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公开(公告)号:US06825162B2
公开(公告)日:2004-11-30
申请号:US10470046
申请日:2004-03-11
申请人: Menno Hazenkamp , Bryan David Grey , Kishor Kumar Mistry , Frank Bachmann , Josef Dannacher , Kenneth Charles Symes , Petr Kvita , Susanne Maier
发明人: Menno Hazenkamp , Bryan David Grey , Kishor Kumar Mistry , Frank Bachmann , Josef Dannacher , Kenneth Charles Symes , Petr Kvita , Susanne Maier
IPC分类号: C11D1100
CPC分类号: C11D3/168 , C11D3/0021 , C11D3/3932 , C11D3/3935 , C11D11/0082
摘要: Water soluble granules or particles of saldimine-type manganese complexes that are suitable as catalysts in reactions with peroxy compounds are described. The granules are used especially in washing agents. They are distinguished by retarded disssolution of and improved action of the manganese complexes.
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公开(公告)号:US07612010B2
公开(公告)日:2009-11-03
申请号:US11901660
申请日:2007-09-18
申请人: Gunther Schlingloff , Torsten Wieprecht , Uwe Heinz , Albert Schneider , Marie-Josée Dubs , Frank Bachmann , Menno Hazenkamp , Thomas Ehlis , Cornelia Vincenzi , Josef Dannacher
发明人: Gunther Schlingloff , Torsten Wieprecht , Uwe Heinz , Albert Schneider , Marie-Josée Dubs , Frank Bachmann , Menno Hazenkamp , Thomas Ehlis , Cornelia Vincenzi , Josef Dannacher
CPC分类号: C07D401/14 , C11D3/168 , C11D3/3932
摘要: Use of metal complex compounds of formula (1) and/or (1′) [LnMemXp]zYq (1), [L′nMemXp]zYq (1′), wherein all substituents are as defined in the claims, as catalysts for oxidation reactions, and also novel metal complex compounds and novel ligands.
摘要翻译: 使用式(1)和/或(1')[LnMemXp] zYq(1),[L'nMemXp] zYq(1')的金属配合物化合物,其中所有取代基如权利要求中所定义,作为氧化催化剂 反应,还有新型金属络合物和新配体。
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公开(公告)号:US06800775B1
公开(公告)日:2004-10-05
申请号:US10031999
申请日:2002-01-10
申请人: Frank Bachmann , Josef Dannacher , Menno Hazenkamp , Gunther Schlingloff , Grit Richter , Helena Dbaly , Rainer Hans Traber
发明人: Frank Bachmann , Josef Dannacher , Menno Hazenkamp , Gunther Schlingloff , Grit Richter , Helena Dbaly , Rainer Hans Traber
IPC分类号: C07F1502
CPC分类号: C11D3/168 , C07C251/24 , C11D3/3932
摘要: Novel metal complexes of tripoadal ligands are useful as catalysts to enhance the action of peroxygen compounds in washing, cleaning and disinfecting processes.
摘要翻译: 三元配体的新型金属络合物可用作增强过氧化合物在洗涤,清洁和消毒过程中的作用的催化剂。
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公开(公告)号:US20080262225A1
公开(公告)日:2008-10-23
申请号:US12214491
申请日:2008-06-19
申请人: Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josef Dannacher , Marie-Josee Dubs , Menno Hazenkamp , Grit Hansler (-Richter) , Brigitte Schmidt , Albert Schneider , Peter Weingartner
发明人: Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josef Dannacher , Marie-Josee Dubs , Menno Hazenkamp , Grit Hansler (-Richter) , Brigitte Schmidt , Albert Schneider , Peter Weingartner
IPC分类号: C07D401/14 , C07D413/14
CPC分类号: B01J31/1815 , B01J23/34 , B01J2231/70 , B01J2231/72 , B01J2531/16 , B01J2531/46 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07D213/61 , C07D213/68 , C07D213/74 , C07F13/005 , C11D3/3932 , D06L4/10 , D06L4/12 , D06P5/02 , D06P5/153 , D21C9/1036 , D21C9/163
摘要: Use of metal complex compounds of formula [LnMemXp]zYq, (1) wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q=z/(charge Y), and L is a ligand of formula wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1-C18alkyl or aryl; cyano; halogen; nitro; —COOR12 or —SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; —SR13, —SO2R13 or —OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl; —N(R13)—NR′13R″13 wherein R13, R′13 and R″13 are as defined above for R13; —NR14R15 or —N⊕R14R15R16 wherein R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are not simultaneously hydrogen, as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1) and the novel ligands of formula (2).
