公开(公告)号：US08927745B2

公开(公告)日：2015-01-06

申请号：US13319803

申请日：2010-05-05

申请人： Philip Kampe ,  Peter Resch ,  Soo Yin Chin ,  Peter Bassler ,  Ulrich Mueller ,  Goetz-Peter Schindler ,  Hans-Georg Goebbel ,  Joaquim Henrique Teles ,  Kai Gumlich ,  Thomas Grassler ,  Christian Bartosch ,  Richard Jacubinas ,  Meinolf Weidenbach

发明人： Philip Kampe ,  Peter Resch ,  Soo Yin Chin ,  Peter Bassler ,  Ulrich Mueller ,  Goetz-Peter Schindler ,  Hans-Georg Goebbel ,  Joaquim Henrique Teles ,  Kai Gumlich ,  Thomas Grassler ,  Christian Bartosch ,  Richard Jacubinas ,  Meinolf Weidenbach

IPC分类号： C07D301/12

CPC分类号： C07D301/12 ,  Y02P20/52

摘要： A process for producing propylene oxide comprising reacting propene with hydrogen peroxide in the presence of a catalyst to give a mixture (G1) comprising propylene oxide, unreacted propene, and oxygen; separating propylene oxide from mixture (G1) to give a mixture (GII) comprising propene and oxygen; and adding hydrogen to mixture (GII) and reducing the oxygen comprised in mixture (GII) at least partially by reaction with hydrogen in the presence of a catalyst comprising copper in elemental and/or oxidic form on a support, wherein copper is present on the support in an amount of 30 to 80 wt.-% based on the whole catalyst and calculated as CuO.

摘要翻译： 一种生产环氧丙烷的方法，包括在催化剂存在下使丙烯与过氧化氢反应得到包含环氧丙烷，未反应的丙烯和氧的混合物（G1） 从混合物（G1）中分离环氧丙烷以得到包含丙烯和氧的混合物（GII）; 并且在载体上含有元素和/或氧化形式的铜的催化剂的存在下，至少部分地通过与氢反应，将氢混合物（GII）加入到混合物（GII）中并且还原含氧物质，其中铜存在于 以全部催化剂为基准，其用量为30-80重量％，以CuO计算。

公开(公告)号：US20120065413A1

公开(公告)日：2012-03-15

申请号：US13319803

申请日：2010-05-05

申请人： Philip Kampe ,  Peter Resch ,  Soo Yin Chin ,  Peter Bassler ,  Ulrich Mueller ,  Goetz-Peter Schindler ,  Hans-Georg Goebbel ,  Joaquim Henrique Teles ,  Kai Gumlich ,  Thomas Grassler ,  Christian Bartosch ,  Richard Jacubinas ,  Meinolf Weidenbach

发明人： Philip Kampe ,  Peter Resch ,  Soo Yin Chin ,  Peter Bassler ,  Ulrich Mueller ,  Goetz-Peter Schindler ,  Hans-Georg Goebbel ,  Joaquim Henrique Teles ,  Kai Gumlich ,  Thomas Grassler ,  Christian Bartosch ,  Richard Jacubinas ,  Meinolf Weidenbach

IPC分类号： C07D301/12

CPC分类号： C07D301/12 ,  Y02P20/52

摘要： A process for producing propylene oxide comprising reacting propene with hydrogen peroxide in the presence of a catalyst to give a mixture (G1) comprising propylene oxide, unreacted propene, and oxygen; separating propylene oxide from mixture (G1) to give a mixture (GII) comprising propene and oxygen; and adding hydrogen to mixture (GII) and reducing the oxygen comprised in mixture (GII) at least partially by reaction with hydrogen in the presence of a catalyst comprising copper in elemental and/or oxidic form on a support, wherein copper is present on the support in an amount of 30 to 80 wt.-% based on the whole catalyst and calculated as CuO.

摘要翻译： 一种生产环氧丙烷的方法，包括在催化剂存在下使丙烯与过氧化氢反应得到包含环氧丙烷，未反应的丙烯和氧的混合物（G1） 从混合物（G1）中分离环氧丙烷以得到包含丙烯和氧的混合物（GII）; 并且在载体上含有元素和/或氧化形式的铜的催化剂的存在下，至少部分地通过与氢反应，将氢混合物（GII）加入到混合物（GII）中并且还原含氧物质，其中铜存在于 以全部催化剂为基准，其用量为30-80重量％，以CuO计算。

公开(公告)号：US08785670B2

公开(公告)日：2014-07-22

申请号：US13312222

申请日：2011-12-06

申请人： Joaquim Henrique Teles ,  Kai Gumlich ,  Peter Bassler ,  Christian Bartosch ,  Philip Kampe ,  Hans-Georg Goebbel ,  Ulrich Mueller ,  Richard Jacubinas

