摘要:
5-acylamino-1-phenylpyrazole herbicides of the formula ##STR1## in which R represents cyano, alkoxycarbonyl, alkenyloxycarbonyl, alkinyloxycarbonyl, aminocarbonyl, alkylaminocarbonyl, alkenylaminocarbonyl or alkinylaminocarbonyl,R.sup.1 represents alkyl, alkenyl, alkinyl, alkoxyalkyl, alkylthioalkyl, halogenoalkyl, cycloalkyl or optionally substituted aryl, and, in the case in which Y represents the ##STR2## group, also represents hydrogen, X represents oxygen or sulphur,Y represents oxygen, sulphur or the ##STR3## group, whereinZ represents hydrogen, alkyl, alkoxy, alkenyl, alkinyl or optionally substituted aryl,R.sup.2 represents hydrogen or the radical ##STR4## and R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7, which are identical or different, represent hydrogen, halogen, cyano, nitro, alkyl, alkoxy, alkylsulphonyl, alkoxycarbonyl or a radical --(X').sub.n --R.sup.8,whereinX' represents oxygen, sulphur, sulphinyl or sulphonyl,n represents 0 or 1 andR.sup.8 represents halogenoalkyl, with the proviso that at least one of the radicals R.sup.3, R.sup.4, R.sup.5, R.sup.6 or R.sup.7 represents a radical --(X').sub.n --R.sup.8, but R does not represent cyano when R.sup.5 represents trifluoromethyl.
摘要:
5-Amino-4-heterocyclyl-1-phenylpyrazoles of the formula ##STR1## in which R.sup.1 represents hydrogen or alkyl,R.sup.2 represents hydrogen or a radical ##STR2## R.sup.3 represents hydrogen, ##STR3## alkyl, alkenyl or alkinyl, R.sup.4, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 independently of one another represent hydrogen, cyano, nitro, halogen, alkyl, alkoxy, alkoxycarbonyl, halogenoalkyl, halogenoalkoxy or a radical --S(O).sub.n --R.sup.10,R.sup.9 represents hydrogen, alkyl, alkenyl, alkinyl, halogenoalkyl, alkoxyalkyl, alkylthioalkyl, optionally substituted cycloalkyl, optionally substituted aryl, alkoxy, alkylthio, optionally substituted aryloxy or aryloxyalkyl, optionally substituted arylthio, alkylamino, dialkylamino or optionally substituted arylamino,R.sup.10 represents alkyl, halogenoalkyl, amino, alkylamino or dialkylamino,X represents oxygen or sulphur,n represents the number 0, 1 or 2 andHet represents a saturated or unsaturated optionally substituted heterocyclic radical,exhibit herbicidal and plant growth-regulating activity.
摘要:
Herbicidally active 5-amino-1-phenylpyrazoles of the formula ##STR1## in which R is CN, or an ester or amido group,R.sup.1 is an organic radical,R.sup.2 is an organic radical, hydrogen or an acyl or thioacyl radical,R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 can be hydrogen or various organic radicals but at least one is a haloalkyl, haloalkoxy, haloalkylthio, haloalkylsulphinyl or haloalkylsulphonyl radical, but R is not CN at the same time as R.sup.5 is CF.sub.3. The compounds ##STR2## are intermediates therefor and are also herbicidal.
摘要翻译:其中R为CN或式(Ⅰ)或酰氨基的式“IMAGE”的除草活性的5-氨基-1-苯基吡唑为R1为有机基团,R2为有机基团,氢或酰基或硫代酰基,R3, R 4,R 5,R 6和R 7可以是氢或各种有机基团,但至少一个是卤代烷基,卤代烷氧基,卤代烷硫基,卤代烷基亚磺酰基或卤代烷基磺酰基,但R 5不是CN,同时是R5是CF3。 化合物“IMAGE”是其中间体,也是除草剂。
摘要:
Herbicidally and fungicidally active novel 2-(alkoximiminoalkoxycarbonyl)-phenylsulphonylureas of the formula ##STR1## in which R.sup.1 represents hydrogen, halogen, alkyl, halogenoalkyl, alkoxy or nitro,R.sup.2 represents hydrogen, alkyl or optionally substituted aryl,R.sup.3 represents hydrogen or alkyl,R.sup.4 represents hydrogen, alkyl, alkoxy, alkylthio, alkoxyalkyl, alkylthioalkyl, cyano, alkoxycarbonyl or optionally substituted aryl,R.sup.5 represents hydrogen, alkyl, alkenyl, alkinyl, halogenoalkyl, halogenoalkenyl, alkoxyalkyl, alkylthioalkyl or optionally substituted aralkyl,Y represents oxygen or sulphur andHet represents a heterocyclic radical of the formula ##STR2## wherein E represents nitrogen or the CH group andR.sup.6 and R.sup.7 independently of one another each represent alkyl, alkoxy or alkoxyalkyl.
摘要:
Novel substituted tetrahydrothiopyran-2,4-dione herbicides of the formula ##STR1## in which R.sup.1 is hydrogen, alkyl, alkenyl, alkinyl, alkoxyalkyl, alkylthioalkyl, halogenoalkyl, cycloalkyl or optionally substituted aryl,R.sup.2 is alkyl, alkenyl, alkinyl, alkoxyalkyl, alkylthioalkyl, halogenoalkyl, halogenoalkenyl, alkoxycarbonylalkyl, alkoximinoalkyl, optionally substituted aralkyl or optionally substituted heterocyclylalkyl, andR.sup.3 and R.sup.4 each independently is hydrogen, alkyl, alkoxyalkyl, alkylthioalkyl, cycloalkyl, optionally substituted aryl, optionally substituted aryloxyalkyl or optionally substituted aralkyl,or metal salts thereof.
