Process for preparing transition metal-carbene complexes
    2.
    发明授权
    Process for preparing transition metal-carbene complexes 有权
    制备过渡金属 - 碳烯配合物的方法

    公开(公告)号:US08410280B2

    公开(公告)日:2013-04-02

    申请号:US12162863

    申请日:2007-01-09

    IPC分类号: C07F15/00

    摘要: Process for preparing cyclometallated transition metal-carbene complexes comprising at least one carbene ligand, which comprises reacting a ligand precursor with a base, an auxiliary reagent and a metal complex comprising at least one metal M1 (route A) or reacting the ligand precursor with a basic auxiliary reagent and a metal complex comprising at least one metal M1 (route B). The present invention further relates to the use of an auxiliary reagent selected from among salts comprising at least one metal selected from the group consisting of Ag, Hg, Sb, Mg, B and Al together with a base in a process for preparing cyclometallated metal complexes.

    摘要翻译: 制备包含至少一个卡宾配体的环金属化过渡金属 - 卡宾络合物的方法,其包括使配体前体与碱,辅助试剂和包含至少一种金属M1(路线A)的金属络合物反应或使配体前体与 碱性助剂和包含至少一种金属M1(路线B)的金属络合物。 本发明还涉及在制备环金属化金属络合物的方法中使用选自包含选自Ag,Hg,Sb,Mg,B和Al中的至少一种金属的盐的辅助试剂与碱一起使用 。

    PROCESS FOR PREPARING TRANSITION METAL-CARBENE COMPLEXES
    4.
    发明申请
    PROCESS FOR PREPARING TRANSITION METAL-CARBENE COMPLEXES 有权
    制备过渡金属碳复合物的方法

    公开(公告)号:US20090018330A1

    公开(公告)日:2009-01-15

    申请号:US12162863

    申请日:2007-01-09

    IPC分类号: C07F15/00

    摘要: Process for preparing cyclometallated transition metal-carbene complexes comprising at least one carbene ligand, which comprises reacting a ligand precursor with a base, an auxiliary reagent and a metal complex comprising at least one metal M1 (route A) or reacting the ligand precursor with a basic auxiliary reagent and a metal complex comprising at least one metal M1 (route B). The present invention further relates to the use of an auxiliary reagent selected from among salts comprising at least one metal selected from the group consisting of Ag, Hg, Sb, Mg, B and Al together with a base in a process for preparing cyclometallated metal complexes.

    摘要翻译: 制备包含至少一个卡宾配体的环金属化过渡金属 - 卡宾络合物的方法,其包括使配体前体与碱,辅助试剂和包含至少一种金属M1(路线A)的金属络合物反应或使配体前体与 碱性助剂和包含至少一种金属M1(路线B)的金属络合物。 本发明还涉及在制备环金属化金属络合物的方法中使用选自包含选自Ag,Hg,Sb,Mg,B和Al中的至少一种金属的盐的辅助试剂与碱一起使用 。