Polyolefin elastomer blends exhibiting improved properties
    5.
    发明授权
    Polyolefin elastomer blends exhibiting improved properties 失效
    表现出改进性能的聚烯烃弹性体共混物

    公开(公告)号:US6005053A

    公开(公告)日:1999-12-21

    申请号:US784681

    申请日:1997-01-22

    摘要: Polymer mixtures are disclosed which comprise at least one homogeneously branched ethylene polymer (A) and at least one ethylene polymer (B) having a crystallinity which is at least 7% greater than the crystallinity of polymer (A) with certain provisos. A process for making a molded article using the disclosed polymer mixtures is disclosed as well as films, film layers, coatings and molded articles formed from those mixtures. These mixtures have several advantages over polymer compositions of the prior art, including improved properties at elevated temperatures such as improved softening point under load, improved hardness, improved toughness, improved 100% modulus of elasticity, improved compression set, improved ability to prevent oil bleed out at lower temperatures when the mixture contains oil and reduced injection molding cycle time. The mixtures retain their performance advantages even when substantial amounts of additives such as oil and filler are incorporated into the mixture. The mixtures may also be crosslinked after they are formed into the shape of an article to form vulcanized elastomeric products. The polymer mixtures have utility in a variety of applications.

    摘要翻译: 公开了包含至少一种均匀支化的乙烯聚合物(A)和至少一种乙烯聚合物(B)的聚合物混合物,其结晶度比聚合物(A)的结晶度大至少7%,具有某些条件。 公开了使用所公开的聚合物混合物制备模塑制品的方法以及由这些混合物形成的薄膜,薄膜层,涂层和模塑制品。 这些混合物具有优于现有技术的聚合物组合物的几个优点,包括在升高的温度下改进的性能,例如负载下改进的软化点,改进的硬度,改进的韧性,改进的100%弹性模量,改进的压缩永久变形,改进的防止油渗出的能力 当混合物含有油和降低注塑周期时,在较低的温度下出来。 即使将大量的添加剂如油和填料加入到混合物中,混合物也保持其性能优势。 在混合物形成制品的形状以形成硫化的弹性体产品之后,它们也可以交联。 聚合物混合物可用于各种应用。

    Method of making elastic articles having improved heat-resistance
    6.
    发明授权
    Method of making elastic articles having improved heat-resistance 有权
    制造具有改善的耐热性的弹性制品的方法

    公开(公告)号:US06803014B2

    公开(公告)日:2004-10-12

    申请号:US10192223

    申请日:2002-07-10

    IPC分类号: B29C3508

    摘要: The present invention relates to a method for making a heat-resistant elastic article and a heat-resistant elastic article. The invention especially relates to a method of making elastic fibers and polymeric elastic fibers wherein the elastic fibers are capable of withstanding dyeing and heat-setting processes that typically are conducted at elevated temperatures (such as 110-230° C. and especially at greater than or equal to 130° C. for minutes). The inventive method comprises radiation crosslinking an article (or plurality of articles) under an inert or oxygen limited atmosphere (for example, in N2, argon, helium, carbon dioxide, xenon and/or a vacuum) wherein the article (or articles) comprises at least one amine stabilizer and preferably another optional stabilizer additive. More preferably, the radiation crosslinking is performed at a low temperature (−50 to 40° C.). The elastic article (or articles) comprises a homogeneously branched ethylene interpolymer (preferably a substantially linear ethylene interpolymer), a substantially hydrogenated block polymer, or a combination of the two. The heat-resistant elastic articles (especially fibers) are useful in various durable or repeated-use fabric applications such as, but not limited to, clothing, under-garments, and sports apparel. The heat-resistant elastic fibers can be conveniently formed into fabrics using well-known techniques such as, for example, by using co-knitting techniques with cotton, nylon, and/or polyester fibers.

    摘要翻译: 本发明涉及一种制造耐热弹性制品和耐热弹性制品的方法。 本发明特别涉及一种制造弹性纤维和聚合物弹性纤维的方法,其中弹性纤维能够耐受染色和热定型过程,其通常在升高的温度(例如110-230℃,特别是大于 或等于130℃,分钟)。 本发明的方法包括在惰性或氧气限制的气氛(例如,在N 2,氩气,氦气,二氧化碳,氙气和/或真空中)中辐射交联物品(或多个制品),其中制品(或制品)包含 至少一种胺稳定剂,优选另一种任选的稳定剂添加剂。 更优选地,辐射交联在低温(-50至40℃)下进行。 弹性制品(或制品)包含均匀支化的乙烯互聚物(优选基本上为线性的乙烯互聚物),基本上氢化的嵌段聚合物或两者的组合。 耐热弹性制品(特别是纤维)可用于各种耐用或重复使用的织物应用,例如但不限于衣服,衣服和运动服装。 耐热弹性纤维可以使用众所周知的技术方便地形成织物,例如通过使用与棉,尼龙和/或聚酯纤维的共同编织技术。