摘要:
5-Halogenoalkyl-1,3,4-thiadiazol-2-yloxyacetamides of the formula ##STR1## in which R.sup.1 is halogenoalkyl, with the exception of trifluoromethyl, andR.sup.2 and R.sup.3 each independently is hydrogen, alkyl, alkenyl, alkinyl, in each case optionally substituted cycloalkyl or cycloalkenyl, halogenoalkyl, alkoxyalkyl, alkoxyalkylenoxy, alkoxy, aralkyl or optionally substituted aryl, orR.sup.2 and R.sup.3, together with the nitrogen atom to which they are bonded, form an optionally substituted heterocyclic radical which can contain further hetero-atoms,which possess herbicidal and fungicidal activity. The intermediates 5-chlorodifluoromethyl- and 5-dichlorofluoromethyl-2-chloro-1,3,4- thiadiazole are also new.
摘要:
Herbicidally active oxyguanidine derivatives of the formula ##STR1## in which M represents hydrogen or one equivalent of a metal,R.sup.1 represents halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.2 -halogenoalkyl, C.sub.1 -C.sub.4 -alkoxy, phenyl or C.sub.1 -C.sub.2 -alkoxy-carbonyl,R.sup.2 represents hydrogen or the radical ##STR2## and R.sup.3 represents C.sub.4 -C.sub.12 -alkyl, isopropyl or--if M represents one equivalent of a metal--also propyl, or represents C.sub.2 -C.sub.12 -halogenoalkyl, C.sub.1 -C.sub.4 -alkoxycarbonyl-C.sub.1 -C.sub.2 -alkyl, aminocarbonylmethyl, C.sub.1 -C.sub.4 -alkylaminocarbonylmethyl, di-C.sub.1 -C.sub.4 -alkylaminocarbonylmethyl, C.sub.3 -C.sub.12 -alkenyl, C.sub.3 -C.sub.12 -alkinyl, benzyl which is substituted by halogen, nitro, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkoxycarbonyl, or phenyl, benzhydryl, or phenethyl, all optionally substituted by halogen, nitro, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkoxycarbonyl, or carboxy-C.sub.1 -Ca.sub.2 -alkyl,or adducts thereof with strong acids.
摘要:
Herbicidally active novel N,N'-bis-sulphonyl guanidines of the formula ##STR1## in which M is hydrogen, a metal or an ammonium radical, andR.sup.4, R.sup.5, R.sup.40 and R.sup.41 are various organic radicals.
摘要:
The novel substituted carboxylic acid anilides of the formula ##STR1## in which X represents oxygen or sulphur,R.sup.1 represents hydrogen, halogen, alkyl with 1 to 6 carbon atoms, trifluoromethyl, optionally substituted phenyl, alkoxy with 1 to 6 carbon atoms or alkylmercapto with 1 to 6 carbon atoms,R.sup.2 represents halogen or methyl,n represents 0, 1 or 2,R.sup.3 represents hydrogen, halogen, optionally substituted alkyl with 1 to 6 carbon atoms, optionally substituted aryl, optionally substituted aralkyl or the radicals --OR.sup.6 or --SO.sub.m --R.sup.6,whereinR.sup.6 represents optionally substituted alkyl with 1 to 6 carbon atoms or optionally substituted aryl andm represents 0, 1 or 2, andR.sup.4 and R.sup.5 independently of one another represent halogen or optionally substituted alkyl with 1 to 6 carbon atoms, orR.sup.4 and R.sup.5, together with the adjacent carbon atom, represent an optionally substituted, saturated or unsaturated carbocyclic ring with 3 to 8 ring carbon atoms,are very active herbicides.
摘要翻译:式(I)的新型取代的羧酸酰苯胺,其中X表示氧或硫,R 1表示氢,卤素,具有1至6个碳原子的烷基,三氟甲基,任选取代的苯基,具有1至6个碳原子的烷氧基 或具有1至6个碳原子的烷基巯基,R 2表示卤素或甲基,n表示0,1或2,R 3表示氢,卤素,任选取代的具有1至6个碳原子的烷基,任选取代的芳基,任选取代的芳烷基或基团 - OR 6或-SO m -R 6,其中R 6表示任选取代的具有1至6个碳原子的烷基或任选取代的芳基,m表示0,1或2,R 4和R 5彼此独立地表示卤素或任选取代的具有1至6个 碳原子或R 4和R 5与相邻的碳原子一起表示任选取代的饱和或不饱和的具有3至8个环碳原子的碳环,是非常活泼的除草剂。
摘要:
Novel herbicides of the formula ##STR1## in which R.sup.1 and R.sup.2 each independently is alkyl,X is cyano, alkoxycarbonyl or aminocarbonyl, andY is hydrogen or, if X is cyano, may also be trimethylsilyl,can be prepared by reacting an imidazo-pyrrolo-pyridine of the formula ##STR2## with trimethylsilyl cyanide of the formula(CH.sub.3).sub.3 Si--CN.