Method for producing expandable granulates containing polylactic acid
    3.
    发明授权
    Method for producing expandable granulates containing polylactic acid 有权
    用于生产含有聚乳酸的可膨胀颗粒的方法

    公开(公告)号:US09212270B2

    公开(公告)日:2015-12-15

    申请号:US13522031

    申请日:2011-01-06

    摘要: The invention relates to a process for producing expandable pelletized material which comprises polylactic acid which comprises the following steps: a) melting and incorporation by mixing of the following components: i) from 50 to 99.9% by weight, based on the total weight of components i to iii), of polylactic acid, ii) from 0 to 49.9% by weight, based on the total weight of components i to iii), of one or more further polymers, iii) from 0.1 to 2% by weight, based on the total weight of components i to iii), of a diepoxide or polyepoxide, and iv) from 0 to 10% by weight of one or more additives, b) incorporation by mixing of v) from 3 to 7% by weight, based on the total weight of components i to iv), of an organic blowing agent into the polymer melt by means of a static or dynamic mixer at a temperature of at least 140° C., c) discharging through a die plate with holes, the diameter of which at the exit from the die is at most 1.5 mm, and d) pelletizing the melt comprising blowing agent directly downstream of the die plate, and under water, at a pressure in the range from 1 to 20 bar. The invention further relates to expandable pelletized material which comprises polylactic acid and which is obtainable by said process, and also to specific expandable pelletized material which comprises polylactic acid and which has a proportion of from 3 to 7% by weight of an organic blowing agent, preferably n-pentane and particularly preferably isopentane. The invention further relates to a preferred process for producing expandable pelletized material which comprises blowing agent and which comprises polylactic acid, and which has low bulk density.

    摘要翻译: 本发明涉及一种生产可膨胀颗粒材料的方法,其包括聚乳酸,其包括以下步骤:a)通过混合以下组分熔融和掺入:i)基于组分的总重量为50至99.9重量% ii)0至49.9重量%,基于组分i至iii的总重量),一种或多种其它聚合物,iii)基于以下物质的0.1至2重量%,基于 组分i至iii),二环氧化物或聚环氧化物的总重量,和iv)0至10重量%的一种或多种添加剂,b)通过混合v)3至7重量%,基于 通过静态或动态混合器在至少140℃的温度下将有机发泡剂的总成分重量分配到聚合物熔体中,c)通过具有孔的模板排出,直径 其中在模具的出口处至多为1.5mm,以及d)将熔体造粒, 直接在模板的下游,并在水下,在1至20巴的压力范围内。 本发明还涉及包含聚乳酸并且可通过所述方法获得的可膨胀颗粒材料,还涉及包含聚乳酸并且具有3-7重量%的有机发泡剂的比例的特定的可膨胀颗粒状材料, 优选正戊烷,特别优选异戊烷。 本发明还涉及一种用于生产可膨胀颗粒材料的优选方法,其包括发泡剂,其包含聚乳酸,并且其堆积密度低。

    METHOD FOR PRODUCING EXPANDABLE GRANULATES CONTAINING POLYLACTIC ACID
    4.
    发明申请
    METHOD FOR PRODUCING EXPANDABLE GRANULATES CONTAINING POLYLACTIC ACID 有权
    生产含有聚氨酯的可膨胀颗粒的方法

