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公开(公告)号：US5212120A
公开(公告)日：1993-05-18
申请号：US900667
申请日：1992-06-19
摘要： A photosensitive borosilicate glass which consists essentially in calculated weight percent on an oxide basis of 20-80% SiO.sub.2, 8-40% B.sub.2 O.sub.3, 0-6% Li.sub.2, 0-28% Na.sub.2, 0-25% K.sub.2 O, the total Na.sub.2 O+K.sub.2 O being 10-28%, 0-18% Al.sub.2 O.sub.3 and minor amounts of photosensitizing agents silver, cerium oxide, antimony oxide and bromine and/or chlorine, the cation ratio of R.sub.2 O--Al.sub.2 O.sub.3 to B.sub.2 O.sub.3 being at least 0.6.
摘要翻译： 感光硼硅酸盐玻璃，其基本上以基于20-80％SiO 2，8-40％B 2 O 3，0-6％Li 2，0-28％Na 2，0-25％K 2 O的氧化物计算的重量百分比组成，总Na 2 O + K2O为10-28％，0-18％Al2O3和少量光敏剂银，氧化铈，氧化锑和溴和/或氯，R2O-Al2O3与B2O3的阳离子比至少为0.6。
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公开(公告)号：US06773635B2
公开(公告)日：2004-08-10
申请号：US09793368
申请日：2001-02-26
IPC分类号： H01B102
CPC分类号： C09K9/00 , C03C3/112 , C03C14/006 , H01B1/08
摘要： Materials, both glass and glass-ceramic, that exhibit UV-induced changes in light transmission and electrical conductivity behavior. The materials consist essentially, in mole %, of 20-40% SiO2, 10-20% AlO1.5, 35-55% SiO2+AlO1.5, at least 30% CdF2, 0-20% PbF2, and/or ZnF2, 0-15% rare earth metal fluoride, and 45-65% total metal fluorides.
摘要翻译： 材料，玻璃和玻璃陶瓷，表现出UV诱导的光透射和导电性能的变化。 材料基本上以摩尔％计，20-40％的SiO2，10-20％的AlO1.5,35-55％的SiO2 + AlO1.5，至少30％的CdF2，0-20％的PbF2和/或ZnF2 ，0-15％稀土金属氟化物和45-65％总金属氟化物。
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公开(公告)号：US6158246A
公开(公告)日：2000-12-12
申请号：US155238
申请日：1998-09-22
IPC分类号： C03C15/00 , C03B27/012 , C03C14/00 , C03C17/06 , C03C17/09 , C03C17/245 , C03C23/00 , C09D1/00 , C03B37/00 , C03C17/00 , C03C25/02
CPC分类号： C03C17/245 , C03C14/006 , C03C17/06 , C03C17/09 , C03C23/00 , C03C2214/08 , C03C2217/216 , C03C2217/25 , C03C2218/151 , C03C2218/152 , C03C2218/154 , C03C2218/328 , C03C2218/355
摘要： Method of patterning or forming color gradients and/or designs on a glass surface are disclosed. Patterns are formed by depositing a film of metal on at least one surface of the glass; forming a layer of photoresist over the metal; exposing the article to light through a mask which contains a desired pattern; developing the piece to remove the exposed photoresist to reveal the underlying metal; removing the underlying metal to reveal the underlying glass; and removing the unexposed photoresist to reveal the underlying metal. To form color gradients or color patterns, the glass article is further treated in hydrogen at a temperature in the range of 300-600.degree. C. to effect the desired surface coloration.