发明人： Joaquim Henrique Teles ,  Kai Gumlich ,  Peter Bassler ,  Christian Bartosch ,  Philip Kampe ,  Hans-Georg Goebbel ,  Ulrich Mueller ,  Richard Jacubinas

IPC分类号： C07D301/12

CPC分类号： C07D301/12 ,  Y02P20/582

摘要： A continuous process for the production of propylene oxide comprising reacting propene with hydrogen peroxide in methanolic solution in the presence of a titanium silicalite-1 catalyst to obtain propylene oxide, wherein a reaction feed comprising propene, methanol and hydrogen peroxide is introduced into a reactor, said reaction feed containing potassium cations and phosphorus in the form of anions of at least one phosphorus oxyacid.

摘要翻译： 一种用于生产环氧丙烷的连续方法，其包括在钛硅沸石-1催化剂存在下，使丙烯与过氧化氢在甲醇溶液中反应以获得环氧丙烷，其中将包含丙烯，甲醇和过氧化氢的反应进料引入反应器中， 所述反应原料含有至少一种含磷酸的阴离子形式的钾阳离子和磷。

公开(公告)号：US20110065939A1

公开(公告)日：2011-03-17

申请号：US12837962

申请日：2010-07-16

申请人： Joaquim Henrique Teles ,  Hans-Georg Göbbel ,  Peter Baßler ,  Philip Kampe ,  Kai Gumlich ,  Christian Bartosch ,  Ulrich Müller ,  Richard Jacubinas ,  Natalia Trukhan ,  Meinolf Weidenbach ,  Martin Cogswell

发明人： Joaquim Henrique Teles ,  Hans-Georg Göbbel ,  Peter Baßler ,  Philip Kampe ,  Kai Gumlich ,  Christian Bartosch ,  Ulrich Müller ,  Richard Jacubinas ,  Natalia Trukhan ,  Meinolf Weidenbach ,  Martin Cogswell

IPC分类号： C07D301/12 ,  C07C255/03

CPC分类号： C07D301/12 ,  B01D17/0208 ,  B01D17/047 ,  Y02P20/582

摘要： A method for separating acetonitrile from water, comprising (i) providing a stream S1 containing at least 95 wt.-%, based on the total weight of S1, acetonitrile and water, wherein the weight ratio of acetonitrile:water is greater than 1; (ii) adding a stream P, comprising at least 95 wt.-% C3, based on the total weight of stream P, to S1 to obtain a mixed stream S2, C3 being propene optionally admixed with propane with a minimum weight ratio of propene:propane of 7:3; (iii) subjecting S2 to a temperature of 92° C. at most and a pressure of at least 10 bar, obtaining a first liquid phase L1 essentially consisting of C3, acetonitrile, and water, and a second liquid phase L2 essentially consisting of water and acetonitrile wherein the weight ratio of acetonitrile:water in L2 is less than 1; (iv) separating L1 from L2.

摘要翻译： 一种从水中分离乙腈的方法，包括（i）提供基于S1的总重量，乙腈和水的至少95重量％的流S1，其中乙腈：水的重量比大于1; （ii）将基于流P的总重量的至少95重量％C 3的流P加入到S1中，以获得混合物流S2，将任选地与丙烷混合的丙烯以最小重量比的丙烯 ：丙烷7：3; （iii）使S2达到最多92℃的温度和至少10巴的压力，得到基本上由C3，乙腈和水组成的第一液相L1和基本上由水组成的第二液相L2 乙腈，其中乙腈：水的重量比小于1; （iv）将L1与L2分离。

公开(公告)号：US08609879B2

公开(公告)日：2013-12-17

申请号：US12837962

申请日：2010-07-16

申请人： Joaquim Henrique Teles ,  Hans-Georg Göbbel ,  Peter Baβler ,  Philip Kampe ,  Kai Gumlich ,  Christian Bartosch ,  Ulrich Müller ,  Richard Jacubinas ,  Natalia Trukhan ,  Meinolf Weidenbach ,  Martin Cogswell

发明人： Joaquim Henrique Teles ,  Hans-Georg Göbbel ,  Peter Baβler ,  Philip Kampe ,  Kai Gumlich ,  Christian Bartosch ,  Ulrich Müller ,  Richard Jacubinas ,  Natalia Trukhan ,  Meinolf Weidenbach ,  Martin Cogswell

