公开(公告)号：US06537722B2

公开(公告)日：2003-03-25

申请号：US09110819

申请日：1998-07-07

申请人： Mathias Eichhorn ,  Karin Maerz ,  Fritz-Feo Grabley

发明人： Mathias Eichhorn ,  Karin Maerz ,  Fritz-Feo Grabley

IPC分类号： G03F7039

CPC分类号： B41C1/1008 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/20 ,  B41C2210/24 ,  B41C2210/262 ,  G03F7/0045 ,  Y10S430/145 ,  Y10S430/165

摘要： A recording material for producing offset printing plates includes: a support having a hydrophilic surface, and an infrared-imageable layer including a) a component which is capable of absorbing infrared radiation and converting the infrared radiation to heat, b) a compound which is capable of releasing acid under the action of the heat generated by component a), and c) a polymeric binder having at least one group which is cleaved by the acid released from the compound b), and at least one hydrophilic group, and wherein the layer becomes soluble in an aqueous-alkaline developer in areas struck by infrared radiation.

摘要翻译： 用于制造胶版印刷版的记录材料包括：具有亲水表面的支撑体和可红外成像层，其包括：a）能够吸收红外辐射并将红外辐射转换成热的组分，b）能够 在由组分a）产生的热的作用下释放酸，和c）具有至少一个被从化合物b）释放的酸裂解的基团和至少一个亲水基团的聚合物粘合剂，并且其中所述层 在被红外线辐射的区域溶于含水碱性显影剂。

公开(公告)号：US6165685A

公开(公告)日：2000-12-26

申请号：US149044

申请日：1998-09-08

申请人： Karin Maerz ,  Helmut Haberhauer ,  Andreas Elsaesser ,  Hans-Joachim Schlosser ,  Fritz-Feo Grabley

发明人： Karin Maerz ,  Helmut Haberhauer ,  Andreas Elsaesser ,  Hans-Joachim Schlosser ,  Fritz-Feo Grabley

IPC分类号： G03F7/004 ,  B41C1/10 ,  B41N1/14 ,  G03F7/00 ,  G03F7/11 ,  G03C1/76

CPC分类号： B41C1/1016 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/14 ,  B41C2210/20 ,  B41C2210/24 ,  B41C2210/262

摘要： The invention relates to a recording material having a substrate and a radiation-sensitive, water-insoluble layer which contains a component absorbing IR radiation and which, after the action of infrared radiation, becomes soluble or at least swellable in an aqueous alkaline developer. A top layer which is opaque to white light but transparent to radiation in the IR range and can be removed with water or an aqueous solution is present on the radiation-sensitive layer. The recording material is substantially insensitive to daylight. By imagewise exposure to IR radiation and subsequent development with an aqueous alkaline developer, it is possible to produce a printing plate for offset printing from the recording material. If the top layer is washed off beforehand, the recording can also be carried out using conventional UV radiation.

摘要翻译： 本发明涉及具有基材和辐射敏感的水不溶性层的记录材料，其含有吸收IR辐射的组分，并且在红外线辐射的作用下，在碱性显影液的水溶液中变得可溶或至少可溶胀。 对于白光不透明但对IR范围内的辐射透明并且可以用水或水溶液除去的顶层存在于辐射敏感层上。 记录材料对日光基本不敏感。 通过用IR辐射成像曝光并随后用含水碱性显影剂显影，可以从记录材料制备用于胶版印刷的印版。 如果顶层被预先洗去，也可以使用常规的紫外线辐射进行记录。

公开(公告)号：US6100004A

公开(公告)日：2000-08-08

申请号：US38162

申请日：1998-03-11

申请人： Andreas Elsaesser ,  Otfried Gaschler ,  Helmut Haberhauer ,  Mathias Eichhorn ,  Fritz-Feo Grabley ,  Thomas Leichsenring ,  Gabor I. Koletar ,  Douglas A. Seeley

发明人： Andreas Elsaesser ,  Otfried Gaschler ,  Helmut Haberhauer ,  Mathias Eichhorn ,  Fritz-Feo Grabley ,  Thomas Leichsenring ,  Gabor I. Koletar ,  Douglas A. Seeley

