摘要:
A fire retardant polycarbonate composition comprises branched polycarbonate resin, polytetrafluoroethylene, a fire retardant free of bromine and chlorine, and an optional siloxane.
摘要:
A method to reduce haze in the production of fire resistant polycarbonate compositions comprising flame retardant salts, wherein the salt is blended with a first polycarbonate to form a concentrate, and the concentrate is then added to a second polycarbonate resin.
摘要:
A method to reduce haze in the production of fire resistant polycarbonate compositions comprising flame retardant salts, wherein the salt is blended with a first polycarbonate to form a concentrate, and the concentrate is then added to a second polycarbonate resin.
摘要:
Improved fire-retarded properties can be imparted to polycarbonate resin composition by incorporating into the polycarbonate a fire-retardant component containing a perfluoroallkane sulfonate such as potassium perfluorobutane sulfonate and a cyclic siloxane such as octaphenylcyclotetrasiloxane. The fire-retardant component is suitably added at levels to form a polycarbonate composition in which the perfluoroalkane sulfonate is present in an amount of from 0.02 to 0.1 phr relative to the composition as a whole, and the cyclic siloxane is present in an amount of at least 0.02 relative to the composition as a whole.
摘要:
A polycarbonate composition comprising a polycarbonate-polysiloxane copolymer resin and a glass flake additive wherein the polycarbonate-polysiloxane copolymer resin has a silicone content in the range of from 3.5 weight % to 7 weight % based on the total weight of the polycarbonate composition and wherein the polycarbonate-polysiloxane copolymer has a haze of less than 10% and wherein the glass flake additive is present in the range of 0.025 weight % to 0.70 weight % based on the total weight of the polycarbonate composition.
摘要:
Disclosed herein are polysiloxane-polycarbonate copolymer articles. In one embodiment, a ⅛th inch thick bar formed from the thermoplastic composition has a B-Y ratio of less than or equal to about 1.75. This article, which has a dimension that is greater than or equal to 1.5 cm, comprises the thermoplastic composition which comprises a polysiloxane-polycarbonate copolymer, wherein the copolymer comprises repeating diorganosiloxane units of formula (1): wherein each R is, independently, a C1-13 monovalent organic group; and E has an average value of 20 to 35.
摘要:
Disclosed herein are polysiloxane-polycarbonate copolymer articles. In one embodiment, a ⅛th inch thick bar formed from the thermoplastic composition has a B-Y ratio of less than or equal to about 1.75. This article, which has a dimension that is greater than or equal to 1.5 cm, comprises the thermoplastic composition which comprises a polysiloxane-polycarbonate copolymer, wherein the copolymer comprises repeating diorganosiloxane units of formula (1): wherein each R is, independently, a C1-13 monovalent organic group; and E has an average value of 20 to 35.
摘要:
Disclosed are aromatic brominated polycarbonate/polyester carbonate/silicone polyimide compositions having improved flame resistance and reduced drippage and heat release rate, comprising by weight:(A) from about 20 to about 77 parts of an aromatic brominated polycarbonate resin;(B) from about 20 to about 77 parts of a polyester carbonate resin;(C) from about 0.5 to about 10 parts of a silicone-polyimide resin;(D) from about 0 to about 25 parts of an aromatic polycarbonate having a molecular weight of from about 40,000 to about 90,000; the sum of (A)-(D) being 100 parts by weight;(E) from about 0.05 to about 2.0 parts of a metal salt of a halogenated monomeric or polymeric aromatic sulfonic acid or mixtures thereof, wherein the metal salt is selected from the group consisting of alkali metal salts, alkaline earth metal salts, and mixtures of the metal salts; and(F) from about 0.1 to about 5.0 parts by weight of filler or a pigment.
摘要:
A method is provided for making siloxane polycarbonate copolymers and blends of other polycarbonates with such copolymers wherein the copolymers and blends have excellent transparency and physical characteristic.
摘要:
The level of anhydride linkages in copolyestercarbonates is decreased by preparing the copolyestercarbonate interfacially in a two-step method from at least one dihydroxyaromatic compound and at least one dicarboxylic acid. The first step is conducted at a pH in the range of about 4.5-9.5, employing the combination of a phase transfer catalyst such as a tetraalkylammonium halide and a tertiary amine such as triethylamine. The proportion of the phase transfer catalyst is in the range of about 3-12 mole percent based on total dihydroxyaromatic compound and dicarboxylic acid employed. In the second phosgenation step, the pH is raised to at least 10 and a stoichiometric phosgene excess of at least 5% is introduced.