合物复合成型体。
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7.发明申请Ion conductive polymer electrolyte membrane and production method for the same 失效离子导电聚合物电解质膜及其制备方法相同公开(公告)号：US20060004112A1
公开(公告)日：2006-01-05
申请号：US11173721
申请日：2005-07-01
申请人： Naoyuki Shimoyama , Fumio Saitoh , Toru Kimura , Masayuki Tobita
发明人： Naoyuki Shimoyama , Fumio Saitoh , Toru Kimura , Masayuki Tobita
CPC分类号： H01M10/0565 , C08J5/2256 , C08J2379/06 , H01M8/1027 , H01M8/103 , H01M8/1081 , H01M8/1086 , H01M10/0525 , H01M2300/0082 , Y02P70/56
摘要： The present invention provides an electrolyte membrane formed of an ion conductive composition. Said composition contains a liquid crystalline polymer having an ionic dissociative group. Molecular chains of the liquid crystalline polymer are orientated in a specific direction. The degree of orientation α of the liquid crystalline polymer is in a range of 0.45 or more and less than 1, as defined by equation (1) as follows; Degree of orientation α=(180−ΔB/180) (1), wherein ΔB is a full width at half maximum of a peak in an X-ray diffraction intensity distribution pattern obtained by measuring an intensity distribution from 0 to 360 degrees in the azimuthal angle direction, at a peak scattering angle, in an X-ray diffraction image of the electrolyte membrane. Ionic conductivity in a thickness direction of the membrane is higher than the ionic conductivity in a direction parallel to a surface of the membrane. The present invention also provides a method for manufacturing an electrolyte membrane formed of an ion conductive composition.
摘要翻译： 本发明提供由离子导电组合物形成的电解质膜。 所述组合物含有具有离子解离基团的液晶聚合物。 液晶聚合物的分子链沿特定方向取向。 液晶聚合物的取向度为如下式（1）所定义的0.45以上且小于1的范围; 取向度α=（180-ΔB/ 180）（1），其中DeltaB是通过测量从0到360度的强度分布而获得的X射线衍射强度分布图中的峰的半峰全宽 在电解质膜的X射线衍射图像中以峰值散射角度的方位角方向。 膜的厚度方向上的离子传导率在平行于膜的表面的方向上高于离子导电率。 本发明还提供一种由离子导电组合物形成的电解质膜的制造方法。
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公开(公告)号：US07264869B2
公开(公告)日：2007-09-04
申请号：US10162520
申请日：2002-06-04
CPC分类号： C09K5/14 , H01L23/3733 , H01L23/3737 , H01L2224/16 , H01L2224/16225 , H01L2224/16227 , H01L2224/32245 , H01L2224/73253 , H01L2924/01019 , H01L2924/01078 , H01L2924/01079 , Y10T428/24994 , Y10T428/25 , Y10T428/254 , Y10T428/26 , Y10T442/2123
摘要： A thermally conductive molded article is produced by molding a conductive composition into a predetermined shape. The composition includes a polymer matrix and carbon powders. The carbon powders are obtained by graphitizing a polymeric material that has an aromatic ring on its main chain by heating. The carbon powders are aligned in a certain direction in the polymer matrix. Thus, the molded article can be produced easily and effectively that has excellent thermal conductivity in a given direction and that is suitable for use as a heat radiator, heat transfer member, or a component thereof in electronic hardware.
摘要翻译： 通过将导电性组合物成型为规定形状来制造导热性成形品。 该组合物包括聚合物基质和碳粉末。 碳粉是通过加热在其主链上具有芳香环的聚合物材料进行石墨化而获得的。 碳粉在聚合物基体中沿某一方向排列。 因此，可以容易且有效地制造模制品，其在给定方向上具有优异的导热性，并且适合用作电子硬件中的散热器，传热构件或其部件。
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公开(公告)号：US07291381B2
公开(公告)日：2007-11-06
申请号：US10409957
申请日：2003-04-09
CPC分类号： C04B35/83 , B29K2995/0013 , C04B2235/5268 , C04B2235/9607 , C08K7/06 , Y10T428/249941 , Y10T428/249945
摘要： A thermally conductive formed article according to the present invention includes a matrix, and short carbon fibers which are present in the matrix. The short carbon fibers are oriented in a fixed direction in the matrix. A ratio I(002)/I(110) between an intensity I(110) of a diffraction peak ascribable to a (110) surface of carbon and an intensity I(002) of a diffraction peak ascribable to a (002) surface of carbon, occurring when X-rays are irradiated onto the thermally conductive formed article along the direction of orientation of the short carbon fibers, is 10 or less.
摘要翻译： 根据本发明的导热成形制品包括基质和存在于基质中的短碳纤维。 短碳纤维在矩阵中沿固定方向取向。 （110）表面的衍射峰的强度I（110）之间的比值I（002）/ I（110）的衍射峰，归因于（002）表面的碳，当X射线照射到导热成形体上时，沿着 短碳纤维为10以下。
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公开(公告)号：US06794035B2
公开(公告)日：2004-09-21
申请号：US10255275
申请日：2002-09-26
IPC分类号： B32B516
CPC分类号： C08K3/04 , C01B32/00 , C01B32/20 , C01P2002/72 , C01P2004/61 , Y10T428/25 , Y10T428/29 , Y10T428/2982 , Y10T428/2991 , Y10T428/2998 , C08L21/00
摘要： Graphitized carbon powder are produced by carbonizing and expanding a pitch by heating to form carbonaceous foam and by graphitizing before pulverizing or graphitizing after pulverizing the carbonaceous foam. The resultant graphitized carbon powders have an interplanar spacing (d002) of graphite planes of less than 0.3370 nm. The powders preferably have an average particle size of from 2 to 200 &mgr;m. A thermally conductive composition includes the graphitized carbon powders in a matrix. The content of the powders is preferably 1 to 800 parts by weight relative to 100 parts by weight of the matrix. Thus, the graphitized carbon powders that have excellent thermal conductivity and a thermally conductive composition including such powders are provided.
摘要翻译： 通过加热碳化和膨胀沥青以形成碳质泡沫并通过石墨化之后，在粉碎碳质泡沫之前进行粉碎或石墨化之前生产石墨化碳粉末。 所得的石墨化碳粉末具有小于0.3370nm的石墨平面的晶面间距（d002）。 粉末的平均粒径优选为2〜200μm。 导热组合物包括基质中的石墨化碳粉。 相对于100重量份的基质，粉末的含量优选为1〜800重量份。 因此，提供具有优异导热性的石墨化碳粉末和包含这种粉末的导热组合物。
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