IPC分类号： G03F7/004 ,  B41C1/10 ,  B41M5/46 ,  C09D11/00 ,  G03F7/00 ,  G03F7/021 ,  G03F7/022 ,  G03F7/32 ,  G03F7/30

CPC分类号： B41M5/465 ,  B41C1/1008 ,  B41C2210/02 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/20 ,  B41C2210/24 ,  B41C2210/262

摘要： A positive-working or negative-working radiation-sensitive mixture includes as an IR absorbing component a carbon black pigment having a primary particle size smaller than 80 nm. The carbon black pigment is predispersed in a polymer containing acidic units having a pK.sub.a of less than 13. The radiation-sensitive component may include an ester of (i) a 1,2-naphthoquinone-2-diazide-4-sulfonic acid or a 1,2-naphthoquinone-2-diazide-5-sulfonic acid and (ii) a compound having at least one phenolic hydroxyl group, such as 3 to 6 phenolic hydroxyl groups. After imagewise radiation exposure, the recording material including the radiation-sensitive mixture can be developed without difficulties in an aqueous alkaline solution without leaving residual coating on the areas that became soluble or that remained soluble upon exposure.

摘要翻译： 正性或负性辐射敏感性混合物包括作为IR吸收组分的一次粒径小于80nm的炭黑颜料。 炭黑颜料预先分散在含有pKa小于13的酸性单元的聚合物中。辐射敏感组分可以包括（i）1,2-萘醌-2-二叠氮-4-磺酸或 1,2-萘醌-2-二叠氮-5-磺酸和（ii）具有至少一个酚羟基的化合物，例如3至6个酚羟基。 在成像辐射曝光之后，包含辐射敏感性混合物的记录材料可以在碱性水溶液中无困难地显影，而不会在易溶的区域或暴露后保持溶解的区域留下残留涂层。

公开(公告)号：US5045222A

公开(公告)日：1991-09-03

申请号：US449990

申请日：1989-12-13

申请人： Hajime Endo ,  Hanspeter Gethoffer ,  Fritz-Feo Grabley ,  Gerd Reinhardt

发明人： Hajime Endo ,  Hanspeter Gethoffer ,  Fritz-Feo Grabley ,  Gerd Reinhardt

IPC分类号： C11D3/395 ,  C11D3/39 ,  C11D7/32 ,  C11D7/54 ,  D06L3/02

CPC分类号： C11D3/3917

摘要： Use of triacylated ethanolamines as liquid, water-miscible peroxide activatorsTriacylated ethanolamines of the formula(RCO)(R.sub.1 CO)N-(CH.sub.2).sub.2 -OCOR.sub.2where R, R.sub.1 and R.sub.2, which may be identical to or different from one another, are each alkyl, alkenyl or aryl, and the total number of carbon atoms in the molecule is from 8 to 14, are liquid and readily water-miscible. Owing to these properties, they are very useful as peroxide activators in liquid detergent compositions.

摘要翻译： 使用三酰化乙醇胺作为液体，水混溶性过氧化物活化剂式（RCO）（R1CO）N-（CH2）2-OCOR2的三酰化乙醇胺其中R，R 1和R 2可以彼此相同或不同， 每个烷基，烯基或芳基，并且分子中的总碳原子数为8至14，是液体且容易与水混溶。 由于这些性质，它们作为液体洗涤剂组合物中的过氧化物活化剂是非常有用的。

公开(公告)号：US6048624A

公开(公告)日：2000-04-11

申请号：US126422

申请日：1998-07-30

申请人： Cornelia Alba ,  Andreas Elsasser ,  Fritz-Feo Grabley ,  Klaus Jorg ,  Peter Lehmann

发明人： Cornelia Alba ,  Andreas Elsasser ,  Fritz-Feo Grabley ,  Klaus Jorg ,  Peter Lehmann

摘要： A dummy plate is provided for offset printing which essentially consists of a plate-, sheet- or band-form, mechanically and/or electro-chemically roughened, anodically oxidized and optionally hydrophilized aluminium support and a non-photosensitive, water-soluble protective layer applied thereto, characterized in that the layer contains a water-soluble organic compound which contains at least one OH- or NH-acidic group having a pKa value of .ltoreq.8 as acid or salt, and has a layer thickness which is smaller than the average roughness ra of the support material, determined by optical means. Even after extended storage at elevated temperature, the dummy plate can easily be used without an additional development step and exhibits no tendency to stick.

