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公开(公告)号:US20200379347A1
公开(公告)日:2020-12-03
申请号:US16428864
申请日:2019-05-31
Applicant: Rohm and Haas Electronic Materials LLC
Inventor: Li Cui , Shintaro Yamada , Iou-Sheng Ke , Paul J. LaBeaume , Suzanne M. Coley , James F. Cameron , Keren Zhang , Joshua Kaitz
Abstract: A resist underlayer composition including a polymer having a polymer backbone and a substituted or unsubstituted fullerene group pendant to the polymer backbone, and a solvent in an amount of from 50 to 99.9 weight % based on the total resist underlayer composition.
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公开(公告)号:US20220197141A1
公开(公告)日:2022-06-23
申请号:US17124743
申请日:2020-12-17
Applicant: ROHM AND HAAS ELECTRONIC MATERIALS LLC
Inventor: Joshua Kaitz , Michael Finch , Paul J. LaBeaume , Shintaro Yamada , Suzanne M. Coley
IPC: G03F7/11 , C08F12/08 , C08F12/22 , C09D125/14 , C09D125/18 , C23C16/02 , C23C16/20 , C23C16/455 , G03F7/16 , H01L21/027
Abstract: A method of forming a pattern on a substrate, the method including: forming a photoresist underlayer over a surface of the substrate, the photoresist underlayer formed from a composition including a polymer having a glass transition temperature of less than 110° C. and a solvent; subjecting the photoresist underlayer to a metal precursor, where the metal precursor infiltrates a free volume of the photoresist underlayer; and exposing the metal precursor-treated photoresist underlayer to an oxidizing agent to provide a metallized photoresist underlayer.
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公开(公告)号:US20190204743A1
公开(公告)日:2019-07-04
申请号:US16236725
申请日:2018-12-31
Applicant: Rohm and Haas Electronic Materials LLC
Inventor: Joshua Kaitz , Tomas Marangoni , Emad Aqad , Amy M. Kwok , Mingqi Li , Thomas Cardolaccia , Choong-Bong Lee , Ke Yang , Cong Liu
IPC: G03F7/11 , G03F7/004 , G03F7/038 , G03F7/039 , C09D133/16 , G03F7/16 , G03F7/20 , G03F7/38 , G03F7/32 , C08F220/28 , C08F220/24
CPC classification number: G03F7/11 , C08F220/24 , C08F220/28 , C08F2220/283 , C09D133/16 , G03F7/0045 , G03F7/038 , G03F7/039 , G03F7/162 , G03F7/168 , G03F7/2006 , G03F7/322 , G03F7/38
Abstract: New photoresist and topcoat compositions are provided that are useful in a variety of applications. In one aspect, new photoresist compositions are provided that comprise: (a) a first matrix polymer; (b) one or more acid generators; and (c) one or more additive compounds of Formulae (I) and/or (II).
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公开(公告)号:US20240241441A1
公开(公告)日:2024-07-18
申请号:US18090638
申请日:2022-12-29
Applicant: ROHM AND HAAS ELECTRONIC MATERIALS LLC
Inventor: Tomas Marangoni , Huan He , Joshua Kaitz , Li Cui , Yinjie Cen , Emad Aqad , Mingqi Li
Abstract: A polymer including a first repeating unit comprising an acid labile group; an anionic endgroup selected from a carboxylate group or a sulfamate group; and an organic cation.