摘要翻译： PCT No.PCT / US97 / 04973 Sec。 371日期：1998年9月22日 102（e）日期1998年9月22日PCT 1997年3月25日PCT公布。 公开号WO97 / 37946 日期1997年10月16日公开了在玻璃表面上图案化或形成色彩渐变和/或设计的方法。 通过在玻璃的至少一个表面上沉积金属膜形成图案; 在金属上形成光致抗蚀剂层; 通过包含所需图案的面罩将物品曝光; 显影该片以除去暴露的光致抗蚀剂以露出下面的金属; 去除下面的金属以露出下面的玻璃; 并除去未曝光的光致抗蚀剂以露出下面的金属。 为了形成色彩渐变或颜色图案，玻璃制品在氢气中在300-600℃的温度下进一步处理以实现所需的表面着色。
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公开(公告)号：US5019538A
公开(公告)日：1991-05-28
申请号：US434222
申请日：1989-11-13
摘要： This invention is directed to photosensitively opacifiable glasses consisting essentially, in weight percent, of about 14-18% Na.sub.2 O, 0-6% Zno, 6-12% Al.sub.2 O.sub.3, 0-5% B.sub.2 O.sub.3, 0-0.2% Sb.sub.2 O.sub.3, 0-0.1% SnO, 65-72% SiO.sub.2, and 0.007-0.04% Ag, 0.008-0.05% CeO.sub.2, 0.7-1.25% Br, and 1.5-2.5% F as analyzed in the glass, the sum of those components constituting at least 90% of the total composition, which, through an exposure to ultraviolet radiation, followed by a three-step heat treatment, and then a re-exposure to ultraviolet radiation at an elevated temperature, can be converted into a colored opal glass.
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公开(公告)号：US06917474B2
公开(公告)日：2005-07-12
申请号：US10385082
申请日：2003-03-10
CPC分类号： G02B3/0075 , G02B3/0012 , G02B3/005 , G02B3/0056
摘要： A lens array and a method for fabricating a lens array that is relatively flat and has useful lenses with relatively uniform sag heights are described herein. In one embodiment, the lens array includes a one-dimensional array of useful lens and two sacrificial lens each of which is formed next to an end of a row of the useful lenses. In another embodiment, the lens array includes a two-dimensional array of useful lens and a plurality of perimeter sacrificial lens each of which is formed next to an end of a row or a column of the useful lenses. In yet another embodiment, the lens array includes an array of useful lenses and a glass region (including possibly a glass matrix) located within a opal border and outside a opal region that surrounds the useful lenses.
摘要翻译： 这里描述了一种透镜阵列和一种制造相对平坦且具有相对均匀凹陷高度的有用透镜的透镜阵列的方法。 在一个实施例中，透镜阵列包括有用透镜的一维阵列和两个牺牲透镜，每个牺牲透镜形成在一行有用透镜的一端的旁边。 在另一个实施例中，透镜阵列包括有用透镜的二维阵列和多个周边牺牲透镜，每个透镜阵列邻近有用透镜的一行或一列的端部形成。 在另一个实施例中，透镜阵列包括有用透镜的阵列和位于蛋白石边界内的玻璃区域（可能包括玻璃基体），以及围绕有用透镜的蛋白石区域外部。
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公开(公告)号：US06298691B1
公开(公告)日：2001-10-09
申请号：US09403712
申请日：1999-10-21
IPC分类号： C03C1500
CPC分类号： C03C21/001 , C03C3/11 , C03C14/006 , C03C21/005 , C03C23/002 , C03C23/007 , C03C2214/08 , C03C2214/16 , C03C2214/30
摘要： Method is disclosed for making glass having both polarizing and non-polarizing regions integral thereto by either ion-exchange or by exposure to light and heat. The polarizing regions of the resulting glass is effective in polarizing light radiation, that is, the glass exhibits permanent dichroic behavior and has at least some polarizing effect in the wavelength range of 400 to 700 nm. The base glass composition contains Cu, Ag and at least one halide such that the resulting precipitated crystal phase consists of a halide.
摘要翻译： 公开了通过离子交换或通过暴露于光和热来制造具有与其成一体的偏振和非偏振区域的玻璃的方法。 所得到的玻璃的偏振区域有效地使光线偏振，即玻璃呈现永久的二色性，并且在400〜700nm的波长范围内具有至少一些偏光效果。 基础玻璃组合物含有Cu，Ag和至少一种卤化物，使得所得沉淀的结晶相由卤化物组成。
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公开(公告)号：US5275979A
公开(公告)日：1994-01-04
申请号：US969388
申请日：1992-10-30
CPC分类号： C03C4/02 , C03C14/006 , C03C3/11 , C03C2214/16
摘要： Thermally induced color is developed in a glass article containing a silver halide crystal phase by including in the glass batch a thermal reducing agent, retaining the thermal reducing agent in its lower valence state while meltinq the batch and forming the glass article and subsequently heat treating the article to partially reduce the silver halide crystal phase.