    公开(公告)号:US20130150468A1

    公开(公告)日:2013-06-13

    申请号:US13522031

    申请日:2011-01-06

    IPC分类号: C08J9/18

    摘要: The invention relates to a process for producing expandable pelletized material which comprises polylactic acid which comprises the following steps: a) melting and incorporation by mixing of the following components: i) from 50 to 99.9% by weight, based on the total weight of components i to iii), of polylactic acid, ii) from 0 to 49.9% by weight, based on the total weight of components i to iii), of one or more further polymers, iii) from 0.1 to 2% by weight, based on the total weight of components i to iii), of a diepoxide or polyepoxide, and iv) from 0 to 10% by weight of one or more additives, b) incorporation by mixing of v) from 3 to 7% by weight, based on the total weight of components i to iv), of an organic blowing agent into the polymer melt by means of a static or dynamic mixer at a temperature of at least 140° C., c) discharging through a die plate with holes, the diameter of which at the exit from the die is at most 1.5 mm, and d) pelletizing the melt comprising blowing agent directly downstream of the die plate, and under water, at a pressure in the range from 1 to 20 bar. The invention further relates to expandable pelletized material which comprises polylactic acid and which is obtainable by said process, and also to specific expandable pelletized material which comprises polylactic acid and which has a proportion of from 3 to 7% by weight of an organic blowing agent, preferably n-pentane and particularly preferably isopentane. The invention further relates to a preferred process for producing expandable pelletized material which comprises blowing agent and which comprises polylactic acid, and which has low bulk density.

    摘要翻译: 本发明涉及一种生产可膨胀颗粒材料的方法,其包括聚乳酸,其包括以下步骤:a)通过混合以下组分熔融和掺入:i)基于组分的总重量为50至99.9重量% ii)0至49.9重量%,基于组分i至iii的总重量),一种或多种其它聚合物,iii)基于以下物质的0.1至2重量%,基于 组分i至iii),二环氧化物或聚环氧化物的总重量,和iv)0至10重量%的一种或多种添加剂,b)通过混合v)3至7重量%,基于 通过静态或动态混合器在至少140℃的温度下将有机发泡剂的总成分重量分配到聚合物熔体中,c)通过具有孔的模板排出,直径 其中在模具的出口处至多为1.5mm,以及d)将熔体造粒, 直接在模板的下游,并在水下,在1至20巴的压力范围内。 本发明还涉及包含聚乳酸并且可通过所述方法获得的可膨胀颗粒材料,还涉及包含聚乳酸并且具有3-7重量%的有机发泡剂的比例的特定的可膨胀颗粒状材料, 优选正戊烷,特别优选异戊烷。 本发明还涉及一种用于生产可膨胀颗粒材料的优选方法,其包括发泡剂,其包含聚乳酸,并且其堆积密度低。

    Impact-modified thermoplastic molding compositions based on vinyl aromatic copolymers and polyamide
    5.
    发明授权
    Impact-modified thermoplastic molding compositions based on vinyl aromatic copolymers and polyamide 失效
    基于乙烯基芳族共聚物和聚酰胺的冲击改性热塑性模塑组合物

    公开(公告)号:US07671127B2

    公开(公告)日:2010-03-02

    申请号:US11721261

    申请日:2005-12-03

    IPC分类号: C08L51/04

    CPC分类号: C08L77/00 C08L33/00 C08L25/00

    摘要: The invention relates to thermoplastic molding compositions, comprising A) from 35 to 95% by weight of at least one graft copolymer A), which is obtainable via reaction of A1) from 5 to 95% by weight of a polymer A1), which is obtained from at least one dicarboxylic anhydride a11) and from at least one vinylaromatic comonomer a12), and A2) from 5 to 95% by weight of a polyamide A2), B) from 5 to 40% by weight of at least one ungrafted or grafted, non-particulate rubber without core-shell structure B), which has functional groups which can react with the end groups of component A), C) from 0 to 50% by weight of at least one particulate or fibrous filler or particulate or fibrous reinforcing material C), D) from 0 to 60% by weight of at least one copolymer D) composed of vinyl aromatic monomers d1) and of comonomers d2), and E) from 0 to 40% by weight of at least one other additive E), where the entirety of components A) to E) gives 100% by weight, and also to processes for preparation of the thermoplastic molding compositions, to the use of the thermoplastic molding compositions for production of moldings, of foils, of fibers, or of foams, and finally to the moldings, foils, fibers, and foams obtainable from the thermoplastic molding compositions.

