摘要:
The present invention relates to a process for oligomerization/polymerization of ethylene and/or alpha-olefins, comprising the steps of oligomerizing/polymerizing ethylene and/or alpha-olefins to produce a reaction product which contains undesired reaction by-products, separating the reaction by-product from the reaction product as one or more reaction by-product fractions, and subjecting at least one of the reaction by-product fractions to steam cracking to produce a steam cracking product which comprises ethylene, which may be optionally purified and feed to the oligomerization/polymerization of ethylene and/or alpha olefins step.
摘要:
The present invention relates to a process for oligomerization/polymerization of ethylene and/or alpha-olefins, comprising the steps of oligomerizing/polymerizing ethylene and/or alpha-olefins to produce a reaction product which contains undesired reaction by-products, separating the reaction by-product from the reaction product as one or more reaction by-product fractions, and subjecting at least one of the reaction by-product fractions to steam cracking to produce a steam cracking product which comprises ethylene, which may be optionally purified and feed to the oligomerization/polymerization of ethylene and/or alpha olefins step.
摘要:
The present invention relates to a method for preparing linear alpha-olefins by oligomerizing of ethylene in the presence of an organic solvent and a homogenous catalyst, characterized in that the method is carried out in a reactor being fed with a gaseous feed comprising a minor amount of ethylene and a major amount of an inert gas.
摘要:
The invention relates to a homogeneous catalyst for the production of linear alpha-olefins by oligomerisation of ethylene, consisting of a zirconium salt of organic acids and a cocatalyst which consists of alkylaluminiums and/or aluminium chloride. The activity of the catalyst, system may sometimes be raised substantially by adjusting the molar ratio of chlorine to aluminium in the cocatalyst within the range between 1.0 and 1.5. The economic viability of the production process and product purity are improved.
摘要:
The present invention relates to a method for processing high molecular weight oligomer waste products formed during the production of linear alpha-olefins by oligomerization of ethylene in a reactor in the presence of a solvent and a catalyst, characterized in that the high molecular weight oligomers are separated in a separation unit from a product stream of the reactor comprising the solvent, the catalyst, linear alpha-olefins and high molecular weight oligomers having a solidification temperature in the range of about 60-100° C., then diluted with a dilution medium and heated to about 130° C. to about 200° C., the diluted high molecular weight oligomers are then transferred to a disposal device, wherein at least some of the dilution medium may be recovered and recycled for addition to the dilution medium.
摘要:
The present invention relates to a method for preparing linear alpha-olefins by oligomerisation of ethylene, comprising the steps of: (i) oligomerising ethylene in a reactor in the presence of a solvent and a catalyst; (ii) transferring a liquid organic outlet stream of the reactor, containing solvent, catalyst, dissolved ethylene and linear alpha-olefins, to a catalyst deactivation section; (iii) deactivating the catalyst by washing the outlet stream with an aqueous basic phase to obtain a deactivated catalyst containing aqueous phase and a water saturated organic phase; (iv) separating the aqueous phase and the organic phase from step (iii); (v) transferring the water saturated organic phase to a distillation column; (vi) distilling the water saturated organic phase; and (vii) separating the distilled organic and aqueous phases.
摘要:
The present invention relates to a method for preparing linear alpha-olefins by oligomerizing of ethylene in the presence of a first organic solvent and a homogenous catalyst in a reactor, characterized in that the reactor overhead is cooled by means of a refrigerant.
摘要:
The present invention relates to a method for preparing linear alpha-olefins by oligomerizing of ethylene in the presence of a first organic solvent and a homogenous catalyst in a reactor, characterized in that the reactor overhead is cooled by means of a refrigerant.
摘要:
The present invention relates to a method for the deactivation of an organometallic catalyst in the product stream from an oligomerization reactor for the production of linear alpha-olefin, characterized in that the catalyst-containing product stream of the reactor is subjected to a temperature of at least 160° C. in a heating device. A reactor system for the method of the invention is also disclosed.
摘要:
The present invention relates to a method for cleaning a reactor having a tendency of fouling by deposition of solids, wherein a hot solvent, in which the solids are soluble and which has a temperature of at least about 75° C., is applied to the reactor, the solids being substantially dissolved and the dissolved solids being discharged from the reactor, wherein the method is carried out without opening the reactor to atmosphere.