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    Method for hydrogenating benzene polycarboxylic acids or derivatives thereof by using a catalyst containing macropores
    1.
    发明授权
    Method for hydrogenating benzene polycarboxylic acids or derivatives thereof by using a catalyst containing macropores 有权

    公开(公告)号：US06284917B1

    公开(公告)日：2001-09-04

    申请号：US09581843

    申请日：2000-06-19

    申请人： Melanie Brunner ,  Arnd Böttcher ,  Boris Breitscheidel ,  Klaus Halbritter ,  Jochem Henkelmann ,  Lucien Thil ,  Rolf Pinkos

    发明人： Melanie Brunner ,  Arnd Böttcher ,  Boris Breitscheidel ,  Klaus Halbritter ,  Jochem Henkelmann ,  Lucien Thil ,  Rolf Pinkos

    IPC分类号： C07C6974

    CPC分类号： C08K5/12 ,  C07C51/36 ,  C07C67/303 ,  C07C69/75 ,  C07C2601/14 ,  C07C61/09

    摘要： A process for hydrogenating a benzenepolycarboxylic acid or a derivative thereof or a mixture of two or more thereof by bringing the benzenepolycarboxylic acid or the derivative thereof or the mixture of two or more thereof into contact with a hydrogen-containing gas is carried out in the presence of a catalyst which comprises as active metal at least one metal of transition group VIII of the Periodic Table alone or together with at least one metal of transition group I or VII of the periodic table applied to a support which contains macropores with the proviso that if dimethyl terephthalate is hydrogenated, the hydrogenation using a catalyst which comprises as active metal ruthenium either alone or together with at least one metal of transition group I, VII or VIII of the Periodic Table applied to a support, where the support has a mean pore diameter of at least 50 nm and a BET surface area of at most 30 m2/g and the amount of the active metal is from 0.01 to 30% by weight, based on the total weight of the catalyst, and the ratio of the surface areas of the active metal and the catalyst support is less than 0.05, and/or a catalyst which comprises as active metal ruthenium either alone or together with at least one metal of transition group I, VII or VIII of the Periodic Table in an amount of from 0.01 to 30% by weight, based on the total weight of the catalyst, applied to a support, where from 10 to 50% of the pore volume of the support is formed by macropores having a pore diameter in the range from 50 nm to 10,000 nm and from 50 to 90% of the pore volume of the support is formed by mesopores having a pore diameter in the range from 2 to 50 nm, where the sum of the pore volumes adds up to 100%, is excluded, and novel hydrogenation products, obtainable by hydrogenating benzenepolycarboxylic acid (derivatives) as well as their use as plasticizers in plastics.

    Preparation of sugar alcohols
    4.
    发明授权
    Preparation of sugar alcohols 失效
    制备糖醇

    公开(公告)号：US06177598B1

    公开(公告)日：2001-01-23

    申请号：US09283866

    申请日：1999-04-01

    申请人： Melanie Brunner ,  Boris Breitscheidel ,  Jochem Henkelmann ,  Arnd Böttcher

    发明人： Melanie Brunner ,  Boris Breitscheidel ,  Jochem Henkelmann ,  Arnd Böttcher

    IPC分类号： C07C29141

    CPC分类号： C07C29/132 ,  C07C31/26

    摘要： A process for the hydrogenation of a sugar or a mixture of two or more thereof comprises the following step: Bringing the sugar or the mixture of two or more thereof into contact with hydrogen in the presence of specific catalysts to give a sugar alcohol or a mixture of two or more thereof, wherein the catalyst comprises at least one metal of transition group VIII of the Periodic Table, either alone or together with at least one metal of transition group I or VII of the Periodic Table.

    摘要翻译： 糖或其两种或多种的混合物的氢化方法包括以下步骤：在特定催化剂存在下，使糖或其两种或多种的混合物与氢接触以得到糖醇或混合物 其中所述催化剂包含元素周期表中至少一种第Ⅷ族过渡金属，单独或与元素周期表中至少一种过渡族I或Ⅶ族金属一起。

    Reaction of organic compounds over macroporous supported catalysts comprising boron oxide
    5.
    发明授权
    Reaction of organic compounds over macroporous supported catalysts comprising boron oxide 失效
    有机化合物与包含氧化硼的大孔载体催化剂反应

    公开(公告)号：US06432861B1

    公开(公告)日：2002-08-13

    申请号：US09349082

    申请日：1999-07-08

    申请人： Boris Breitscheidel ,  Uwe Diehlmann ,  Alois Kindler ,  Jochem Henkelmann ,  Arnd Böttcher

    发明人： Boris Breitscheidel ,  Uwe Diehlmann ,  Alois Kindler ,  Jochem Henkelmann ,  Arnd Böttcher

    IPC分类号： C08F804

    CPC分类号： C08F8/04 ,  B01J21/02

    摘要： In a process for reacting an organic compound in the presence of a catalyst comprising, as active metal, at least one metal of transition group VIII of the Periodic Table, either alone or together with at least one metal of transition group I or VII of the Periodic Table, in an amount of from 0.01 to 30% by weight, based on the total weight of the catalyst, applied to a support containing macropores, the support comprises, as a support component, boron(III) oxide in an amount of from 10 to 100% by weight, based on the total weight of the support.

    摘要翻译： 在一种催化剂存在下使有机化合物反应的方法，该催化剂包含作为活性金属的至少一种元素周期表第VIII族金属，单独或与至少一种第 周期表，以基于催化剂总重量的0.01至30重量％的量施用于含有大孔的载体，载体包含作为载体组分的氧化硼（III），其量为 10至100重量％，基于载体的总重量。

    Selected cyclohexane -1,3-and -1,4-dicarboxylic acid esters
    6.
    发明授权
    Selected cyclohexane -1,3-and -1,4-dicarboxylic acid esters 有权
    选择的环己烷-1,3和-1,4-二羧酸酯

    公开(公告)号：US07208545B1

    公开(公告)日：2007-04-24

    申请号：US09959380

    申请日：2000-06-09

    申请人： Melanie Brunner ,  Lucien Thil ,  Boris Breitscheidel

    发明人： Melanie Brunner ,  Lucien Thil ,  Boris Breitscheidel

    IPC分类号： C08K5/12 ,  C07C69/74

    CPC分类号： C08K5/12 ,  B01J23/40 ,  B01J23/462 ,  B01J35/10 ,  C07C67/303 ,  C07C69/75

    摘要： Selected cyclohexane-1,3- and -1,4-dicarboxylic acid esters are described, as is their use as plasticizers in plastics and their preparation by hydrogenation of the corresponding isophthalic or terephthalic esters by bringing one or more of these isophthalic or terephthalic esters into contact with a hydrogen-containing gas in the presence of a catalyst which comprises, as active metal, at least one metal of the 8th transition group of the Periodic Table on its own or together with at least one metal of the 1st or 7th transition group of the Periodic Table, applied to a support, which comprises using a support having micropores.

    摘要翻译： 描述了选择的环己烷-1,3-和-1,4-二羧酸酯，它们在塑料中作为增塑剂的用途，以及通过使这些间苯二甲酸或对苯二甲酸酯中的一种或多种与对苯二甲酸或对苯二酸酯氢化制备 在催化剂存在下与含氢气体接触，该催化剂包含作为活性金属的元素周期表第8族过渡基团中的至少一种金属或与第一或第七转变体中的至少一种金属 包括使用具有微孔的载体的元素周期表。