摘要翻译： 在含有卤化银结晶相的玻璃制品中，通过在玻璃批料中包含热还原剂，将热还原剂保持在其低价态，同时熔化批料并形成玻璃制品，然后热处理 制品部分还原卤化银晶相。
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公开(公告)号：US4710430A
公开(公告)日：1987-12-01
申请号：US729965
申请日：1985-05-03
CPC分类号： C03C23/007 , C03C21/002 , C03C4/06 , Y10S430/163
摘要： This invention is directed to a method for modifying the coloration produced in a silver halide-containing photochromic glass when heat treating the glass at a temperature not exceeding 450.degree. C. under reducing conditions. The method comprises subjecting such a glass having a base composition which contains at least 1% by weight Li.sub.2 O, at least 2% by weight Na.sub.2 O, and at least 6% by weight Li.sub.2 O+Na.sub.2 O+K.sub.2 O to an ion exchange reaction, wherein lithium ions, and potassium ions, when the latter are present in the composition, in the glass surface are exchanged with sodium ions from an external source, prior to the reduction heat treatment.
摘要翻译： 本发明涉及一种用于在还原条件下在不超过450℃的温度下热处理玻璃时，改变在含卤化银的光致变色玻璃中产生的着色的方法。 该方法包括将具有至少1重量％Li 2 O，至少2重量％Na 2 O和至少6重量％Li 2 O + Na 2 O + K 2 O的基础组合物的玻璃进行离子交换反应，其中锂离子 ，并且当还原热处理之前，在组合物中存在的钾离子在玻璃表面中与钠离子从外部源交换。
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公开(公告)号：US5449645A
公开(公告)日：1995-09-12
申请号：US296450
申请日：1994-08-26
CPC分类号： C03C14/006 , C03C2214/16
摘要： This invention is directed to the production of glass bodies containing crystallites of PbS and/or PbSe. The crystallite-containing bodies are formed by the thermal crystallization in situ of glass bodies having compositions essentially free from CdO and consisting essentially, expressed in terms of weight percent on the oxide basis except for fluorine, sulfur, and selenium which are expressed in terms of weight percent on the elemental basis, of______________________________________ SiO.sub.2 58-65 RO 0-15 Na.sub.2 O 10-15 F 1-3.5 ZnO 5-17 S 0-3 Al.sub.2 O.sub.3 0.5-5 Se 0-3 PbO 3-6 S + Se 1-3 ______________________________________ wherein RO consists of at least one alkaline earth metal oxide in the indicated proportions selected from the group consisting of 0-5% BeO, 0-5% MgO, 0-15% CaO, 0-10% SrO, and 0-10% BaO.
摘要翻译： 本发明涉及生产含有PbS和/或PbSe微晶的玻璃体。 含微晶体的物质是通过基本上不含CdO的组成的玻璃体进行热结晶而形成的，并且基本上以氧化物的重量百分数表示，除了氟，硫和硒之外，其以 重量百分比的基础上，SiO2 58-65 RO 0-15 - Na2O 10-15 F 1-3.5 - ZnO 5-17 S 0-3 - Al2O3 0.5-5 Se 0-3 - PbO 3-6 S + Se 1-3 - 其中RO由至少一种选自0-5％BeO，0-5％MgO，0-15％CaO，0-10％SrO的指定比例的碱土金属氧化物组成 ，0-10％BaO。
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公开(公告)号：US5062877A
公开(公告)日：1991-11-05
申请号：US506078
申请日：1990-04-09
CPC分类号： G02B3/0018 , C03C21/002 , G02B6/1245 , G02B2006/12183 , Y10S359/90
摘要： This invention is directed to a method of forming optical devices composed of a photonucleable, crystallizable, lithium silicate glass body having at least one glass lens integral with and rising above at least one surface thereof, the lens being surrounded by a crystallized glass matrix, and optical devices produced by such method. The inventive method comprises subjecting the crystallized body to an ion exchange reaction wherein sodium and/or potassium ions from an external source are exchanged for lithium ions within the surface of the glass lens, the exchange reaction being conducted at a temperature of about 25.degree.-125.degree. C. above the annealing point of the glass for a time sufficient to produce a lens having an axial height in excess of 100% greater than that of lenses produced solely by selectively crystallizing a photonucleable, lithium silicate glass body.
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