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公开(公告)号：US4551546A
公开(公告)日：1985-11-05
申请号：US551697
申请日：1983-11-14
Applicant: Nazim Punja
Inventor： Nazim Punja
IPC: A01N53/00 , A01N53/06 , C07C17/26 , C07C29/10 , C07C29/14 , C07C29/147 , C07C33/46 , C07C43/23 , C07C45/00 , C07C51/15 , C07C63/68 , C07C63/70 , C07C63/72 , C07C63/74 , C07C69/743 , C07C69/753 , C07D309/12 , C07C69/74
CPC classification number: C07C17/269 , A01N53/00 , C07C17/2632 , C07C29/10 , C07C29/14 , C07C29/147 , C07C317/00 , C07C323/00 , C07C43/23 , C07C45/00 , C07C51/15 , C07D309/12
Abstract: This invention relates to novel cyclopropane derivatives useful as insecticides, to processes for their preparation, to compositions comprising them and to methods of combatting insect and similar invertebrate pests using them.
Abstract translation: 本发明涉及可用作杀虫剂的新型环丙烷衍生物，其制备方法，包含它们的组合物以及使用它们对抗昆虫和类似无脊椎动物害虫的方法。
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2.发明授权
公开(公告)号：US4405640A
公开(公告)日：1983-09-20
申请号：US211943
申请日：1980-12-01
Applicant: Nazim Punja
Inventor： Nazim Punja
IPC: C07C69/747 , A01N53/00 , A01N53/06 , A01N53/08 , C07C17/26 , C07C27/00 , C07C29/10 , C07C29/128 , C07C29/14 , C07C29/147 , C07C33/46 , C07C41/00 , C07C43/23 , C07C45/00 , C07C47/55 , C07C51/15 , C07C63/70 , C07C63/72 , C07C63/74 , C07C67/00 , C07C67/14 , C07C69/743 , C07C215/68 , C07C219/32 , C07C233/25 , C07C313/00 , C07C315/04 , C07C317/14 , C07C317/22 , C07C323/19 , C07D309/12
CPC classification number: A01N53/00 , C07C17/2632 , C07C17/269 , C07C29/10 , C07C29/14 , C07C29/147 , C07C317/00 , C07C323/00 , C07C43/23 , C07C45/00 , C07C47/55 , C07C63/70 , C07C63/72 , C07C63/74 , C07C69/743 , C07D309/12 , C07C2101/02
Abstract: Insecticides of the formula ##STR1## wherein R.sup.1 and R.sup.2 are each selected from methyl, halomethyl, and halo; X is oxygen, sulphur, sulphonyl or a group NR.sup.4 where R.sup.4 represents hydrogen, lower alkyl or lower carboxylic acyl; R.sup.3 is lower alkyl, lower alkenyl or benzyl; m has the value zero or one, and n has a value from one to four.
Abstract translation: 式IMA的杀虫剂，其中R1和R2各自选自甲基，卤代甲基和卤素; X是氧，硫，磺酰基或基团NR4，其中R4代表氢，低级烷基或低级羧酰基; R3是低级烷基，低级烯基或苄基; m的值为零或1，n的值为1到4。
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公开(公告)号：US4486355A
公开(公告)日：1984-12-04
申请号：US488434
申请日：1983-04-25
Applicant: Philip D. Bentley , Nazim Punja
Inventor： Philip D. Bentley , Nazim Punja
IPC: C07C69/747 , A01N29/10 , A01N31/04 , A01N35/04 , A01N37/10 , A01N37/34 , A01N37/38 , A01N53/00 , A01N53/06 , C07C17/00 , C07C17/14 , C07C17/26 , C07C25/13 , C07C45/00 , C07C49/80 , C07C49/807 , C07C49/82 , C07C51/15 , C07C61/40 , C07C63/70 , C07C67/00 , C07C67/03 , C07C67/08 , C07C67/11 , C07C67/14 , C07C69/743 , C07C69/76 , C07C69/78 , C07C201/00 , C07C205/12 , C07C205/42 , C07C253/00 , C07C255/32 , C07C255/49 , C07C255/50 , C07C255/53 , C07C255/55 , C07C121/52 , C07C49/327
CPC classification number: C07C205/12 , A01N53/00 , C07C17/14 , C07C17/263 , C07C17/266 , C07C61/40
Abstract: Compounds of formula I wherein R.sup.1 and R.sup.2 are each selected from halomethyl and halo and R is nitro, cyano, lower alkoxycarbonyl, lower alkylcarbonyl, or di- or trifluoromethyl, and n has a value of zero to four, and compositions comprising them are useful as insecticides in agriculture, horticulture and other outlets. They may optionally be combined with other pesticides and/or synergists. The compounds may be prepared by conventional esterification processes from the corresponding acids and appropriately substituted benzyl alcohols or halides, some of which are novel. ##STR1##
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公开(公告)号：US4298616A
公开(公告)日：1981-11-03
申请号：US197681
申请日：1980-10-16
Applicant: Nazim Punja , William G. Rathmell
Inventor： Nazim Punja , William G. Rathmell
IPC: A01N43/08 , C07D307/68 , C07D307/71 , C07D307/73
CPC classification number: C07D307/71 , C07D307/68
Abstract: This invention relates to alkynyl acylanilide derivatives useful as pesticides, to a process for preparing them, to pesticidal compositions containing them, and to a method of combating pests using them.