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公开(公告)号:US20220066321A1
公开(公告)日:2022-03-03
申请号:US17007903
申请日:2020-08-31
Applicant: ROHM AND HAAS ELECTRONIC MATERIALS LLC
Inventor: Joshua Kaitz , Sheng Liu , Li Cui , Shintaro Yamada , James F. Cameron , Emad Aqad , Iou-Sheng Ke , Suzanne M. Coley
IPC: G03F7/11 , C08G8/04 , C09D161/06
Abstract: An underlayer composition, comprising a polymer comprising a repeating unit of formula (1): wherein Ar is a monocyclic or polycyclic C5-60 aromatic group, wherein the aromatic group comprises one or more aromatic ring heteroatoms, a substituent group comprising a heteroatom, or a combination thereof; X is C or O; R1, R2; Ra and Rb are as provided herein; optionally, R1 and R2 can be taken together form a 5- to 7-membered ring; optionally, one of R11 to R13 can be taken together with R1 to form a 5- to 7-membered ring; wherein Ra and Rb optionally may be taken together to form a 5- to 7-membered ring; wherein one of Ra or Rb optionally may be taken together with R2 to form a 5- to 7-membered ring; and when X is O, Ra and Rb are absent.
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公开(公告)号:US11762294B2
公开(公告)日:2023-09-19
申请号:US17007877
申请日:2020-08-31
Applicant: ROHM AND HAAS ELECTRONIC MATERIALS LLC
Inventor: Joshua Kaitz , Sheng Liu , Li Cui , Shintaro Yamada , Suzanne M. Coley , Iou-Sheng Ke
Abstract: A photoresist underlayer composition, comprising a polymer comprising a repeating unit of formula (1):
wherein Ar is a monocyclic or polycyclic C5-60 aromatic group, wherein the aromatic group comprises one or more aromatic ring heteroatoms, a substituent group comprising a heteroatom, or a combination thereof; R1 is hydrogen, substituted or unsubstituted C1-30 alkyl, substituted or unsubstituted C1-30 heteroalkyl, substituted or unsubstituted C3-30 cycloalkyl, substituted or unsubstituted C2-30 heterocycloalkyl, substituted or unsubstituted C2-30 alkenyl, substituted or unsubstituted C2-30 alkynyl, substituted or unsubstituted C6-30 aryl, substituted or unsubstituted C7-30 arylalkyl, substituted or unsubstituted C7-30 alkylaryl, substituted or unsubstituted C3-30 heteroaryl, or substituted or unsubstituted C4-30 heteroarylalkyl; and R2 is substituted or unsubstituted C1-30 alkyl, substituted or unsubstituted C1-30 heteroalkyl, substituted or unsubstituted C3-30 cycloalkyl, substituted or unsubstituted C2-30 heterocycloalkyl, substituted or unsubstituted C2-30 alkenyl, substituted or unsubstituted C2-30 alkynyl, substituted or unsubstituted C6-30 aryl, substituted or unsubstituted C7-30 arylalkyl, substituted or unsubstituted C7-30 alkylaryl, substituted or unsubstituted C3-30 heteroaryl, or substituted or unsubstituted C4-30 heteroarylalkyl, wherein R1 and R2 can be optionally taken together to form a ring.
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公开(公告)号:US20220214616A1
公开(公告)日:2022-07-07
申请号:US17564476
申请日:2021-12-29
Inventor: Joshua Kaitz , Brian Malbrecht , Deyan Wang , Michael Henry Howard, JR.
Abstract: A photoresist composition, comprising a first polymer comprising a first repeating unit comprising an acid-labile group, and a second polymer comprising a repeating unit derived from one or more monomers of formula (4); a photoacid generator; and a solvent, wherein Z1, Z2, R1, R2, and L are as described herein, and P is a polymerizable group.