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公开(公告)号:US20060100123A1
公开(公告)日:2006-05-11
申请号:US10520841
申请日:2003-07-03
申请人: Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josef Dannacher , Marie-Josee Dubs , Menno Hazenkamp , Uwe Heinz , Markus Frey , Albert Schneider
发明人: Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josef Dannacher , Marie-Josee Dubs , Menno Hazenkamp , Uwe Heinz , Markus Frey , Albert Schneider
IPC分类号: C11D3/00
CPC分类号: C11D3/168 , C07D213/68 , C07D213/74 , C11D3/3932
摘要: Use of metal complex compounds of formula (1) [LnMcmXp]zYq wherein Mc is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q=z/(charge Y), and L is a ligand of formula (2) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen: unsubstituted or substituted C1-C18alkyl or aryl; cyano; halogen; nitro; —COOR12 or —SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl: —SR13, —SO12R13 or —OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl; —NR14R15; —(C1-C6alkylene)-NR14R15; —NoR14R15R16; —(C1-C6alkylene)-NoR14R15R16; —N(R)15)—(C1-C6alkylene)-NR1R15; —N[(C1-C6alkylene)-NR14R15]2; —N(R13)—(C1-C6alkylene)-NoR14R15R16, —N[C1-C6alkylene)-NoR14R15R16]2; —N(R13)—N—R14R15 or —N(R13)—NoR14R15R16: wherein R13 is as defined above and R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further heterotatoms; with the proviso that (i) at least one of the substituents R1—R11 contains a quaternized atom which is not directly bonded to one of the three pyridine A, B or C and that (ii) Y is neither I′ nor Cl′ in the case that Me is Mn(II), R1—R5 and R7—R11 are hydrogen and R6 is formula (III) as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1), the novel ligands of formula (2) and their starting materials.
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公开(公告)号:US07692004B2
公开(公告)日:2010-04-06
申请号:US12214491
申请日:2008-06-19
申请人: Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josef Dannacher , Marie-Josée Dubs , Menno Hazenkamp , Grit Hänsler (-Richter) , Brigitte Schmidt , Albert Schneider , Peter Weingartner
发明人: Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josef Dannacher , Marie-Josée Dubs , Menno Hazenkamp , Grit Hänsler (-Richter) , Brigitte Schmidt , Albert Schneider , Peter Weingartner
CPC分类号: B01J31/1815 , B01J23/34 , B01J2231/70 , B01J2231/72 , B01J2531/16 , B01J2531/46 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07D213/61 , C07D213/68 , C07D213/74 , C07F13/005 , C11D3/3932 , D06L4/10 , D06L4/12 , D06P5/02 , D06P5/153 , D21C9/1036 , D21C9/163
摘要: Use of metal complex compounds of formula [LnMemXp]zYq (1), wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q=z/(charge Y), and L is a ligand of formula wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1-C18alkyl or aryl; cyano; halogen; nitro; —COOR12 or —SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; —SR13, —SO2R13 or —OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl; —N(R13)—NR′13R″13 wherein R13, R′13 and R″13 are as defined above for R13; —NR14R15 or —N⊕R14R15R16 wherein R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are not simultaneously hydrogen, as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1) and the novel ligands of formula (2).
摘要翻译: 使用式[LnMemXp] zYq(1)的金属络合物,其中Me是锰,钛,铁,钴,镍或铜,X是配位或桥连基团,n和m各自独立地为具有 值为1〜8,p为0〜32的整数,z为金属络合物的电荷,Y为抗衡离子,q = z /(电荷Y),L为 其中R 1,R 2,R 3,R 4,R 5,R 6,R 7,R 8,R 9,R 10和R 11各自独立地为氢; 未取代或取代的C 1 -C 18烷基或芳基; 氰基; 卤素; 硝基 -COOR 12或-SO 3 R 12,其中R 12在各种情况下为氢,阳离子或未取代或取代的C 1 -C 18烷基或芳基; -SR 13,-SO 2 R 13或-OR 13,其中R 13各自为氢或未取代或取代的C 1 -C 18烷基或芳基; -N(R 13)-NR'13R“13其中R 13,R 13和R 13如对R 13所定义; -NR14R15或-N⊕R14R15R16,其中R14,R15和R16各自独立地为氢或未取代或取代的C1-C18烷基或芳基,或者R14和R15与其键合的氮原子一起形成未取代或取代的5 可以任选地含有其它杂原子的6-或7-元环; 条件是R 1,R 2,R 3,R 4,R 5,R 6,R 7,R 8,R 9,R 10和R 11不同时为氢,作为氧化反应的催化剂,并且式(1)和新颖的新型金属络合物 式(2)的配体。
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公开(公告)号:US07494964B2
公开(公告)日:2009-02-24
申请号:US10520841
申请日:2003-07-03
申请人: Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josef Dannacher , Marie-Josée Dubs , Menno Hazenkamp , Uwe Heinz , Markus Frey , Albert Schneider
发明人: Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josef Dannacher , Marie-Josée Dubs , Menno Hazenkamp , Uwe Heinz , Markus Frey , Albert Schneider
CPC分类号: C11D3/168 , C07D213/68 , C07D213/74 , C11D3/3932
摘要: The present invention relates to the use of metal complex compounds which have terpyridine ligands and contain at least one quaternized nitrogen atom as oxidation catalysts. The present invention relates also to formulations comprising such metal complex compounds, to novel metal complex compounds and to novel ligands.