Abstract translation: 本发明涉及可用作杀虫剂的炔基酰基酰苯胺衍生物，其制备方法，含有它们的杀虫组合物，以及使用它们的防治害虫的方法。
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公开(公告)号：US4091110A
公开(公告)日：1978-05-23
申请号：US786394
申请日：1977-04-11
Applicant: Nazim Punja
Inventor： Nazim Punja
Abstract: Compounds of the formula ##STR1## wherein R.sup.1 represents a branched lower alkyl radical; R.sup.2 represents a phenyl group optionally substituted with halogeno or lower alkyl radicals; R.sup.3 and R.sup.4 represent halogeno radicals; and R.sup.5 represents a hydrogen atom or the cyano radical. These compounds are useful as insecticides.
Abstract translation: 其中R 1表示支链低级烷基的式“IMAGE”的化合物; R 2表示任选被卤代或低级烷基取代的苯基; R3和R4代表卤代基; R 5表示氢原子或氰基。 这些化合物可用作杀虫剂。
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公开(公告)号：US4310464A
公开(公告)日：1982-01-12
申请号：US702732
申请日：1976-07-06
Applicant: Winston Costain , Bernard W. H. Terry , Nazim Punja , Peter J. V. Cleare
Inventor： Winston Costain , Bernard W. H. Terry , Nazim Punja , Peter J. V. Cleare
IPC: A01N43/08 , C07C51/00 , C07C51/58 , C07C57/52 , C07C57/76 , C07C67/00 , C07C69/65 , C07C69/743 , C07C69/747 , C07C253/00 , C07C255/23 , C07C255/48 , C07D307/33 , C07D307/32
CPC classification number: C07D307/33 , C07C51/58 , C07C57/52
Abstract: 4-.beta., .beta.-dichlorovinyl (or dibromovinyl)-3,3-dimethylbutyrolactones are prepared from 1,1-dichloro (or dibromo)-4-methylpenta-1,3-diene by reacting with an acid of formula CH.sub.2 R.CO.sub.2 H in presence of a salt of a metal in one of its higher valency states, especially manganese (III), cerium (IV), or vanadium (V). Higher yields are obtained in the presence of the anhydride of the acid and of the sodium or potassium salt of the acid. Treatment of the lactones with an inorganic acid halide opens the lactone ring with formation of the corresponding 4-haloacid halide, which with alcohols affords the corresponding 4-haloacid ester, cyclised by bases to a 3-.beta.,.beta.-dichloro (or dibromo)vinyl-2,2-dimethylcyclopropanecarboxylic ester, intermediate for insecticides such as the m-phenoxybenzyl ester.
Abstract translation: 由1,1-二氯（或二溴）-4-甲基戊-1,3-二烯通过与式CH2R.CO2H的酸反应制备4-β，β-二氯乙烯基（或二溴乙烯基）-3,3-二甲基丁内酯 在其较高价态之一，特别是锰（III），铈（IV）或钒（V）之一中存在金属盐。 在酸的酸酐和酸的钠盐或钾盐的存在下获得更高的产率。 用无机酰卤处理内酯，形成相应的4-卤代卤化物，使其与醇反应，形成相应的4-卤代酸酯，通过碱环化为3-β，β-二氯（或二溴） 乙烯基-2,2-二甲基环丙烷羧酸酯，间苯氧基苄基酯等杀虫剂的中间体。
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7.发明授权Process for preparing 2-dihalovinyl-3,3-dimethyl cyclo propane derivatives 失效制备2-二羟基-3,3-二甲基环丙烷衍生物的方法
公开(公告)号：US4000180A
公开(公告)日：1976-12-28
申请号：US601495
申请日：1975-08-04
Applicant: Nazim Punja
Inventor： Nazim Punja
IPC: C07C17/363 , C07C20060101 , C07C17/00 , C07C23/04 , C07C67/00 , C07C69/74 , C07C69/743 , C07C253/00 , C07C255/45 , C07C255/48 , C07C120/00
CPC classification number: C07C255/00 , C07C45/673
Abstract: A process for the preparation of a compound of formula: ##STR1## wherein X is chlorine or bromine, and Q is selected from the group consisting of cyano, acetyl and alkoxycarbonyl which comprises the step of heating a compound of formula: ##STR2## wherein R is a lower alkyl group, for a period of from one to 30 hours, at a temperature in the range 130.degree. to 200.degree. C in a polar aprotic solvent in the presence of at least two molar equivalents of water.
