摘要:
The invention relates to a process for production of fatty acids directly from soapstock generated in the alkali refining process including the steps of (a) adding a lipase directly to the alkaline soapstock to facilitate hydrolysis of glycerides without prior neutralisation, (b) neutralizing and splitting the soaps with strong acids, and (c) separating the fatty acid phase from the aqueous phase by settling and/or centrifugation. A second embodiment is a process in which the soapstock is first neutralized and split with strong acids, followed by adding a lipase to facilitate glyceride hydrolysis, and separating the fatty acid phase. The fatty acids so obtained can be esterified with C1-C6 alcohols using a lipase that is selective for fatty acids and does not transesterify the sterolesters, and the fatty acid esters and sterolesters are separated by distillation.The sterolesters are useful as supplements for food, as pharmaceutical agents for lowering cholesterol and as biofuel and biodiesel.
摘要:
The invention relates to a process for production of fatty acids directly from soapstock generated in the alkali refining process including the steps of (a) adding a lipase directly to the alkaline soapstock to facilitate hydrolysis of glycerides without prior neutralization, (b) neutralizing and splitting the soaps with strong acids, and (c) separating the fatty acid phase from the aqueous phase by settling and/or centrifugation. A second embodiment is a process in which the soapstock is first neutralized and split with strong acids, followed by adding a lipase to facilitate glyceride hydrolysis, and separating the fatty acid phase. The fatty acids so obtained can be esterified with C1-C6 alcohols using a lipase that is selective for fatty acids and does not transesterify the sterolesters, and the fatty acid esters and sterolesters are separated by distillation.The sterolesters are useful as supplements for food, as pharmaceutical agents for lowering cholesterol and as biofuel and biodiesel.
摘要:
The disclosed invention provides a process for obtaining fatty acid alkyl esters, rosin acids and sterols from crude tall oil (CTO), characterised in that the CTO is subjected to the following steps: (a) reacting the free fatty acids present in the CTO with lower alcohols; (b) separating the fatty acid lower alkyl esters thus obtained from the remaining CTO to produce a first stream of fatty acid esters; (c) esterifying the sterols in the remaining CTO with boric acid; (d) separating the remaining rosin acids from the sterol borates previously obtained to produce a second stream of rosin acids; and (e) converting said sterol borates into the free sterols to produce a third stream of free sterols.
摘要:
The disclosed invention refers to a process for obtaining fatty acid alkyl esters, rosin acids and sterols from crude tall oil (CTO), which is characterized by the following steps: (a) reacting the free fatty acids present in the CTO with lower alcohols; (b) esterifying the sterols in the CTO with boric acid or transesterifying the sterols with a catalyst; (c) separating the fatty acid lower alkyl esters and rosin acids from the remaining sterol borate esters or sterol esters of fatty acids to produce a stream of sterol esters; (d) separating the fatty acid alkyl esters from the rosin acids to produce a first stream of fatty acid alky esters and a second stream of rosin acids; and (e) converting the sterol esters into the free sterols to produce a third stream of free sterols.
摘要:
The disclosed invention refers to a process for obtaining fatty acid alkyl esters, rosin acids and sterols from crude tall oil (CTO), which is characterised by the following steps: (a) reacting the free fatty acids present in the CTO with lower alcohols; (b) esterifying the sterols in the CTO with boric acid or transesterifying the sterols with a catalyst; (c) separating the fatty acid lower alkyl esters and rosin acids from the remaining sterol borate esters or sterol esters of fatty acids to produce a stream of sterol esters; (d) separating the fatty acid alkyl esters from the rosin acids to produce a first stream of fatty acid alky esters and a second stream of rosin acids; and (e) converting the sterol esters into the free sterols to produce a third stream of free sterols.
摘要:
The invention discloses a method for encrypting and/authenticating, comprising the following steps: Sending a request for a first bit combination or character combination as a first sub key (102); storing said first bit combination or character combination in the memory (104); generating a second bit combination or character combination as a second sub key (106), wherein the second bit combination or character combination is a random or pseudo random pattern; and combining said first sub key and second sub key to a key (108); further comprising at least one of the following steps: encrypting the data with the key (110); using the key as an authentication password (112); and a method of decrypting and/or authenticating, comprising the following steps: sending a request for a first bit combination or character combination as a first sub key (202); storing said first bit combination or character combination in the memory (204); repeating the following steps until a key has been verified as valid: generating one by one a second bit combination or character combination as a second sub key (206), wherein the second bit combination or character combination is one by one taken from the set of all possible second sub keys (208); combining said first sub key and second sub key to a key (210); verifying, whether the key is valid (212); if said key has been verified as valid, decrypting the data with the key (214) and/or using the key an authentication password (216).
摘要:
A rolling-element bearing assembly includes an inner ring, an outer ring and a plurality of rolling elements disposed between the inner ring and the outer ring on a common pitch circle diameter. A retaining device is attached to one of the inner ring and the outer ring and holds the rolling-element bearing assembly together without falling apart. The rolling elements include balls and rollers disposed on the common pitch circle diameter in an alternating manner. Further, at least one of the inner ring and the outer ring includes a raceway groove that axially supports the roller bearing balls.
摘要:
A method and apparatus are disclosed for a multi-spool gas turbine engine with a variable area turbine nozzle and a motor/alternator device on the highest pressure turbo-compressor spool for starting the gas turbine and power extraction during engine operation. During power down of the engine, the variable area turbine nozzle may be used in conjunction with power extraction to maintain a near constant combustor outlet temperature while controlling turbine inlet temperatures on the turbines downstream of the highest pressure turbine and controlling spool speed on the highest pressure turbine.
摘要:
The air guiding device has one or more air guiding bodies. Each air guiding body has an elongate attachment that extends in the longitudinal direction of the vehicle that bulges in a convex manner, is composed of a flexible or soft-elastic material and is embodied in the form of a half shell having a lateral elongate opening and can be adjusted automatically in the driving condition from a rest position into an operative position, in which it can be lowered in the direction of the roadway. In the rest position, the air guiding body is arranged close to the undersurface and, in the operative position, the air guiding body is held in a lowered position relative to the undersurface.
摘要:
According to the invention, a process for the rectification of mixtures of high-boiling air- and/or temperature-sensitive substances which require a high separation efficiency is proposed, in particular a process for the working-up of a VE- or VEA-containing product stream. The process is characterized in particular in that, in a first purification stage, low-boiling products and unspecified isomers of the useful product are separated from the product stream virtually without loss of useful product and that, in a second purification stage, the useful product is removed in a stream having a purity of >97% by weight and a further stream having a purity of >92% by weight. A preferred embodiment of the process serves for working up VEA, in which the loss of useful product in the first purification stage is less than 5%, based on that amount of VEA in the feed which is added to the purification stage per unit time. Furthermore, the first purification stage may comprise a rectification column (1), from the top (1a) of which the low-boiling products and the unspecified isomers of VEA are taken off, a stream containing the useful product in purified form being taken off at the side (15) and/or at the bottom (1b) of the column (1).