    摘要翻译: 本发明涉及热塑性模塑组合物,其包含A)35至95重量%的至少一种接枝共聚物A),其可通过A1)5至95重量%的聚合物A1)的反应获得,其为 由至少一种二羧酸酐a11)和至少一种乙烯基芳族共聚单体a12)和A2)5至95重量%的聚酰胺A2),B)5至40重量%的至少一种未接枝或 接枝的,不含核 - 壳结构的非颗粒橡胶B),其具有可与组分A)的端基反应的官能团,C)0至50重量%的至少一种颗粒或纤维填料或颗粒或 纤维增强材料C),D)0至60重量%的由乙烯基芳族单体d1)和共聚单体d2)组成的至少一种共聚物D),和E)0至40重量%的至少一种其它 添加剂E),其中组分A)至E)的总量为100重量%,以及制备方法o 热塑性模塑组合物,热塑性模塑组合物用于生产模制品,箔,纤维或泡沫塑料的使用,最后是由热塑性模塑组合物获得的模制品,箔,纤维和泡沫。

    IMPACT-MODIFIED THERMOPLASTIC MOLDING COMPOSITIONS BASED ON VINYL AROMATIC COPOLYMERS AND POLYAMIDE
    6.
    发明申请
    IMPACT-MODIFIED THERMOPLASTIC MOLDING COMPOSITIONS BASED ON VINYL AROMATIC COPOLYMERS AND POLYAMIDE 失效
    基于乙烯芳族共聚物和聚酰胺的影响改性的热塑性成型组合物

    公开(公告)号:US20090239990A1

    公开(公告)日:2009-09-24

    申请号:US11721261

    申请日:2005-12-03

    IPC分类号: C08L51/04 C08L77/06

    CPC分类号: C08L77/00 C08L33/00 C08L25/00

    摘要: The invention relates to thermoplastic molding compositions, comprising A) from 35 to 95% by weight of at least one graft copolymer A), which is obtainable via reaction of A1) from 5 to 95% by weight of a polymer A1), which is obtained from at least one dicarboxylic anhydride a11) and from at least one vinylaromatic comonomer a12), and A2) from 5 to 95% by weight of a polyamide A2), B) from 5 to 40% by weight of at least one ungrafted or grafted, non-particulate rubber without core-shell structure B), which has functional groups which can react with the end groups of component A), C) from 0 to 50% by weight of at least one particulate or fibrous filler or particulate or fibrous reinforcing material C), D) from 0 to 60% by weight of at least one copolymer D) composed of vinyl aromatic monomers d1) and of comonomers d2), and E) from 0 to 40% by weight of at least one other additive E), where the entirety of components A) to E) gives 100% by weight, and also to processes for preparation of the thermoplastic molding compositions, to the use of the thermoplastic molding compositions for production of moldings, of foils, of fibers, or of foams, and finally to the moldings, foils, fibers, and foams obtainable from the thermoplastic molding compositions.

    摘要翻译: 本发明涉及热塑性模塑组合物,其包含A)35至95重量%的至少一种接枝共聚物A),其可通过A1)5至95重量%的聚合物A1)的反应获得,其为 由至少一种二羧酸酐a11)和至少一种乙烯基芳族共聚单体a12)和A2)5至95重量%的聚酰胺A2),B)5至40重量%的至少一种未接枝或 接枝的,不含核 - 壳结构的非颗粒橡胶B),其具有可与组分A)的端基反应的官能团,C)0至50重量%的至少一种颗粒或纤维填料或颗粒或 纤维增强材料C),D)0至60重量%的由乙烯基芳族单体d1)和共聚单体d2)组成的至少一种共聚物D),和E)0至40重量%的至少一种其它 添加剂E),其中组分A)至E)的总量为100重量%,以及制备方法o 热塑性模塑组合物,热塑性模塑组合物用于生产模制品,箔,纤维或泡沫塑料的使用,最后是由热塑性模塑组合物获得的模制品,箔,纤维和泡沫。