公开(公告)号：US06238838B1

公开(公告)日：2001-05-29

申请号：US09362861

申请日：1999-07-29

申请人： Otfried Gaschler ,  Andreas Elsaesser ,  Fritz-Feo Grabley ,  Joerg Jung ,  Engelbert Pliefke ,  Hans-Joachim Schlosser

发明人： Otfried Gaschler ,  Andreas Elsaesser ,  Fritz-Feo Grabley ,  Joerg Jung ,  Engelbert Pliefke ,  Hans-Joachim Schlosser

IPC分类号： G03C177

CPC分类号： B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/14 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/20 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262

摘要： A positive-working, radiation-sensitive mixture which contains an organic, polymeric binder which is insoluble in water but soluble or at least swellable in aqueous alkaline solution and at least one IR-absorbing dye, is described. A daylight-insensitive recording material which can be provided with an image using IR radiation and has a substrate and a layer comprising the mixture is also disclosed. After imagewise exposure, in particular to IR laser beams, and development with an aqueous alkaline solution, an offset printing plate can be formed therefrom.

摘要翻译： 描述了一种正面工作的，辐射敏感的混合物，其包含不溶于水但在碱性水溶液和至少一种IR吸收染料中可溶或至少可溶胀的有机聚合物粘合剂。 还公开了可以使用IR辐射提供图像并具有基底和包含该混合物的层的日光不敏感记录材料。 在成像曝光之后，特别是对于IR激光束，并用碱性水溶液进行显影，可以形成胶版印刷版。

公开(公告)号：US4778629A

公开(公告)日：1988-10-18

申请号：US922277

申请日：1986-10-23

申请人： Fritz-Feo Grabley ,  Gerd Reinhardt ,  Georg Bader ,  Walter Rupp

发明人： Fritz-Feo Grabley ,  Gerd Reinhardt ,  Georg Bader ,  Walter Rupp

IPC分类号： C07C309/42 ,  C07C20060101 ,  C07C67/00 ,  C07C301/00 ,  C07C303/06 ,  C07C303/32 ,  C07C309/28 ,  C11C3/00

CPC分类号： C07C309/00

摘要： A process for the preparation of acyloxybenzenesulfonic acids and salts thereof, of the formula ##STR1## in which R is C.sub.1 -C.sub.17 -alkyl or C.sub.2 -C.sub.17 -alkenyl and M is an alkali or alkaline earth metal, ammonium or hydrogen, including the stages of (a) sulfonation of phenol, if appropriate (b) thermal treatment of the sulfonated phenol, (c) esterification of the sulfonated phenol and if appropriate (d) neutralization of the ester, wherein the sulfonation of the phenol is carried out with sulfuric acid or oleum and the water of reaction is removed during or after stage (b) by distillation and/or by reaction with a dehydrating agent.

摘要翻译： 制备其中R为C 1 -C 17 - 烷基或C 2 -C 17 - 链烯基且M为碱金属或碱土金属，铵或氢的式“IMAGE”的酰氧基苯磺酸及其盐的方法，包括步骤 （a）苯酚磺化，如果合适（b）磺化苯酚的热处理，（c）磺化苯酚的酯化，如果合适（d）中和该酯，其中苯酚的磺化用硫酸进行 酸或发烟硫酸，并且通过蒸馏和/或通过与脱水剂反应在阶段（b）期间或之后除去反应水。

公开(公告)号：US06207287B1

公开(公告)日：2001-03-27

申请号：US09126422

申请日：1998-07-30

申请人： Cornelia Alba ,  Andreas Elsässer ,  Fritz-Feo Grabley ,  Klaus Jörg ,  Peter Lehmann

发明人： Cornelia Alba ,  Andreas Elsässer ,  Fritz-Feo Grabley ,  Klaus Jörg ,  Peter Lehmann

IPC分类号： B32B1504

CPC分类号： B41N1/083 ,  B41N3/03 ,  B41N3/036 ,  Y10S428/913 ,  Y10T428/265 ,  Y10T428/31678

摘要： A dummy plate is provided for offset printing which essentially consists of a plate-, sheet- or band-form, mechanically and/or electro-chemically roughened, anodically oxidized and optionally hydrophilized aluminium support and a non-photosensitive, water-soluble protective layer applied thereto, characterized in that the layer contains a water-soluble organic compound which contains at least one OH- or NH-acidic group having a pKa value of ≦8 as acid or salt, and has a layer thickness which is smaller than the average roughness ra of the support material, determined by optical means. Even after extended storage at elevated temperature, the dummy plate can easily be used without an additional development step and exhibits no tendency to stick.

