摘要:
The present invention relates to a fragrance composition comprising a mixture of diastereomers of 2-isobutyl-4-methyl-tetrahydro-2H-pyran-4-ol, which comprises more than 95 wt. % of the optically inactive cis-racemate and less than 5 wt. % of the optically inactive trans-racemate. The present invention further relates to a method for producing a perfumed product or article as well as perfumed or aromatized articles comprising the fragrance compositions of the present invention.
摘要:
The present invention relates to a method of producing pure or enriched bisabolol by separating substance mixtures comprising bisabolol and farnesol by selective esterification of farnesol and subsequent distillative separation. The invention relates specifically to a method as specified above comprising the selective transesterification of mixtures comprising formyl-bisabolol and formyl-farnesol and subsequent distillative separation.The present invention furthermore relates to a method of producing farnesol esters.
摘要:
The present invention relates to a particularly economic overall method for producing menthol, specifically for producing optically active, essentially enantiomerically and diastereomerically pure L-menthol and racemic menthol, starting from the starting material citral which is available inexpensively on an industrial scale. The method comprises the following steps a.1) catalytic hydrogenation of neral and/or geranial to give citronellal, b.1) cyclization of citronellal to isopulegol in the presence of an acidic catalyst, c.1) purification of isopulegol by crystallization and d.1) catalytic hydrogenation of isopulegol to give menthol.
摘要:
The present invention relates to a process for preparing 4,4′-[1-(trifluoromethyl)alkylidene]bis(2,6-diphenylphenols), in particular for preparing 4,4′-[1-(trifluoromethyl)ethylidene]bis(2,6-diphenylphenol), which comprises the self-condensation of cyclohexanone in the presence of a basic catalyst to form tricyclic condensation products, dehydrogenation of the resulting tricyclic condensation products in the presence of a supported transition metal catalyst in the condensed phase to form 2,6-diphenylphenol and reaction of the 2,6-diphenylphenol with a trifluoromethyl ketone. The invention further provides an improved process for preparing 2,6-diphenylphenol by aldol self-condensation of cyclohexanone.
摘要:
The present invention relates to a continuous process for preparing racemic or optically active menthol in pure or enriched form by distillatively separating menthol from substance mixtures which comprise essentially menthol and diastereomers thereof. This distillatiive separation is performed in a dividing wall column with 50 to 300 theoretical plates and one or more side draw points at an absolute operating pressure of 5 to 500 mbar.
摘要:
The present invention relates to a method of producing ethylgeranonitrile through reaction of ethylheptenone with a deprotonated nitrile and, if appropriate, subsequent saponification and decarboxylation. Moreover, the invention relates to mixtures comprising 3,7-dimethyl-2,6-nonadienenitrile and at least one compound selected from the group of compounds 3,7-dimethyl-3,6-nonadienenitrile and 3-methylene-7-methyl-6-nonenenitrile, and to fragrance compositions comprising these.
摘要:
The present invention relates to a continuous process for preparing racemic or optically active menthol in pure or enriched form by distillatively separating menthol from substance mixtures which comprise essentially menthol and diastereomers thereof. This distillatiive separation is performed in a dividing wall column with 50 to 300 theoretical plates and one or more side draw points at an absolute operating pressure of 5 to 500 mbar.
摘要:
The invention relates to an ankle orthosis comprising a U-shaped support stirrup made of a flexible material, the sides of which stirrup converge beneath the foot in a web projecting as a tab toward the metatarsus, extend past the bones, and are held together at their end regions by a fastening strap wrapping around the leg. The tab has a convexity, which presses against the cuboid bone of the foot due to a preloading of the tab.
摘要:
The process for the preparation of carbonyl compounds of the formula I where R1 and R2 are a hydrocarbon radical, or R1 and R2 together are an unsubstituted or substituted alkylene group, and X is=O or two alkoxy groups, comprises oxidizing alcohols of the formula II where R1 to R2 and X are as defined above, with oxygen in the gaseous phase a) at temperatures of from 270 to 600° C. on silver coated catalysts which comprise an abrasion-resistant coating of metallic silver on a core of inert support material, or b) at temperatures of from 450 to 750° C. on silver crystals and/or copper crystals having a particle size of from 0.1 to 2.5 mm for a residence time of at most 0.1 second. Also claimed is an advantageous overall process for the preparation of &agr;-diketones, preferably diacetal, from the corresponding ketone, in particular methyl ethyl ketone, via the carbonyl compounds of the formula I where X is two alkoxy groups.
摘要:
A regulating valve comprising a housing having a cylindrical valve chamber, the valve chamber being provided with at least one inlet and at least two outlets, the inlet and the outlets being at least partially closeable as needed by a common valve body arranged in the valve chamber and rotatable around an axis, the valve body being operable by an actuator, the inlet and/or at least one of the outlets being surrounded by a sealing device on the side of the housing facing the valve body and the sealing device being able to be brought into sealing engagement with the valve body under elastic preload. The valve body is designed having the shape of the segment of a cylinder and is bounded on the peripheral side by two boundary surfaces which each have an edge on the side facing the housing, the edge overtravelling the inlet during its opening being designed as an efflux edge and having an elliptically shaped recess extending in axial direction. Configured in the valve body is a duct-shaped opening which extends between the boundary surfaces and penetrates them.