IPC分类号： C07C255/00

CPC分类号： C07D301/12 ,  B01D17/0208 ,  B01D17/047 ,  Y02P20/582

摘要： A method for separating acetonitrile from water, comprising (i) providing a stream S1 containing at least 95 wt.-%, based on the total weight of S1, acetonitrile and water, wherein the weight ratio of acetonitrile: water is greater than 1; (ii) adding a stream P, comprising at least 95 wt.-% C3, based on the total weight of stream P, to S1 to obtain a mixed stream S2, C3 being propene optionally admixed with propane with a minimum weight ratio of propene: propane of 7:3; (iii) subjecting S2 to a temperature of 92° C. at most and a pressure of at least 10 bar, obtaining a first liquid phase L1 essentially consisting of C3, acetonitrile, and water, and a second liquid phase L2 essentially consisting of water and acetonitrile wherein the weight ratio of acetonitrile: water in L2 is less than 1; (iv) separating L1 from L2.

摘要翻译： 一种从水中分离乙腈的方法，包括（i）提供基于S1的总重量，乙腈和水的至少95重量％的流S1，其中乙腈：水的重量比大于1; （ii）将基于流P的总重量的至少95重量％C 3的流P加入到S1中，以获得混合物流S2，将任选地与丙烷混合的丙烯以最小重量比的丙烯 ：丙烷7：3; （iii）使S2达到最多92℃的温度和至少10巴的压力，得到基本上由C3，乙腈和水组成的第一液相L1和基本上由水组成的第二液相L2 乙腈，其中乙腈：水的重量比小于1; （iv）将L1与L2分离。

公开(公告)号：US07786317B2

公开(公告)日：2010-08-31

申请号：US12159404

申请日：2006-12-18

申请人： Hans-Georg Goebbel ,  Peter Bassler ,  Joaquim Henrique Teles ,  Peter Rudolf ,  Ulrich Mueller ,  Anna Forlin ,  Malte Schulz ,  Meinolf Weidenbach

发明人： Hans-Georg Goebbel ,  Peter Bassler ,  Joaquim Henrique Teles ,  Peter Rudolf ,  Ulrich Mueller ,  Anna Forlin ,  Malte Schulz ,  Meinolf Weidenbach

IPC分类号： C07D301/12

CPC分类号： C07D301/12

摘要： The present invention provides a process for the epoxidation of propene which comprises reacting propene with hydrogen peroxide in the presence of methanol as solvent and a titanium zeolite catalyst, the process further comprising separating propylene oxide from the reaction mixture to obtain a mixture comprising methanol, water, at least one carboxylic acid and at least one carbonyl compound, wherein the at least one carboxylic acid is at least partially neutralized, said process optionally comprising a hydrogenation stage.

摘要翻译： 本发明提供丙烯环氧化方法，其包括在甲醇作为溶剂和钛沸石催化剂的存在下使丙烯与过氧化氢反应，该方法还包括从反应混合物中分离环氧丙烷以获得包含甲醇，水 ，至少一种羧酸和至少一种羰基化合物，其中所述至少一种羧酸被至少部分中和，所述方法任选地包含氢化阶段。

公开(公告)号：US20100305369A1

公开(公告)日：2010-12-02

申请号：US12599395

申请日：2008-04-24

申请人： Hans-Georg Goebbel ,  Peter Bassler ,  Joaquim Henrique Teles ,  Peter Rudolf ,  Ulrich Mueller ,  Anna Forlin ,  Malte Schulz ,  Meinolf Weidenbach

发明人： Hans-Georg Goebbel ,  Peter Bassler ,  Joaquim Henrique Teles ,  Peter Rudolf ,  Ulrich Mueller ,  Anna Forlin ,  Malte Schulz ,  Meinolf Weidenbach

IPC分类号： C07C27/10

CPC分类号： C07D301/12 ,  Y02P20/584

摘要： The present invention relates to a continuous process for the preparation of an olefin oxide wherein an olefin is reacted with a hydroperoxidein the presence of a catalyst, and wherein the reaction which is carried out in at least three reactors operated in parallel is controlled by specifically adjusting the catalyst loads in the reactors.

摘要翻译： 本发明涉及一种用于制备烯烃氧化物的连续方法，其中烯烃在催化剂存在下与氢过氧化物反应，并且其中在至少三个并联操作的反应器中进行的反应通过特别调节来控制 反应器中的催化剂负载。

公开(公告)号：US07973183B2

公开(公告)日：2011-07-05

申请号：US12599395

申请日：2008-04-24

申请人： Hans-Georg Goebbel ,  Peter Bassler ,  Joaquim Henrique Teles ,  Peter Rudolf ,  Ulrich Mueller ,  Anna Forlin ,  Malte Schulz ,  Meinolf Weidenbach

发明人： Hans-Georg Goebbel ,  Peter Bassler ,  Joaquim Henrique Teles ,  Peter Rudolf ,  Ulrich Mueller ,  Anna Forlin ,  Malte Schulz ,  Meinolf Weidenbach

IPC分类号： C07D301/12

CPC分类号： C07D301/12 ,  Y02P20/584

摘要： The present invention relates to a continuous process for the preparation of an olefin oxide wherein an olefin is reacted with a hydroperoxidein the presence of a catalyst, and wherein the reaction which is carried out in at least three reactors operated in parallel is controlled by specifically adjusting the catalyst loads in the reactors.

