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    Method for the Isomerisation of Transition Metal Complexes Containing Cyclometallated, Carbene Ligands
    3.
    发明申请
    Method for the Isomerisation of Transition Metal Complexes Containing Cyclometallated, Carbene Ligands 有权

    公开(公告)号：US20080200686A1

    公开(公告)日：2008-08-21

    申请号：US11916455

    申请日：2006-06-13

    申请人： Oliver Molt ,  Klaus Kahle

    发明人： Oliver Molt ,  Klaus Kahle

    IPC分类号： C07F19/00 ,  C07F15/00

    CPC分类号： C07F15/0033

    摘要： The present invention relates to a process for converting an isomerically pure compound C1 of the formula I or a mixture M1 comprising C1 into an isomeric compound C2 of the formula I which is different from C1 or a mixture M2 comprising C2, where the variables have the following meanings: n is 2 or 3; M is Pd or Pt, in each case in the formal oxidation state +II, when n is 2; and is Ru, Os, Co, Rh or Ir, in each case in the formal oxidation state +III, when n is 3; Do is a donor atom selected from the group consisting of N, O, S and P; r is 1 when Do is N or P, and is 0 when Do is O or S; Y1, Y2 are each, independently of one another, hydrogen, alkyl, alkenyl, alkynyl, aryl, heteroaryl, alkyloxy, aryloxy, alkylthio, arylthio, alkylcarbonyl, arylcarbonyl, carboxyl, alkyloxycarbonyl, aryloxycarbonyl, hydroxysulfonyl, alkyloxysulfonyl, aryloxysulfonyl, halogen, CN, CHO, NO2 or NO, or Y1 and Y2 together with the carbon atom to which they are bound form a six-membered aromatic ring which may comprise one or two nitrogen atoms and may optionally be fused with a further, optionally fused and optionally hetero-atom-comprising ring; Y3 is alkyl, alkenyl, alkynyl, aryl or heteroaryl; A is a bridge having three or four atoms of which one or two atoms may be heteroatoms and the remaining atoms are carbon atoms, so that the group forms a five- or six-membered heteroaromatic ring or benzene ring which may optionally be substituted by substituents selected from the group consisting of alkyl, alkenyl, alkynyl, aryl, heteroaryl, alkyloxy, aryloxy, alkylthio, arylthio, alkylcarbonyl, arylcarbonyl, carboxyl, alkyloxycarbonyl, aryloxycarbonyl, hydroxysulfonyl, alkyloxysulfonyl, aryloxysulfonyl, halogen, CN, CHO, NO2 and NO and may optionally be fused with a further, optionally heteroatom-comprising ring which may likewise be fused and substituted by substituents selected from the group consisting of alkyl, alkenyl, alkynyl, aryl, heteroaryl, alkyloxy, aryloxy, alkylthio, arylthio, alkylcarbonyl, arylcarbonyl, carboxyl, alkyloxycarbonyl, aryloxycarbonyl, hydroxysulfonyl, alkyloxysulfonyl, aryloxysulfonyl, halogen, CN, CHO, NO2 and NO; which comprises allowing a Brönsted acid or a mixture of Brönsted acids to act on C1 or M1 in the presence of a solvent or solvent mixture at a temperature of from 0° C. to the boiling point of the solvent or the solvent mixture, with the proviso that a) the formation of C2 from C1 occurs under the conditions of the process and b) when both M1 and M2 are mixtures comprising C1 and C2, the respective isomer ratios of C1 and C2 in the mixtures M1 and M2 are different from one another.