摘要翻译: 本发明涉及具有三联吡啶配位体并含有至少一个季铵化氮原子的金属络合物作为氧化催化剂的用途。 本发明还涉及包含这种金属络合物的制剂,新颖的金属络合物和新配体。
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公开(公告)号:US20070032656A1
公开(公告)日:2007-02-08
申请号:US11520398
申请日:2006-09-13
申请人: Gunther Schlingloff , Torsten Wieprecht , Uwe Heinz , Albert Schneider , Marie-Josee Dubs , Frank Bachmann , Menno Hazenkamp , Thomas Ehlis , Cornelia Vincenzi , Josef Dannacher
发明人: Gunther Schlingloff , Torsten Wieprecht , Uwe Heinz , Albert Schneider , Marie-Josee Dubs , Frank Bachmann , Menno Hazenkamp , Thomas Ehlis , Cornelia Vincenzi , Josef Dannacher
IPC分类号: C07D211/32
CPC分类号: C07D401/14 , C11D3/168 , C11D3/3932
摘要: Use of metal complex compounds of formula (1) and/or (1′) [LnMemXp]zYq (1), [L′nMemXp]zYq (1′),wherein all substituents are as defined in the claims, as catalysts for oxidation reactions, and also novel metal complex compounds and novel ligands.
摘要翻译: 使用式(1)和/或(1')的金属络合物化合物<?in-line-formula description =“In-line Formulas”end =“lead”?> [L> n (1),&lt;&lt;行内公式描述=“In” -line公式“end =”tail“?> <?in-line-formula description =”In-line Formulas“end =”lead“?> [L' i> (1'),<?in-line-formula description =“在线公式” 其中所有取代基如权利要求中所定义,作为用于氧化反应的催化剂,以及新型金属络合物和新型配体。
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公开(公告)号:US20060264633A1
公开(公告)日:2006-11-23
申请号:US11497444
申请日:2006-08-01
申请人: Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josef Dannacher , Marie-Josee Dubs , Menno Hazenkamp , Grit Hansler (-Richter) , Brigitte Schmidt , Albert Schneider , Peter Weingartner
发明人: Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josef Dannacher , Marie-Josee Dubs , Menno Hazenkamp , Grit Hansler (-Richter) , Brigitte Schmidt , Albert Schneider , Peter Weingartner
CPC分类号: B01J31/1815 , B01J23/34 , B01J2231/70 , B01J2231/72 , B01J2531/16 , B01J2531/46 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07D213/61 , C07D213/68 , C07D213/74 , C07F13/005 , C11D3/3932 , D06L4/10 , D06L4/12 , D06P5/02 , D06P5/153 , D21C9/1036 , D21C9/163
摘要: Use of metal complex compounds of formula [LnMemXp]zYq (1), wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q=z/(charge Y), and L is a ligand of formula wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11, are each independently of the others hydrogen; unsubstituted or substituted C1-C18alkyl or aryl; cyano; halogen; nitro; —COOR12 or —SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; —SR13, —SO2R13 or —OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl; —N(R13)—NR′13R″13 wherein R13, R′13 and R″13 are as defined above for R13; —NR14R15 or —N⊕R14R15R16 wherein R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are not simultaneously hydrogen, as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1) and the novel ligands of formula (2).
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公开(公告)号:US06689733B1
公开(公告)日:2004-02-10
申请号:US09914911
申请日:2001-09-05
申请人: Frank Bachmann , Rachel Allemann , Josef Dannacher , Marie-Josée Dubs , Cornelia Makowka , Grit Richter , Gunther Schlingloff , Peter Weingartner , Menno Hazenkamp
发明人: Frank Bachmann , Rachel Allemann , Josef Dannacher , Marie-Josée Dubs , Cornelia Makowka , Grit Richter , Gunther Schlingloff , Peter Weingartner , Menno Hazenkamp
IPC分类号: C11D320
CPC分类号: C07F13/005 , C07C251/24 , C07C2601/14 , C11D3/168 , C11D3/3932
摘要: The present invention relates to novel manganese complexes of salen ligands and the use thereof as catalysts that enhance the action of peroxy compounds in washing, cleaning, and disinfecting processes.
摘要翻译: 本发明涉及新型的salen配体的锰络合物及其作为催化剂的用途,其可增强洗涤,清洗和消毒过程中过氧化合物的作用。
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