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公开(公告)号:US20220066320A1
公开(公告)日:2022-03-03
申请号:US17007877
申请日:2020-08-31
Applicant: ROHM AND HAAS ELECTRONIC MATERIALS LLC
Inventor: Joshua Kaitz , Sheng Liu , Li Cui , Shintaro Yamada , Suzanne M. Coley , Iou-Sheng Ke
Abstract: A photoresist underlayer composition, comprising a polymer comprising a repeating unit of formula (1): wherein Ar is a monocyclic or polycyclic C5-60 aromatic group, wherein the aromatic group comprises one or more aromatic ring heteroatoms, a substituent group comprising a heteroatom, or a combination thereof; R1 is hydrogen, substituted or unsubstituted C1-30 alkyl, substituted or unsubstituted C1-30 heteroalkyl, substituted or unsubstituted C3-30 cycloalkyl, substituted or unsubstituted C2-30 heterocycloalkyl, substituted or unsubstituted C2-30 alkenyl, substituted or unsubstituted C2-30 alkynyl, substituted or unsubstituted C6-30 aryl, substituted or unsubstituted C7-30 arylalkyl, substituted or unsubstituted C7-30 alkylaryl, substituted or unsubstituted C3-30 heteroaryl, or substituted or unsubstituted C1-30 heteroarylalkyl; and R2 is substituted or unsubstituted C1-30 alkyl, substituted or unsubstituted C1-30 heteroalkyl, substituted or unsubstituted C3-30 cycloalkyl, substituted or unsubstituted C2-30 heterocycloalkyl, substituted or unsubstituted C2-30 alkenyl, substituted or unsubstituted C2-30 alkynyl, substituted or unsubstituted C6-30 aryl, substituted or unsubstituted C7-30 arylalkyl, substituted or unsubstituted C7-30 alkylaryl, substituted or unsubstituted C3-30 heteroaryl, or substituted or unsubstituted C4-30 heteroarylalkyl, wherein R1 and R2 can be optionally taken together to form a ring.
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公开(公告)号:US20200377713A1
公开(公告)日:2020-12-03
申请号:US16885628
申请日:2020-05-28
Applicant: ROHM AND HAAS ELECTRONIC MATERIALS LLC
Inventor: Joshua Kaitz , Xisen Hou , Mingqi Li , Tomas Marangoni , Emad Aqad , Yang Song
Abstract: Disclosed herein is a polymer comprising a first repeat unit and a second repeat unit, where the first repeat unit contains an acid labile group and where the second repeat unit has the structure of formula (1): wherein R1, R2 and R3 are each independently hydrogen, a halogen, a substituted or unsubstituted C1 to C12 alkyl group or C3 to C12 cycloalkyl group optionally containing an ether group, a carbonyl group, an ester group, a carbonate group, an amine group, an amide group, a urea group, a sulfate group, a sulfone group, a sulfoxide group, an N-oxide group, a sulfonate group, a sulfonamide group, or a combination thereof, a substituted or unsubstituted C6 to C14 aryl group, or C3 to C12 heteroaryl group, wherein the substitution is halogen, hydroxyl, cyano, nitro, C1 to C12 alkyl group, C1 to C12 haloalkyl group, C1 to C12 alkoxy group, C3 to C12 cycloalkyl group, amino, C2-C6 alkanoyl, carboxamido, a substituted or unsubstituted C6 to C14 aryl group, or C3 to C12 heteroaryl group; wherein R1 and R2 together optionally form a ring; and wherein n=1-3.
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公开(公告)号:US11829069B2
公开(公告)日:2023-11-28
申请号:US16236725
申请日:2018-12-31
Applicant: Rohm and Haas Electronic Materials LLC
Inventor: Joshua Kaitz , Tomas Marangoni , Emad Aqad , Amy M. Kwok , Mingqi Li , Thomas Cardolaccia , Choong-Bong Lee , Ke Yang , Cong Liu
IPC: G03F7/11 , G03F7/004 , G03F7/038 , G03F7/039 , G03F7/20 , G03F7/16 , G03F7/32 , G03F7/38 , C09D133/16 , C08F220/24 , C08F220/28 , C08F220/18
CPC classification number: G03F7/11 , C08F220/24 , C08F220/283 , C09D133/16 , G03F7/0045 , G03F7/0046 , G03F7/038 , G03F7/039 , G03F7/0397 , G03F7/162 , G03F7/168 , G03F7/2006 , G03F7/2041 , G03F7/322 , G03F7/38 , C08F220/1808
Abstract: New photoresist and topcoat compositions are provided that are useful in a variety of applications. In one aspect, new photoresist compositions are provided that comprise: (a) a first matrix polymer; (b) one or more acid generators; and (c) one or more additive compounds of Formulae (I) and/or (II).