摘要:
There are provided a polymer electrolyte membrane having at least one surface with an average surface roughness Ra′ of from 30 nm to 500 nm and a surface area ratio Sr of 1.2 or more in which Sr is defined as S/S0 with S0 representing a surface area when the at least one surface is ideally flat and S representing an actual surface area of the at least one surface, and a polymer electrolyte fuel cell comprising the polymer electrolyte membrane. Thereby, a polymer electrolyte fuel cell is provided that improves the efficiency of contact between the polymer electrolyte membrane and the catalyst, efficiently separates hydrogen ions and electrons produced on the catalyst, and provides high output characteristics.
摘要:
The membrane electrode assembly of the present invention for the proton-exchange membrane fuel cell includes a polymer electrolyte membrane and an electrode catalyst layer, wherein at least a part of the polymer electrolyte membrane infiltrates into the electrode catalyst layer, and wherein the polymer electrolyte membrane is formed by polymerizing a composition containing at least a compound having proton conductivity and a compound having activity to an active energy ray, or a composition containing at least a compound having proton conductivity and activity to the active energy ray. The object of the present invention is to provide a membrane electrolyte assembly for realizing a high-output proton-exchange membrane fuel cell by improving a bonding state between the polymer electrolyte membrane and the electrode catalyst layer to reduce an internal resistance, and by providing a three-dimensional three-phase interface to increase reaction areas.
摘要:
There are provided a polymer electrolyte membrane having at least one surface with an average surface roughness Ra′ of from 30 nm to 500 nm and a surface area ratio Sr of 1.2 or more in which Sr is defined as S/S0 with S0 representing a surface area when the at least one surface is ideally flat and S representing an actual surface area of the at least one surface, and a polymer electrolyte fuel cell comprising the polymer electrolyte membrane. Thereby, a polymer electrolyte fuel cell is provided that improves the efficiency of contact between the polymer electrolyte membrane and the catalyst, efficiently separates hydrogen ions and electrons produced on the catalyst, and provides high output characteristics.
摘要翻译:提供了具有至少一个平均表面粗糙度Ra'为30nm至500nm并且表面积比Sr为1.2或更大的表面积比Sr的聚合物电解质膜,其中Sr定义为S / S < / SUB>,其表示当所述至少一个表面理想地平坦且S表示所述至少一个表面的实际表面积时的表面积,以及包含所述聚合物电解质的聚合物电解质燃料电池 膜。 由此,提供了提高高分子电解质膜与催化剂的接触效率的高分子电解质型燃料电池,能有效地分离在催化剂上产生的氢离子和电子,提供高输出特性。
摘要:
An electrolyte membrane made of a phosphate-containing siloxane-based polymer for fuel cell, where the polymer comprises a siloxane backbone and a poly(meth)acrylate chain to which phosphate groups are attached, and the polymer is formed by vinyl polymerization of a silane compound having a (meth)acrylate functional group or a hydrolysis-polycondensation product thereof and a (meth)acrylate compound having a phosphate group, followed by siloxane crosslinking. The electrolyte membrane of a siloxane-based polymer has a high conductivity for a fuel cell.
摘要:
An electrolyte membrane made of a phosphate-containing siloxane-based polymer for fuel cell, where the polymer comprises a siloxane backbone and a poly(meth)acrylate chain to which phosphate groups are attached, and the polymer is formed by vinyl polymerization of a silane compound having a (meth)acrylate functional group or a hydrolysis-polycondensation product thereof and a (meth)acrylate compound having a phosphate group, followed by siloxane crosslinking. The electrolyte membrane of a siloxane-based polymer has a high conductivity for a fuel cell.
摘要:
In a manufacturing process for a fuel cell having a fuel electrode, an oxidizer electrode, and a polymer electrolyte membrane held between both the electrodes, and having electrode catalyst layers which are individually provided between both the electrodes and the polymer electrolyte membrane, the process has the step of ejecting an electrode catalyst composition containing conductive particles carrying thereon at least a catalyst, by an ink-jet process to form the electrode catalyst layers. This provides a fuel cell manufacturing process which can accurately control the coverage of catalyst layers and also can simply provide pores while controlling the same.
摘要:
Provided is a method of producing an optical film which has an excellent strength and a low refractive index, and can be used for an optical antireflective film. The production method includes preparing a coating liquid including a capsule having a shell of a halogenated compound of an element of Group 2 by forming an emulsion of one of an aqueous solution including a compound containing an element of Group 2 and an aqueous solution including a compound containing a halogen, and an organic solvent, applying the coating liquid on a substrate, and heating the coating liquid, thereby forming an optical film containing a hollow particle having the shell of a halogenated compound of an element of Group 2.
摘要:
Provided is a method of producing an optical film which has an excellent strength and a low refractive index, and can be used for an optical antireflective film. The production method includes preparing a coating liquid including a capsule having a shell of a halogenated compound of an element of Group 2 by forming an emulsion of one of an aqueous solution including a compound containing an element of Group 2 and an aqueous solution including a compound containing a halogen, and an organic solvent, applying the coating liquid on a substrate, and heating the coating liquid, thereby forming an optical film containing a hollow particle having the shell of a halogenated compound of an element of Group 2.
摘要:
A method of producing a magnesium fluoride coating includes a step of forming a coating by applying a solution containing a fluorine-containing organic magnesium compound represented by the following formula to a base and a step of heat-treating the coating while the coating is being irradiated with a beam of light with a wavelength of 246 nm or less: Mg(CF3—X—COO)2 (1) wherein X represents a single bond or one of —(CF2)n—, —(CH2)m—, and —CH2CF2— that may have a substituent, where n and m each represent an integer of 1 to 4. The temperature of the heat-treating step can be 250° C. or lower. The coating can be irradiated with a beam of light with a wavelength of 185 nm or less.
摘要:
A coating liquid including a fluorine-containing organic magnesium compound represented by the following chemical formula (1), a method for manufacturing an optical component having an optical film obtained from the coating liquid, and a photographic optical system are disclosed: Mg(OR11)(OR22) Chemical formula (1) where R11 represents an alkyl group that may have a substituent group having 1 or more and 6 or less carbon atoms having at least a fluorine atom, R22 represents an alkyl group that may have a substituent group having 1 or more and 6 or less carbon atoms that may have a fluorine atom, or an aromatic cyclic group that may have a substituent group, and R11 is different from R22.