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8 条记录 (耗时 0.038 秒)

    Synthesis method of metal cyclopentadienide in bulk
    5.
    发明授权
    Synthesis method of metal cyclopentadienide in bulk 有权
    大量金属环戊二烯的合成方法

    公开(公告)号：US08057714B2

    公开(公告)日：2011-11-15

    申请号：US12515819

    申请日：2007-11-02

    申请人： Yong gyu Han ,  Ki-soo Lee ,  Heon-yong Kwon ,  Jong-sang Park ,  Nicola Maggiarosa

    发明人： Yong gyu Han ,  Ki-soo Lee ,  Heon-yong Kwon ,  Jong-sang Park ,  Nicola Maggiarosa

    IPC分类号： C07F1/00

    CPC分类号： C07F17/00 ,  C07F1/00 ,  C07F1/04

    摘要： The present invention relates to a synthesis method of metal cyclopentadienide by direct reaction of dicyclopentadiene with a group 1 metal in the presence of an aprotic solvent. Unlike the conventional method depending on retro Diels-Alder reaction of dicyclopentadiene to generate indirectly cyclopentadiene, the method of the present invention favors generation of cyclopentadiene and metal cyclopentadienide as well by adding dicyclopentadiene directly when the reaction temperature reaches to the boiling point of a reaction solvent.

    摘要翻译： 本发明涉及金属环戊二烯的合成方法，其通过在非质子溶剂的存在下二环戊二烯与第1族金属直接反应。 不同于依靠二环戊二烯的Diels-Alder反应产生间接环戊二烯的常规方法，当反应温度达到反应溶剂的沸点时，本发明的方法也有利于环戊二烯和环戊二烯金属的生成，直接加入二环戊二烯 。

    Synthesis Method Of Metal Cyclopentadienide In Bulk
    6.
    发明申请
    Synthesis Method Of Metal Cyclopentadienide In Bulk 有权
    金属环戊二烯的体积合成方法

    公开(公告)号：US20100096762A1

    公开(公告)日：2010-04-22

    申请号：US12515819

    申请日：2007-11-02

    申请人： Yong-gyu Han ,  Ki-soo Lee ,  Heon-yong Kwon ,  Jong-sang Park ,  Nicola Maggiarosa

    发明人： Yong-gyu Han ,  Ki-soo Lee ,  Heon-yong Kwon ,  Jong-sang Park ,  Nicola Maggiarosa

    IPC分类号： C07F1/04 ,  C07F1/06

    CPC分类号： C07F17/00 ,  C07F1/00 ,  C07F1/04

    摘要： The present invention relates to a synthesis method of metal cyclopentadienide by direct reaction of dicyclopentadiene with a group 1 metal in the presence of an aprotic solvent. Unlike the conventional method depending on retro Diels-Alder reaction of dicyclopentadiene to generate indirectly cyclopentadiene, the method of the present invention favors generation of cyclopentadiene and metal cyclopentadienide as well by adding dicyclopentadiene directly when the reaction temperature reaches in the boiling point of a reaction solvent.

    摘要翻译： 本发明涉及金属环戊二烯的合成方法，其通过在非质子溶剂的存在下二环戊二烯与第1族金属直接反应。 不同于依靠二环戊二烯复古Diels-Alder反应产生间接环戊二烯的常规方法，当反应温度达到反应溶剂的沸点时，本发明的方法也有利于生成环戊二烯和金属环戊二烯，直接加入二环戊二烯 。

    Preparation of tri-alkyl gallium or tri-alkyl indium compounds
    7.
    发明授权
    Preparation of tri-alkyl gallium or tri-alkyl indium compounds 有权
    三烷基镓或三烷基铟化合物的制备

    公开(公告)号：US08513447B1

    公开(公告)日：2013-08-20

    申请号：US13744522

    申请日：2013-01-18

    申请人： Nicola Maggiarosa ,  Angelika Preetz ,  David J. Sikora

    发明人： Nicola Maggiarosa ,  Angelika Preetz ,  David J. Sikora

    IPC分类号： C07F1/00

    CPC分类号： C07F5/00

    摘要： Trialkyl metal compounds, such as trialkyl gallium and indium compounds, are prepared in high yield and high purity by the addition of a trialkyl aluminum compound to a mixture prepared by adding a metal trihalide, e.g., GaCl3 or InCl3, and a halide salt of a monovalent metal to an ionic liquid such as a molten salt of the formula M[AlRnX(4-n)] wherein M is a monovalent metal such as Li, Na, K or Cs, R is an alkyl group X is a halide and n is a number from 1 to 3, typically at temperatures of from 75 to 160° C.

    摘要翻译： 三烷基金属化合物，例如三烷基镓和铟化合物，通过将三烷基铝化合物加入到通过加入金属三卤化物如GaCl 3或InCl 3制备的混合物中，以高产率和高纯度制备三烷基金属化合物， 一价金属对离子液体如式M [AlRnX（4-n）]的熔融盐，其中M是一价金属如Li，Na，K或Cs，R是烷基X是卤化物，n 是1至3的数，通常在75至160℃的温度

    Preparation of Tri-Alkyl Gallium or Tri-Alkyl Indium Compounds
    8.
    发明申请
    Preparation of Tri-Alkyl Gallium or Tri-Alkyl Indium Compounds 有权
    三烷基镓或三烷基铟化合物的制备

    公开(公告)号：US20130197252A1

    公开(公告)日：2013-08-01

    申请号：US13744522

    申请日：2013-01-18

    申请人： Nicola Maggiarosa ,  Angelika Preetz ,  David J. Sikora

    发明人： Nicola Maggiarosa ,  Angelika Preetz ,  David J. Sikora

    IPC分类号： C07F5/00

    CPC分类号： C07F5/00

    摘要： Trialkyl metal compounds, such as trialkyl gallium and indium compounds, are prepared in high yield and high purity by the addition of a trialkyl aluminum compound to a mixture prepared by adding a metal trihalide, e.g., GaCl3 or InCl3, and a halide salt of a monovalent metal to an ionic liquid such as a molten salt of the formula M[AlRn X(4-n)] wherein M is a monovalent metal such as Li, Na, K or Cs, R is an alkyl group X is a halide and n is a number from 1 to 3, typically at temperatures of from 75 to 160° C.

    摘要翻译： 三烷基金属化合物，例如三烷基镓和铟化合物，通过将三烷基铝化合物加入到通过加入金属三卤化物如GaCl 3或InCl 3制备的混合物中，以高产率和高纯度制备三烷基金属化合物， 一价金属与离子液体如式M [AlRn X（4-n）]的熔融盐，其中M为一价金属如Li，Na，K或Cs，R为烷基X为卤化物， n为1至3的数，通常为75至160℃。