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    Elastomeric polymer blends and processes for their production
    1.
    发明授权
    Elastomeric polymer blends and processes for their production 有权
    弹性聚合物共混物及其生产方法

    公开(公告)号：US08247495B2

    公开(公告)日：2012-08-21

    申请号：US13015364

    申请日：2011-01-27

    申请人： Rainer Kolb ,  John W. Chu ,  Gabor Kiss ,  Robert P. Reynolds, Jr. ,  Jean-Roch Schauder ,  Thomas T. Sun

    发明人： Rainer Kolb ,  John W. Chu ,  Gabor Kiss ,  Robert P. Reynolds, Jr. ,  Jean-Roch Schauder ,  Thomas T. Sun

    IPC分类号： C08F8/00 ,  C08L23/04 ,  C08L23/10

    CPC分类号： C08L23/142 ,  C08L2205/02 ,  C08L2314/06 ,  C08L2666/06

    摘要： Elastomeric polymer blends and processes for their production are described. Specifically, the polymer blends comprise a first polymer and a second polymer, where the first polymer comprises from about 70 wt % to about 90 wt % units derived from propylene and from about 10 wt % to about 30 wt % units derived from ethylene and/or a C4-C10 alpha-olefin, and the second polymer comprises from about 88 wt % to about 98 wt % units derived from propylene and from about 2 wt % to about 12 wt % units derived from ethylene and/or a C4-C10 alpha-olefin. The elastomeric polymer blends are further characterized by having two or more of the following properties: an overall propylene content of between about 75 wt % and about 90 wt %, a melting point between about 110° C. and about 145° C., a Vicat softening point greater than about 45° C., a tensile stress at 300% strain of less than about 500 psi (3447 kPa), as determined by a stress strain test according to ASTM D412, or an average maximum force for pellet separation of less than about 10 N in an accelerated storage stability test. The polymer blends are produced in a dual reactor process, in which the first polymer and the second polymer are prepared using differing catalyst systems.

    摘要翻译： 描述了弹性聚合物共混物及其生产方法。 具体地，聚合物共混物包含第一聚合物和第二聚合物，其中第一聚合物包含约70重量％至约90重量％的衍生自丙烯的单元和约10重量％至约30重量％的衍生自乙烯和/ 或C 4 -C 10α-烯烃，并且第二聚合物包含衍生自丙烯的约88重量％至约98重量％的单元和衍生自乙烯和/或C 4 -C 10的约2重量％至约12重量％的单元 α-烯烃。 弹性体聚合物共混物的进一步特征在于具有两种或更多种以下性能：总丙烯含量为约75重量％至约90重量％，熔点为约110℃至约145℃， 维卡软化点大于约45℃，通过根据ASTM D412的应力应变测试确定的小于约500psi（3447kPa）的300％应变下的拉伸应力或丸粒分离的平均最大力 在加速储存稳定性试验中小于约10N。 聚合物共混物在双重反应器方法中制备，其中使用不同的催化剂体系制备第一聚合物和第二聚合物。

    Elastomeric Polymer Blends and Processes for Their Production
    2.
    发明申请
    Elastomeric Polymer Blends and Processes for Their Production 有权
    弹性体聚合物共混物及其制备方法

    公开(公告)号：US20110207888A1

    公开(公告)日：2011-08-25

    申请号：US13015364

    申请日：2011-01-27

    申请人： Rainer Kolb ,  John W. Chu ,  Gabor Kiss ,  Robert P. Reynolds, JR. ,  Jean-Roch Schauder ,  Thomas T. Sun

    发明人： Rainer Kolb ,  John W. Chu ,  Gabor Kiss ,  Robert P. Reynolds, JR. ,  Jean-Roch Schauder ,  Thomas T. Sun

    IPC分类号： C08L23/14 ,  C08J5/00

    CPC分类号： C08L23/142 ,  C08L2205/02 ,  C08L2314/06 ,  C08L2666/06

    摘要： Elastomeric polymer blends and processes for their production are described. Specifically, the polymer blends comprise a first polymer and a second polymer, where the first polymer comprises from about 70 wt % to about 90 wt % units derived from propylene and from about 10 wt % to about 30 wt % units derived from ethylene and/or a C4-C10 alpha-olefin, and the second polymer comprises from about 88 wt % to about 98 wt % units derived from propylene and from about 2 wt % to about 12 wt % units derived from ethylene and/or a C4-C10 alpha-olefin. The elastomeric polymer blends are further characterized by having two or more of the following properties: an overall propylene content of between about 75 wt % and about 90 wt %, a melting point between about 110° C. and about 145° C., a Vicat softening point greater than about 45° C., a tensile stress at 300% strain of less than about 500 psi (3447 kPa), as determined by a stress strain test according to ASTM D412, or an average maximum force for pellet separation of less than about 10 N in an accelerated storage stability test. The polymer blends are produced in a dual reactor process, in which the first polymer and the second polymer are prepared using differing catalyst systems.

