摘要:
A process for preparing cyclopentene oligomer mixtures of the formula I comprises reacting in a homogeneously or heterogeneously catalyzed metathesis reaction a hydrocarbon mixture which contains cyclopentene and acyclic monoolefins and which originates from petroleum processing by cracking (C5 fraction); cyclopentene oligomers of the formula I obtainable by this process and their use are also described.
摘要:
A process for preparing tetrahydrofuran, which comprises reacting 1,4-butenediol diethers of the formulae I and/or II RO—CH2—CH═CH—CH2—OR I RO—CH2—CH2═CH—CH2—OR II, where the R radicals can be identical or different and are C1-C15-alkyl or cycloalkyl radicals, C6-C12-aryl radicals or C7-C15-aralkyl radicals, with water and hydrogen at from 20 to 300° C. under from 1 to 300 bar in the presence of catalysts or catalyst combinations which comprise components which are both capable of hydrogenation and have acidic or basic centers and a novel process for preparing 1,4-butanediol diethers of the formula I by metathesis are described.
摘要:
The preparation of amines of the formula (I): R1R2CH—N R3R4 (I) in which R1, R2, R3 and R4, independently of one another, are hydrogen, straight-chain or branched C1-C12-alkyl, C3-C12-cycloalkyl, C6-C10-aryl or C7-C11-aralkyl, takes place by catalytic, reductive amination of mixtures comprising carbonyl compounds of the formula (II) and/or alcohols of the formula (III) R1—C(═O)—R2 (II) R1—CH(OH)—R2 (III) which also comprise at least 50 ppm, based on the mixtures, of halogen, with nitrogen compounds of the formula (IV): H N R3 R4 (IV) with the abovementioned meanings for R1 to R4, in the presence of Co- and/or Ni-containing catalysts, which comprises carrying out the reductive amination additionally in the presence of solid acidic cocatalysts.
摘要:
Pyrroles of the formula (I) are prepared by dehydrogenating pyrrolidines of the formula (II) where R1 and R2, independently of one another, are hydrogen or an aliphatic radical of 1 to 6 carbon atoms, or pyridines of the formula (III) are prepared by dehydrogenating piperidines of the formula (IV) where R3, R4 and R5, independently of one another, are hydrogen or an aliphatic radical of 1 to 6 carbon atoms, in the presence of a supported noble metal catalyst, by a process in which the dehydrogenation is carried out in the presence of from 1 to 50% by weight, based on the pyrrolidine or piperidine and water, of water.
摘要:
The present invention relates to a packaging comprising a container surrounding a container interior, wherein at least the inner surface of the container in contact with the container interior is produced from a composition which comprises a thermoplastic polymer, and a plasticizer composition comprising—a polymeric plasticizer and a polyol ester, and wherein the container is at least partly filled with a lipophilic packed product.
摘要:
The invention relates to a process for oxidizing at least one organic substance with oxygen, which comprises the following steps: (a) adding the at least one organic substance as a liquid and an oxygenous gas stream to a first reaction stage to form a reaction mixture, at least some of the oxygen reacting with the organic compound to form a reaction product, (b) adding the reaction mixture from the first reaction stage to an adiabatically operated reaction stage in which the unconverted organic substance reacts further at least partly to give the product. The invention further relates to an apparatus for performing the process.
摘要:
The present invention relates to a packaging comprising a container surrounding a container interior, wherein at least the inner surface of the container in contact with the container interior is produced from a composition which comprises a thermoplastic polymer, and a plasticizer composition comprising a polymeric plasticizer and a polyol ester, and wherein the container is at least partly filled with a lipophilic packed product.
摘要:
The present invention relates to a process for the production of a packaging which is at least partly filled with a lipophilic packed product and comprises a container (1) and a closure (2) having a seal (3), comprising as process steps i) provision of a container which has an opening (4) and which is at least partly filled with a lipophilic packed product; ii) provision of a closure which is suitable for closing the container having the opening; iii) application of a composition to at least a part of the inner surfaces of the closure, wherein the composition is obtainable by mixing a particulate thermoplastic polymer with a plasticizer composition comprising a polymeric plasticizer and a polyol ester; iv) heating of the composition applied to at least a part of the inner surfaces of the closure to a temperature which is sufficient to gel the composition; v) cooling of the gelled composition; vi) closing of the container with the closure. The present invention also relates to a packaging which is obtainable by this process and is filled with a lipophilic packed product, and a packaging comprising a container and a closure, wherein the closure has a seal.
摘要:
A method of producing a turbine blade is provided, wherein the turbine blade is produced by an additive production method. Cavities and/or lattice structures can be produced in one and the same process. The additive production method also allows drainage slots, heating openings, and/or other holes or, as the case may be, recesses to be provided in the turbine blade while the turbine blade is being produced. Holes can furthermore be furnished completely or partially with a lattice structure.
摘要:
A method produces a marked object. To be able to create markings in a particularly flexible way, it is provided that the object is produced by an additive production process, at least one marking being formed in the object during the additive production process. The method makes many degrees of freedom possible in the design of the marking. For example, the method makes it possible in a very simple way for two- or three-dimensional structures to be concealed within the object during the additive production process. In addition or as an alternative, production parameters can be varied, whether stochastically or deterministically, to produce variations in density. For example, a porous microstructure may be produced as a marking. It is also possible for basic material in the object to be left untreated or to be differently treated, so that it forms the marking.