摘要翻译： 本发明涉及一种用于制备烯烃氧化物的连续方法，其中烯烃在催化剂存在下与氢过氧化物反应，并且其中在至少三个并联操作的反应器中进行的反应通过特别调节来控制 反应器中的催化剂负载。

公开(公告)号：US08211822B2

公开(公告)日：2012-07-03

申请号：US12556961

申请日：2009-09-10

申请人： Ulrich Mueller ,  Georg Krug ,  Peter Rudolf ,  Joaquim Henrique Teles ,  Hans-Georg Goebbel ,  Peter Bassler

发明人： Ulrich Mueller ,  Georg Krug ,  Peter Rudolf ,  Joaquim Henrique Teles ,  Hans-Georg Goebbel ,  Peter Bassler

IPC分类号： B01J21/06 ,  B01J21/08

CPC分类号： C07D301/12 ,  Y02P20/52

摘要： Process for preparing propylene oxide, which comprises at least the steps (i) and (ii): (i) providing a catalyst comprising at least one porous oxidic material; (ii) reacting propene with a hydroperoxide in at least one nitrile as solvent or in a solvent mixture comprising at least one nitrile in the presence of the catalyst of (i), wherein the at least one porous oxidic material is a zeolite which is assigned X-ray-crystallographically to the MWW type.

摘要翻译： 制备环氧丙烷的方法，其至少包括步骤（i）和（ii）：（i）提供包含至少一种多孔氧化物质的催化剂; （ii）使丙烯与至少一种腈作为溶剂中的氢过氧化物反应或在包含至少一种腈的溶剂混合物中，在（i）的催化剂存在下反应，其中所述至少一种多孔氧化物质是被分配的沸石 X射线晶体学到MWW型。

公开(公告)号：US08119550B2

公开(公告)日：2012-02-21

申请号：US10526939

申请日：2003-09-16

申请人： Ulrich Mueller ,  Georg Krug ,  Peter Bassler ,  Hans-Georg Goebbel ,  Peter Rudolf ,  Joaquim Henrique Teles

发明人： Ulrich Mueller ,  Georg Krug ,  Peter Bassler ,  Hans-Georg Goebbel ,  Peter Rudolf ,  Joaquim Henrique Teles

IPC分类号： B01J29/06 ,  C07D301/19

CPC分类号： C07D301/19 ,  B01J29/89 ,  B01J37/10 ,  B01J2229/36 ,  B01J2229/40 ,  C07D301/12 ,  Y02P20/125

摘要： The present invention relates to a process for treating a solid material containing at least one zeolite and being at least partly crystalline or treating a shaped body obtained from said solid material wherein said solid material or shaped body is brought in contact with a composition containing water after at least one of the following steps of an integrated process for producing a solid material or a shaped body containing at least one zeolite: (i) after step (II) of separating the at least partly crystalline solid material from its mother liquor or (ii) after step (S) of shaping said solid material into a shaped body or (iii) after a step (C) of calcining said solid material or said shaped body. The present invention furthermore relates to the solid material obtainable by the inventive process and the shaped body obtainable by the inventive process. The present invention also relates to the use of the solid material or the shaped body as mentioned above as a catalyst in chemical reactions, in particular in reactions of compounds containing at least one C-C double bond with at least one hydroperoxide.

摘要翻译： 本发明涉及一种用于处理含有至少一种沸石并且至少部分结晶的固体材料或处理由所述固体材料获得的成形体的方法，其中所述固体材料或成形体与含有水的组合物接触 用于生产固体材料或含有至少一种沸石的成形体的整合方法中的至少一个步骤：（i）在从母液中分离出至少部分结晶固体材料的步骤（II）之后，或（ii ）在将所述固体材料成形为成形体的步骤（S）之后或（iii）在煅烧所述固体材料或所述成形体的步骤（C）之后。 本发明还涉及可通过本发明方法获得的固体材料和通过本发明方法获得的成形体。 本发明还涉及如上所述的固体材料或成形体作为化学反应中的催化剂，特别是在含有至少一个C-C双键的化合物与至少一种氢过氧化物的反应中的用途。