摘要翻译： 提供了用于胶版印刷的虚拟板，其基本上由板，片或带形机械和/或电化学粗糙化的阳极氧化和任选亲水化的铝载体和非感光性水溶性保护层 其特征在于，该层含有水溶性有机化合物，其含有pKa值<= 8的至少一种OH-或NH-酸性基团作为酸或盐，并且具有小于 通过光学手段确定支撑材料的平均粗糙度ra。 即使在升高的温度下延长储存后，也可以容易地使用虚拟板而不需要额外的显影步骤，并且不会发生粘附。

公开(公告)号：US5924364A

公开(公告)日：1999-07-20

申请号：US008249

申请日：1998-01-16

申请人： Fritz-Feo Grabley ,  Willi-Kurt Gries ,  Hans-Joachim Schlosser

发明人： Fritz-Feo Grabley ,  Willi-Kurt Gries ,  Hans-Joachim Schlosser

IPC分类号： B41C1/10 ,  B41N1/00 ,  B41N1/08

CPC分类号： B41C1/1033 ,  B41N1/003 ,  B41C2210/16

摘要： The invention relates to a recording material having a plate- or sheet-like substrate, at least one IR-absorbing layer, which comprises at least one IR-absorbing component and at least one polymeric, organic binder and decomposes under the action of IR laser radiation or changes so that its adhesion to the silicone top layer decreases, and a top layer comprising a cured silicone rubber. The substrate comprises an oxidizable metal or one of its alloys and, at least on the side facing the IR-absorbing layer, is roughened and is covered with a layer of an oxide of the metal. The invention also relates to a process for the production of a waterless offset printing plate and to the printing plate itself which is produced from the recording material according to the invention and in which the hydrophilic surface of the oxide layer is ink-carrying and the oleophobic top layer is ink-repellent.

摘要翻译： 本发明涉及具有板状或片状衬底的记录材料，至少一个IR吸收层，其包含至少一种IR吸收组分和至少一种聚合物有机粘合剂，并在IR激光器的作用下分解 辐射或变化，使得其与硅酮顶层的粘合力降低，而顶层包含固化的硅橡胶。 衬底包括可氧化金属或其合金之一，并且至少在面向IR吸收层的一侧被粗糙化并被金属氧化物层覆盖。 本发明还涉及一种生产无水胶版印刷版和印刷版本身的方法，该印刷版本身是由根据本发明的记录材料生产的，其中氧化物层的亲水表面是油墨携带和疏油性 顶层是防墨水的。

公开(公告)号：US5744272A

公开(公告)日：1998-04-28

申请号：US620951

申请日：1996-03-25

申请人： Andreas Elsaesser ,  Werner Frass ,  Fritz-Feo Grabley ,  Gabor Jerling

发明人： Andreas Elsaesser ,  Werner Frass ,  Fritz-Feo Grabley ,  Gabor Jerling

IPC分类号： G03G5/05 ,  G03G13/28

CPC分类号： G03G13/283 ,  G03G13/28 ,  G03G5/0535 ,  G03G5/0546

摘要： An electrophotographic recording material comprising: an electrically conductive base layer; a photoconductive layer which can be de-coated with alkaline solutions, the photoconductive layer comprising an organic photoconductor, a sensitizer and a binder comprising a mixture of: a) a copolymer comprising units composed of a first vinyl aromatic compound and units composed of maleic anhydride and/or a maleic partial ester, and b) a copolymer comprising units composed of a second vinyl aromatic compound and units of (meth)acrylic acid.

摘要翻译： 一种电子照相记录材料，包括：导电基底层; 可以用碱溶液去除的光电导层，光电导层包含有机光电导体，敏化剂和粘合剂，其包含以下混合物：a）包含由第一乙烯基芳族化合物组成的单元和由马来酸酐组成的单元的共聚物 和/或马来酸偏酯，和b）包含由第二乙烯基芳族化合物和（甲基）丙烯酸单元组成的单元的共聚物。