    Method of making elastic articles having improved heat-resistance
    7.
    发明授权
    Method of making elastic articles having improved heat-resistance 失效
    制造具有改善的耐热性的弹性制品的方法

    公开(公告)号:US06437014B1

    公开(公告)日:2002-08-20

    申请号:US09627534

    申请日:2000-07-28

    IPC分类号: C08K513

    摘要: The present invention relates to a method for making a heat-resistant elastic article and a heat-resistant elastic article. The invention especially relates to a method of making elastic fibers and polymeric elastic fibers wherein the elastic fibers are capable of withstanding dyeing and heat-setting processes that typically are conducted at elevated temperatures (such as 110-230° C. and especially at greater than or equal to 130° C. for minutes). The inventive method comprises radiation crosslinking an article (or plurality of articles) under an inert or oxygen limited atmosphere (for example, in N2, argon, helium, carbon dioxide, xenon and/or a vacuum) wherein the article (or articles) comprises at least one amine stabilizer and preferably another optional stabilizer additive. More preferably, the radiation crosslinking is performed at a low temperature (−50 to 40° C.). The elastic article (or articles) comprises a homogeneously branched ethylene interpolymer (preferably a substantially linear ethylene interpolymer), a substantially hydrogenated block polymer, or a combination of the two. The heat-resistant elastic articles (especially fibers) are useful in various durable or repeated-use fabric applications such as, but not limited to, clothing, under-garments, and sports apparel. The heat-resistant elastic fibers can be conveniently formed into fabrics using well-known techniques such as, for example, by using co-knitting techniques with cotton, nylon, and/or polyester fibers.

    摘要翻译: 本发明涉及一种制造耐热弹性制品和耐热弹性制品的方法。 本发明特别涉及一种制造弹性纤维和聚合物弹性纤维的方法,其中弹性纤维能够耐受染色和热定型过程,其通常在升高的温度(例如110-230℃,特别是大于 或等于130℃,分钟)。 本发明的方法包括在惰性或氧气限制的气氛(例如,在N 2,氩气,氦气,二氧化碳,氙气和/或真空中)中辐射交联物品(或多个制品),其中制品(或制品)包含 至少一种胺稳定剂,优选另一种任选的稳定剂添加剂。 更优选地,辐射交联在低温(-50至40℃)下进行。 弹性制品(或制品)包含均匀支化的乙烯互聚物(优选基本上为线性的乙烯互聚物),基本上氢化的嵌段聚合物或两者的组合。 耐热弹性制品(特别是纤维)可用于各种耐用或重复使用的织物应用,例如但不限于衣服,衣服和运动服装。 耐热弹性纤维可以使用众所周知的技术方便地形成织物,例如通过使用与棉,尼龙和/或聚酯纤维的共同编织技术。

    Electronic Device Module Comprising Heterogeneous Polyolefin Copolymer and Optionally Silane
    10.
    发明申请
    Electronic Device Module Comprising Heterogeneous Polyolefin Copolymer and Optionally Silane 审中-公开
    包含非均相聚烯烃共聚物和任选的硅烷的电子器件模块

    公开(公告)号:US20130087198A1

    公开(公告)日:2013-04-11

    申请号:US13703405

    申请日:2011-06-15

    IPC分类号: H01L31/0203 H05K1/03

    摘要: An electronic device module comprising: A. At least one electronic device, e.g., a solar cell, and B. A polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising (1) a polyolefin copolymer characterized as having has an average Mv and a valley temperature between the interpolymer and high crystalline fraction, Thc, such that the average Mv for a fraction above Thc from ATREF divided by average Mv of the whole polymer from ATREF (Mhc/Mp) is less than about 1.95 and wherein the copolymer has a CDBI of less than 60%, (2) optionally, a vinyl silane, (3) optionally, free radical initiator or a photoinitiator in an amount of at least about 0.05 wt % based on the weight of the copolymer, and (4) optionally, a co-agent in an amount of at least about 0.05 wt % based upon the weight of the copolymer.

    摘要翻译: 一种电子设备模块,包括:A.至少一个电子设备,例如太阳能电池和B.与所述电子设备的至少一个表面紧密接触的聚合材料,所述聚合物材料包括(1)聚烯烃共聚物, 具有在互聚物和高结晶部分Thc之间具有平均Mv和谷值温度,使得在ATREF之上的Thc以上的分数的平均Mv除以ATREF(Mhc / Mp)之外的整个聚合物的平均Mv小于 约1.95,并且其中所述共聚物的CDBI小于60%,(2)任选的乙烯基硅烷,(3)任选的自由基引发剂或光引发剂,其量为至少约0.05重量% 共聚物,和(4)任选地,基于共聚物的重量,至少约0.05重量%的助剂。