    摘要翻译： 描述了弹性聚合物共混物及其生产方法。 具体地，聚合物共混物包含第一聚合物和第二聚合物，其中第一聚合物包含约70重量％至约90重量％的衍生自丙烯的单元和约10重量％至约30重量％的衍生自乙烯和/ 或C 4 -C 10α-烯烃，并且第二聚合物包含衍生自丙烯的约88重量％至约98重量％的单元和衍生自乙烯和/或C 4 -C 10的约2重量％至约12重量％的单元 α-烯烃。 弹性体聚合物共混物的进一步特征在于具有两种或更多种以下性能：总丙烯含量为约75重量％至约90重量％，熔点为约110℃至约145℃， 维卡软化点大于约45℃，通过根据ASTM D412的应力应变测试确定的小于约500psi（3447kPa）的300％应变下的拉伸应力或丸粒分离的平均最大力 在加速储存稳定性试验中小于约10N。 聚合物共混物在双重反应器方法中制备，其中使用不同的催化剂体系制备第一聚合物和第二聚合物。

    Fouling prevention in polymerization reactors
    3.
    发明授权
    Fouling prevention in polymerization reactors 有权
    聚合反应堆防污

    公开(公告)号：US07745552B2

    公开(公告)日：2010-06-29

    申请号：US12157972

    申请日：2008-06-13

    申请人： Gabor Kiss ,  Robert P. Reynolds, Jr. ,  Charles K. Morgan ,  John W. Chu ,  Megan Meier

    发明人： Gabor Kiss ,  Robert P. Reynolds, Jr. ,  Charles K. Morgan ,  John W. Chu ,  Megan Meier

    IPC分类号： C08F2/00 ,  B01J19/18

    CPC分类号： B01J4/002 ,  B01J4/001 ,  B01J19/18 ,  B01J19/26 ,  B01J2219/00094 ,  B01J2219/00247 ,  B01J2219/00254 ,  B01J2219/1923 ,  C08F10/00 ,  C08F110/06 ,  C08F210/06 ,  Y02P20/544 ,  Y10S526/918 ,  C08F2/002 ,  C08F2/06

    摘要： Reactor designs and processes for operating such reactor designs to minimize or eliminate fouling in homogeneous polymerization processes (solution and supercritical). The process includes providing a reactor with one or more feed entry ports, wherein the reactor feed components are fed through each of the one or more feed entry ports at a linear velocity of greater than or equal to 0.3 m/min. The one or more feed entry ports may also be optionally extended beyond the interior reactor wall by greater than or equal to 2% of the internal radius of the reactor to further decrease the propensity for fouling. A stirred reactor may also include a stirrer feed port for purging the stirrer with a stirrer purge stream at a linear velocity of greater than or equal to 0.3 m/min to decrease stirrer fouling.

    摘要翻译： 用于操作这种反应器设计的反应器设计和方法以在均匀聚合过程（溶液和超临界）中最小化或消除结垢。 该方法包括向反应器提供一个或多个进料口，其中反应器进料组分以大于或等于0.3m / min的线速度通过一个或多个进料口中的每一个进料。 一个或多个进料口也可以任选地延伸超过内部反应器壁大于或等于反应器内半径的2％，以进一步降低结垢倾向。 搅拌反应器还可以包括用于以大于或等于0.3m / min的线速度用搅拌器吹扫流吹扫搅拌器的搅拌器进料口，以减少搅拌器结垢。

    Fouling prevention in polymerization reactors
    4.
    发明申请
    Fouling prevention in polymerization reactors 有权
    聚合反应堆防污

    公开(公告)号：US20090005520A1

    公开(公告)日：2009-01-01

    申请号：US12157972

    申请日：2008-06-13

    申请人： Gabor Kiss ,  Robert P. Reynolds, JR. ,  Charles K. Morgan ,  John W. Chu ,  Megan Meier

    发明人： Gabor Kiss ,  Robert P. Reynolds, JR. ,  Charles K. Morgan ,  John W. Chu ,  Megan Meier