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公开(公告)号：US3987079A
公开(公告)日：1976-10-19
申请号：US638283
申请日：1975-12-05
Applicant: Ian Trevor Kay , Nazim Punja
Inventor： Ian Trevor Kay , Nazim Punja
IPC: C25B3/04 , C07C43/28 , C07C121/75
CPC classification number: C25B3/04 , C07C45/565
Abstract: Compounds of the formula ##SPC1##Wherein X is halogen or hydroxy; R.sup.3 and R.sup.4 represent halogen radicals; and R.sup.5 represents a hydrogen atom or the cyano radical. These compounds are used in the preparation of pesticidal cyclopropane carboxylates.
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公开(公告)号：US4385070A
公开(公告)日：1983-05-24
申请号：US116597
申请日：1980-01-28
Applicant: Philip D. Bentley , Nazim Punja
Inventor： Philip D. Bentley , Nazim Punja
IPC: C07C69/747 , A01N29/10 , A01N31/04 , A01N35/04 , A01N37/10 , A01N37/34 , A01N37/38 , A01N53/00 , A01N53/06 , C07C17/00 , C07C17/14 , C07C17/26 , C07C25/13 , C07C45/00 , C07C49/80 , C07C49/807 , C07C49/82 , C07C51/15 , C07C61/40 , C07C63/70 , C07C67/00 , C07C67/03 , C07C67/08 , C07C67/11 , C07C67/14 , C07C69/743 , C07C69/76 , C07C69/78 , C07C201/00 , C07C205/12 , C07C205/42 , C07C253/00 , C07C255/32 , C07C255/49 , C07C255/50 , C07C255/53 , C07C255/55
CPC classification number: C07C205/12 , A01N53/00 , C07C17/14 , C07C17/263 , C07C17/266 , C07C61/40
Abstract: Compounds of formula I wherein R.sup.1 and R.sup.2 are each selected from halomethyl and halo and R is nitro, cyano, lower alkoxycarbonyl, lower alkylcarbonyl, or di- or trifluoromethyl, and n has a value of zero to four, and compositions comprising them are useful as insecticides in agriculture, horticulture and other outlets. They may optionally be combined with other pesticides and/or synergists. The compounds may be prepared by conventional esterification processes from the corresponding acids and appropriately substituted benzyl alcohols or halides, some of which are novel. ##STR1##
Abstract translation: 式I化合物，其中R 1和R 2各自为卤代甲基和卤素，R为硝基，氰基，低级烷氧基羰基，低级烷基羰基或二 - 或三氟甲基，n为0至4，其组成为有用的 作为农药，园艺等渠道的杀虫剂。 它们可以任选地与其他农药和/或增效剂组合。 化合物可以通过常规酯化方法由相应的酸和适当取代的苄醇或卤化物制备，其中一些是新的。
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公开(公告)号：US4257975A
公开(公告)日：1981-03-24
申请号：US78834
申请日：1979-09-25
Applicant: Nazim Punja
Inventor： Nazim Punja
IPC: C07C69/743 , B01J23/00 , B01J23/44 , B01J31/00 , B01J31/02 , C07C20060101 , C07C43/12 , C07C67/00 , C07C69/52 , C07C69/63 , C07C69/74 , C07C253/00 , C07C255/45 , C07C255/48 , C07C121/16 , C07C121/20
CPC classification number: C07C255/00
Abstract: A compound of the formula: ##STR1## wherein X and Y are independently selected from cyano and alkoxycarbonyl containing from 1 to 4 carbon atoms in the alkoxy group, and Q, R and Z are independently selected from chlorine and bromine provided that Q is always bromine when either Z or R is bromine. The compounds are useful as chemical intermediates.
Abstract translation: 下式的化合物，其中X和Y独立地选自氰基和烷氧基中含有1至4个碳原子的烷氧基羰基，Q，R和Z独立地选自氯和溴，条件是Q总是 当Z或R为溴时，溴。 这些化合物可用作化学中间体。
