公开(公告)号：US20140206909A1

公开(公告)日：2014-07-24

申请号：US14127866

申请日：2012-06-21

申请人： Paolo Calaresu ,  Elena Bencini ,  Alessandro Casalini ,  Alessandro Del Seppia ,  Giovanni Antonio Fois

发明人： Paolo Calaresu ,  Elena Bencini ,  Alessandro Casalini ,  Alessandro Del Seppia ,  Giovanni Antonio Fois

IPC分类号： C07C2/86 ,  C07C37/08

CPC分类号： C07C2/864 ,  C07C29/143 ,  C07C37/08 ,  C07C45/53 ,  C07C2529/70 ,  Y02P20/52 ,  Y02P20/582 ,  C07C15/073 ,  C07C15/06 ,  C07C15/107 ,  C07C15/085 ,  C07C15/08 ,  C07C39/04 ,  C07C49/08 ,  C07C31/10

摘要： Process for the alkylation of aromatic hydrocarbons by means of aliphatic alcohols containing from 1 to 8 carbon atoms, which comprises feeding the hydrocarbon and alcohol to the head of a fixed-bed reactor, operating with “trickle flow” regime, containing at least one layer of a catalyst comprising a zeolite selected from medium-pore zeolites and large-pore zeolites.

摘要翻译： 用于通过含有1至8个碳原子的脂族醇烷基化芳族烃的方法，该方法包括将烃和醇进料到固定床反应器的头部，以“滴流”方式操作，其包含至少一层 包含选自中孔沸石和大孔沸石的沸石的催化剂。

公开(公告)号：US20140142348A1

公开(公告)日：2014-05-22

申请号：US14127421

申请日：2012-06-21

申请人： Paolo Calaresu ,  Alessandro Del Seppia ,  Elena Bencini ,  Giovanni Antonio Fois ,  Alessandro Casalini

发明人： Paolo Calaresu ,  Alessandro Del Seppia ,  Elena Bencini ,  Giovanni Antonio Fois ,  Alessandro Casalini

IPC分类号： C07C2/66 ,  C07C37/08

CPC分类号： C07C2/66 ,  C07C29/143 ,  C07C37/08 ,  C07C45/53 ,  C07C2529/70 ,  Y02P20/52 ,  Y02P20/582 ,  C07C15/085 ,  C07C15/107 ,  C07C15/073 ,  C07C39/04 ,  C07C49/08 ,  C07C31/10

摘要： Process for the alkylation of aromatic hydrocarbons by means of olefins containing from 2 to 8 carbon atoms, which comprises feeding the hydrocarbon, olefin, and possibly water, to the head of a fixed-bed reactor, operating with a “trickle flow” regime, containing at least one layer of a catalyst comprising a medium- or large-pore zeolite.

摘要翻译： 通过含有2-8个碳原子的烯烃烷基化芳族烃的方法，该方法包括将烃，烯烃和可能的水进料到以“滴流”方式运行的固定床反应器的头部， 含有至少一层包含中孔或大孔沸石的催化剂。

公开(公告)号：US09096488B2

公开(公告)日：2015-08-04

申请号：US14127866

申请日：2012-06-21

申请人： Paolo Calaresu ,  Elena Bencini ,  Alessandro Casalini ,  Alessandro Del Seppia ,  Giovanni Antonio Fois

发明人： Paolo Calaresu ,  Elena Bencini ,  Alessandro Casalini ,  Alessandro Del Seppia ,  Giovanni Antonio Fois

IPC分类号： C07C37/08 ,  C07C45/53 ,  C07C2/86 ,  C07C29/143

CPC分类号： C07C2/864 ,  C07C29/143 ,  C07C37/08 ,  C07C45/53 ,  C07C2529/70 ,  Y02P20/52 ,  Y02P20/582 ,  C07C15/073 ,  C07C15/06 ,  C07C15/107 ,  C07C15/085 ,  C07C15/08 ,  C07C39/04 ,  C07C49/08 ,  C07C31/10

摘要： Process for the alkylation of aromatic hydrocarbons by means of aliphatic alcohols containing from 1 to 8 carbon atoms, which comprises feeding the hydrocarbon and alcohol to the head of a fixed-bed reactor, operating with “trickle flow” regime, containing at least one layer of a catalyst comprising a zeolite selected from medium-pore zeolites and large-pore zeolites.

摘要翻译： 用于通过含有1至8个碳原子的脂族醇烷基化芳族烃的方法，该方法包括将烃和醇进料到固定床反应器的头部，以“滴流”方式操作，其包含至少一层 包含选自中孔沸石和大孔沸石的沸石的催化剂。

公开(公告)号：US09012696B2

公开(公告)日：2015-04-21

申请号：US14127421

申请日：2012-06-21

申请人： Paolo Calaresu ,  Alessandro Del Seppia ,  Elena Bencini ,  Giovanni Antonio Fois ,  Alessandro Casalini

发明人： Paolo Calaresu ,  Alessandro Del Seppia ,  Elena Bencini ,  Giovanni Antonio Fois ,  Alessandro Casalini

IPC分类号： C07C37/08 ,  C07C2/66 ,  C07C29/143 ,  C07C45/53

CPC分类号： C07C2/66 ,  C07C29/143 ,  C07C37/08 ,  C07C45/53 ,  C07C2529/70 ,  Y02P20/52 ,  Y02P20/582 ,  C07C15/085 ,  C07C15/107 ,  C07C15/073 ,  C07C39/04 ,  C07C49/08 ,  C07C31/10

摘要： Process for the alkylation of aromatic hydrocarbons by means of olefins containing from 2 to 8 carbon atoms, which comprises feeding the hydrocarbon, olefin, and possibly water, to the head of a fixed-bed reactor, operating with a “trickle flow” regime, containing at least one layer of a catalyst comprising a medium-or large-pore zeolite.

摘要翻译： 通过含有2-8个碳原子的烯烃烷基化芳族烃的方法，该方法包括将烃，烯烃和可能的水进料到以“滴流”方式运行的固定床反应器的头部， 含有至少一层包含中孔或大孔沸石的催化剂。

公开(公告)号：US10525429B2

公开(公告)日：2020-01-07

申请号：US14116046

申请日：2012-04-27

申请人： Alessandro Del Seppia ,  Elena Ghirardo

发明人： Alessandro Del Seppia ,  Elena Ghirardo

IPC分类号： B01J8/22 ,  C07C249/04 ,  B01J8/10 ,  B01J8/00

摘要： Ammoximation reactor for cyclohexanone oxime production comprising: (a) a reactor vessel provided with a stirrer; (b) an internal filtering system; (c) an internal liquid ammonia evaporation coil; (d) an internal gaseous ammonia toroidal distributor; (e) an external cyclohexanone toroidal distributor; (f) an internal hydrogen peroxide toroidal distributor; (g) an internal cylindrical draft tube; (h) an external cooling jacket. Said ammoximation reactor allows to obtain a better mixing of the components of the ammoximation reaction and to maximize both the heat-transfer coefficients and the mass-transfer coefficients. Moreover, said ammoximation reactor allows to increase the packing time of the catalyst used in the ammoximation reaction on the filtering system (i.e. the plugging phenomena) so as to avoid the necessity of carrying out the backwashings with nitrogen. Moreover, said ammoximation reactor does not require external downstream separation units to separate the catalyst from the reaction mixture obtained from the ammoximation reaction.