    IPC分类号： C08F2/01 ,  C08F2/00 ,  B01J19/18 ,  B01J19/24

    CPC分类号： B01J4/002 ,  B01J4/001 ,  B01J19/18 ,  B01J19/26 ,  B01J2219/00094 ,  B01J2219/00247 ,  B01J2219/00254 ,  B01J2219/1923 ,  C08F10/00 ,  C08F110/06 ,  C08F210/06 ,  Y02P20/544 ,  Y10S526/918 ,  C08F2/002 ,  C08F2/06

    摘要： Reactor designs and processes for operating such reactor designs to minimize or eliminate fouling in homogeneous polymerization processes (solution and supercritical). The process includes providing a reactor with one or more feed entry ports, wherein the reactor feed components are fed through each of the one or more feed entry ports at a linear velocity of greater than or equal to 0.3 m/min. The one or more feed entry ports may also be optionally extended beyond the interior reactor wall by greater than or equal to 2% of the internal radius of the reactor to further decrease the propensity for fouling. A stirred reactor may also include a stirrer feed port for purging the stirrer with a stirrer purge stream at a linear velocity of greater than or equal to 0.3 m/min to decrease stirrer fouling.

    摘要翻译： 用于操作这种反应器设计的反应器设计和方法以在均匀聚合过程（溶液和超临界）中最小化或消除结垢。 该方法包括向反应器提供一个或多个进料口，其中反应器进料组分以大于或等于0.3m / min的线速度通过一个或多个进料口中的每一个进料。 一个或多个进料口也可以任选地延伸超过内部反应器壁大于或等于反应器内半径的2％，以进一步降低结垢倾向。 搅拌反应器还可以包括用于以大于或等于0.3m / min的线速度用搅拌器吹扫流吹扫搅拌器的搅拌器进料口，以减少搅拌器结垢。

    Heat-seal resin and package formed therefrom
    7.
    发明授权
    Heat-seal resin and package formed therefrom 有权
    热封树脂和由此形成的包装

    公开(公告)号：US08173748B1

    公开(公告)日：2012-05-08

    申请号：US12972035

    申请日：2010-12-17

    申请人： David John Lohse ,  Thomas Tungshi Sun ,  Aspy K. Mehta ,  Gabor Kiss ,  Robert Patrick Reynolds, Jr. ,  John W. Chu ,  Manika Varma-Nair

    发明人： David John Lohse ,  Thomas Tungshi Sun ,  Aspy K. Mehta ,  Gabor Kiss ,  Robert Patrick Reynolds, Jr. ,  John W. Chu ,  Manika Varma-Nair

    IPC分类号： C08F8/00 ,  C08L23/00 ,  C08L23/04 ,  C08L23/10

    CPC分类号： C08L23/142 ,  C08L2205/025

    摘要： Provided is a heat-seal resin. The resin includes 5 wt % to 95 wt % of a first copolymer and 95 wt % to 5 wt % of a second copolymer based on the total weight of the resin. The first copolymer and the second copolymer together are 90 wt % or more of the total weight of the resin. The first copolymer includes a first monomer of an alphaolefin of 2 to 4 carbon atoms and a second monomer selected from a second monomer of an alphaolefin of 2 to 8 carbon atoms. The first monomer and the second monomer of the first copolymer are different. The first copolymer has an MFR of from 5 to 1000 g/10 minutes and a Tfm of 66° C. to 80° C. The second copolymer includes a first monomer of an alphaolefin of 2 to 4 carbon atoms and a second monomer selected from a second monomer of an alphaolefin of 2 to 8 carbon atoms. The first monomer and the second monomer of the second copolymer are different. The second copolymer has an MFR of from 0.5 to 5 g/10 minutes and a Tfm of 45° C. to 66° C., wherein the first copolymer has an MFR of at least 2 g/10 minutes greater and a Tfm of at least 10° C. greater than the second copolymer. There is also a package formed partly or entirely of the resin.