    USE OF ACRIDINE DERIVATIVES AS MATRIX MATERIALS AND/OR ELECTRON BLOCKERS IN OLEDS
    6.
    发明申请
    USE OF ACRIDINE DERIVATIVES AS MATRIX MATERIALS AND/OR ELECTRON BLOCKERS IN OLEDS 有权
    在OLED中作为基质材料和/或电子阻挡剂使用吡啶衍生物

    公开(公告)号：US20100219406A1

    公开(公告)日：2010-09-02

    申请号：US12681023

    申请日：2008-09-26

    申请人： Klaus Kahle ,  Oliver Molt ,  Nicolle Langer ,  Christian Lennartz ,  Christian Schildknecht ,  Simon Nord ,  Evelyn Fuchs ,  Jens Rudolph

    发明人： Klaus Kahle ,  Oliver Molt ,  Nicolle Langer ,  Christian Lennartz ,  Christian Schildknecht ,  Simon Nord ,  Evelyn Fuchs ,  Jens Rudolph

    IPC分类号： H01L51/54 ,  H01L51/52

    CPC分类号： H01L51/0072 ,  H01L51/0061 ,  H01L51/0085 ,  H01L51/5016 ,  H01L51/5096

    摘要： The present invention relates to the use of (hetero)aryl-substituted acridine derivatives as matrix materials in a light-emitting layer of organic light-emitting diodes (OLEDs) and/or in a blocking layer for electrons in organic light-emitting diodes. The present invention further relates to a light-emitting layer which comprises at least one emitter material and at least one matrix material, wherein the matrix material used is at least one (hetero)aryl-substituted acridine derivative, and to an organic light-emitting diode which comprises at least one inventive light-emitting layer, to an organic light-emitting diode which comprises at least one acridine derivative of the formula (I) in a blocking layer for electrons, and to a device selected from stationary and mobile visual display units and illumination units which comprise at least one inventive organic light-emitting diode.

    摘要翻译： 本发明涉及在有机发光二极管（OLED）的发光层和/或有机发光二极管中的电子阻挡层中使用（杂）芳基取代的吖啶衍生物作为基质材料。 本发明还涉及包含至少一种发射体材料和至少一种基质材料的发光层，其中使用的基质材料是至少一种（杂）芳基取代的吖啶衍生物，并且涉及有机发光 包括至少一个本发明的发光层的二极管与包含至少一种式（I）的吖啶衍生物的有机发光二极管在用于电子的阻挡层中，以及选自固定和移动视觉显示的装置 单元和照明单元，其包括至少一个本发明的有机发光二极管。

    PROCESS FOR PREPARING TRANSITION METAL-CARBENE COMPLEXES
    9.
    发明申请
    PROCESS FOR PREPARING TRANSITION METAL-CARBENE COMPLEXES 有权
    制备过渡金属碳复合物的方法

    公开(公告)号：US20090018330A1

    公开(公告)日：2009-01-15

    申请号：US12162863

    申请日：2007-01-09

    申请人： Oliver Molt ,  Evelyn Fuchs ,  Martina Egen ,  Klaus Kahle ,  Christian Lennartz

    发明人： Oliver Molt ,  Evelyn Fuchs ,  Martina Egen ,  Klaus Kahle ,  Christian Lennartz

    IPC分类号： C07F15/00

    CPC分类号： C07F15/0033 ,  B01J31/2265 ,  C07F15/0073 ,  C07F15/0086

    摘要： Process for preparing cyclometallated transition metal-carbene complexes comprising at least one carbene ligand, which comprises reacting a ligand precursor with a base, an auxiliary reagent and a metal complex comprising at least one metal M1 (route A) or reacting the ligand precursor with a basic auxiliary reagent and a metal complex comprising at least one metal M1 (route B). The present invention further relates to the use of an auxiliary reagent selected from among salts comprising at least one metal selected from the group consisting of Ag, Hg, Sb, Mg, B and Al together with a base in a process for preparing cyclometallated metal complexes.

    摘要翻译： 制备包含至少一个卡宾配体的环金属化过渡金属 - 卡宾络合物的方法，其包括使配体前体与碱，辅助试剂和包含至少一种金属M1（路线A）的金属络合物反应或使配体前体与 碱性助剂和包含至少一种金属M1（路线B）的金属络合物。 本发明还涉及在制备环金属化金属络合物的方法中使用选自包含选自Ag，Hg，Sb，Mg，B和Al中的至少一种金属的盐的辅助试剂与碱一起使用 。