    摘要翻译： 提供一种热封树脂。 基于树脂的总重量，树脂包含5重量％至95重量％的第一共聚物和95重量％至5重量％的第二共聚物。 第一共聚物和第二共聚物一起是树脂总重量的90重量％以上。 第一共聚物包括2至4个碳原子的α-烯烃的第一单体和选自2至8个碳原子的α-烯烃的第二单体的第二单体。 第一共聚物的第一单体和第二单体是不同的。 第一共聚物的MFR为5至1000g / 10分钟，Tfm为66℃至80℃。第二共聚物包括第一单体，其具有2至4个碳原子的α-烯烃，第二单体选自 2至8个碳原子的α-烯烃的第二单体。 第二共聚物的第一单体和第二单体是不同的。 第二共聚物的MFR为0.5〜5g / 10分钟，Tfm为45〜66℃，其中第一共聚物的MFR为2g / 10分钟以上， 比第二共聚物大至少10℃。 还有一部分或全部由树脂形成的包装。

    IN-LINE PROCESS FOR PRODUCING PLASTICIZED POLYMERS AND PLASTICIZED POLYMER BLENDS
    8.
    发明申请
    IN-LINE PROCESS FOR PRODUCING PLASTICIZED POLYMERS AND PLASTICIZED POLYMER BLENDS 有权
    生产聚合物和聚合物增稠剂的在线工艺

    公开(公告)号：US20090076216A1

    公开(公告)日：2009-03-19

    申请号：US12283045

    申请日：2008-09-09

    申请人： Gabor Kiss ,  Alan Anthony Galuska ,  Robert Patrick Reynolds, JR. ,  John W. Chu ,  Bryan R. Chapman ,  Patrick Brant ,  Sudhin Datta

    发明人： Gabor Kiss ,  Alan Anthony Galuska ,  Robert Patrick Reynolds, JR. ,  John W. Chu ,  Bryan R. Chapman ,  Patrick Brant ,  Sudhin Datta

    IPC分类号： C08L23/18 ,  C08L23/12 ,  C08L23/06

    CPC分类号： C08F10/00 ,  B01J2219/00038 ,  B01J2219/0004 ,  C08F210/16 ,  C08J3/18 ,  C08F2/01 ,  C08F2/001 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/08 ,  C08F2500/20

    摘要： A process for fluid phase in-line blending of plasticized polymers is provided. The process includes providing two or more reactor trains configured in parallel and a separator for product blending and product-feed separation, wherein one or more of the reactor trains produces one or more polymers and one or more of the reactor trains produces one or more plasticizers; contacting in at least one of the parallel reactor trains olefin monomers, catalyst systems, optional comonomers, optional scavengers, and optional diluents or solvents, at a temperature above the solid-fluid phase transition temperature of the polymerization system and a pressure no lower than 10 MPa below the cloud point pressure of the polymerization system and less than 1500 MPa; forming a reactor effluent including a homogeneous fluid phase polymer-monomer mixture and plasticizer-monomer mixture in each parallel reactor train; passing the reactor effluents through the separator; maintaining the temperature and pressure within the separator above the solid-fluid phase transition point but below the cloud point pressure and temperature to form a fluid-fluid two-phase system including a plasticized polymer-rich blend phase and a monomer-rich phase; and separating the monomer-rich phase from the plasticized polymer-rich blend phase. The polymer-rich blend phase is conveyed to a downstream finishing stage for further monomer stripping, drying and/or pelletizing to form a plasticized polymer product blend. Suitable plasticizers for in-line production and blending include polyalphaolefin oligomers, polybutenes, low glass transition temperature polymers and combinations thereof.

    摘要翻译： 提供了一种用于增塑聚合物的流体相在线共混的方法。 该方法包括提供并联配置的两个或多个反应器列和用于产物共混和产物 - 进料分离的分离器，其中一个或多个反应器列产生一种或多种聚合物，并且一个或多个反应器列产生一种或多种增塑剂 ; 在高于聚合体系的固体 - 流体相转变温度的温度下，在至少一个平行反应器系列烯烃单体，催化剂体系，任选的共聚单体，任选的清除剂和任选的稀释剂或溶剂中接触，并且压力不低于10 MPa低于聚合体系的浊点压力，小于1500MPa; 在每个平行的反应器列中形成包含均相流体相聚合物 - 单体混合物和增塑剂 - 单体混合物的反应器流出物; 使反应器流出物通过分离器; 将分离器内的温度和压力保持在固体 - 流体相转变点之上但低于浊点压力和温度，以形成包括增塑的富含聚合物的共混相和富单体相的流体 - 流体两相系统; 并将富单体相与增塑的富聚合物相分离。 富含聚合物的共混相被输送到下游整理阶段以用于进一步的单体汽提，干燥和/或造粒以形成增塑的聚合物产物混合物。 用于在线生产和共混的合适的增塑剂包括聚α-烯烃低聚物，聚丁烯，低玻璃化转变温度聚合物及其组合。