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11 条记录 (耗时 0.017 秒)

    Process for the preparation of thiocarbamates
    1.
    发明授权
    Process for the preparation of thiocarbamates 失效
    硫代氨基甲酸酯的制备方法

    公开(公告)号：US4617416A

    公开(公告)日：1986-10-14

    申请号：US713603

    申请日：1985-03-19

    申请人： Renato Ugo ,  Stefano Campolmi ,  Vittorio Carletti

    发明人： Renato Ugo ,  Stefano Campolmi ,  Vittorio Carletti

    IPC分类号： C07B61/00 ,  B01J31/00 ,  C07C67/00 ,  C07C325/00 ,  C07C333/02 ,  C07C333/04 ,  C07C333/06 ,  C07C333/20 ,  C07C333/22 ,  C07C155/02

    CPC分类号： C07C333/02

    摘要： There is disclosed a process for the preparation of thiocarbamates having the following general formula: ##STR1## wherein: R represents alkyl C.sub.1 -C.sub.4 optionally substituted with one or more halogen atoms, alkenyl C.sub.2 -C.sub.4 optionally substituted with one or more halogen atoms, phenyl optionally substituted with one or more halogen atoms, benzyl optionally substituted with one or more halogen atoms on the phenyl ring;R.sup.1 and R.sup.2, equal or different from one another, represent alkyl C.sub.1 -C.sub.4 or cycloalkyl;consisting in reacting organic dithiocarbonates with organic carbamoyl halides, in the presence of an aqueous solution of an inorganic base and a phase transfer catalyst, at a temperature of 10.degree. to 50.degree. C. for time periods of 5 to 10 hours.The thiocarbamates obtained are used as herbicides, fungicides, etc., and in general in various fields of "fine chemicals".

    摘要翻译： 公开了制备具有以下通式的硫代氨基甲酸酯的方法：其中：R表示任选被一个或多个卤素原子取代的C 1 -C 4烷基，任选被一个或多个卤素原子取代的烯基C 2 -C 4，苯基 任选地被一个或多个卤素原子取代，苯基上任选被一个或多个卤素原子取代的苄基; R1和R2彼此相同或不同，表示烷基C1-C4或环烷基; 在有机二硫代碳酸酯与有机氨基甲酰卤反应的条件下，在无机碱和相转移催化剂的水溶液存在下，在10〜50℃的温度下反应5〜10小时。 所得的硫代氨基甲酸酯用作除草剂，杀真菌剂等，一般用于“精细化学品”的各个领域。

    Process for preparing N-methylcarbamate of methylthioacetaldoxime
    2.
    发明授权
    Process for preparing N-methylcarbamate of methylthioacetaldoxime 失效
    制备甲硫基乙醛肟的N-甲基氨基甲酸酯的方法

    公开(公告)号：US4333882A

    公开(公告)日：1982-06-08

    申请号：US234842

    申请日：1981-02-17

    申请人： Stefano Campolmi ,  Vittorio Carletti ,  Marcello Marchi

    发明人： Stefano Campolmi ,  Vittorio Carletti ,  Marcello Marchi

    IPC分类号： C07C381/04 ,  C07C20060101 ,  C07C67/00 ,  C07C325/00 ,  C07C119/18

    CPC分类号： C07C327/58

    摘要： A process is disclosed for preparing N-methylcarbamate of methylthioacetaldoxime, characterized in that an aqueous suspension of methylthioacetaldoxime is additioned, in one step only, with gaseous phosgene and aqueous methylamine in the presence of an inorganic alkaline base substantially at room temperature and pressure.The product obtained, known commercially as "Methomyl", is an important active principle in the field of insecticides.

    摘要翻译： 公开了一种制备甲基硫代乙醛肟的N-甲基氨基甲酸酯的方法，其特征在于在无机碱性碱存在下，基本上在室温和高压下，仅在一个步骤中仅加入甲基硫代乙醛肟的水性悬浮液与气体光气和甲胺水溶液。 获得的商品名为“甲氧基”，是杀虫剂领域的重要活性成分。

    Process for preparing 2-(6'-methoxy-2'-naphthyl)-propionic acid
    3.
    发明授权
    Process for preparing 2-(6'-methoxy-2'-naphthyl)-propionic acid 失效
    制备2-（6'-甲氧基-2'-萘基） - 丙酸的方法

    公开(公告)号：US4239914A

    公开(公告)日：1980-12-16

    申请号：US40955

    申请日：1979-05-21

    申请人： Stefano Campolmi ,  Maria G. Felicioli ,  Vittorio Carletti ,  Roberto Santi

    发明人： Stefano Campolmi ,  Maria G. Felicioli ,  Vittorio Carletti ,  Roberto Santi

    IPC分类号： C07C51/00 ,  C07C51/36 ,  C07C59/64 ,  C07C67/00 ,  C07C65/00 ,  C07C65/11

    CPC分类号： C07C59/64 ,  C07C51/36

    摘要： There is disclosed an improved process for selectively preparing 2-(6'-methoxy-2'-naphthyl)-propionic acid in the active antipode (+) form by reacting 2-acetyl-6-methoxynaphthalene, in an organic solvent, with a system consisting of(a) a haloform selected from CHCl.sub.3 and CHBr.sub.3 ;(b) an aqueous solution of an inorganic base selected from NaOH and KOH; and(c) a crown-ether or hydrocarbyl salt of quaternary ammonium, or of phosphonium;and hydrogenating the 2-(6'-methoxy-2'-naphthyl)-acrylic acid thus formed to obtain 2-(6'-methoxy-2'-naphthyl)-propionic acid.

    摘要翻译： 公开了一种通过使有机溶剂中的2-乙酰基-6-甲氧基萘与有机溶剂中的2-（6'-甲氧基-2'-萘基）丙酸与有机溶剂反应来选择性地制备活性对映体（+）形式的2-（6'-甲氧基-2'-萘基） 系统由（a）选自CHCl 3和CHBr 3的卤代基组成; （b）选自NaOH和KOH的无机碱的水溶液; 和（c）季铵或鏻的冠醚或烃基盐; 并氢化由此形成的2-（6'-甲氧基-2'-萘基） - 丙烯酸，得到2-（6'-甲氧基-2'-萘基） - 丙酸。

    Process for preparing the mono-methallyl ether of pyrocatechin
    4.
    发明授权
    Process for preparing the mono-methallyl ether of pyrocatechin 失效
    制备邻苯二酚单甲基烯丙基醚的方法

    公开(公告)号：US4390733A

    公开(公告)日：1983-06-28

    申请号：US263598

    申请日：1981-05-14

    申请人： Stefano Campolmi ,  Vittorio Carletti ,  Marcello Marchi

    发明人： Stefano Campolmi ,  Vittorio Carletti ,  Marcello Marchi

    IPC分类号： C07C41/16 ,  C07C41/00 ,  C07C43/23 ,  C07C67/00

    CPC分类号： C07C43/23

    摘要： The mono-methallyl ether of pyrocatechin of formula (I): ##STR1## is prepared by reacting pyrocatechin of formula (II): ##STR2## with a methallyl halide of formula (III): ##STR3## in a homogeneous dissolving medium, e.g., alcohols, aliphatic polyalcohols and monoethers thereof, or water, in the presence of an organic or inorganic base.The mono-methallyl ether of pyrocatechin is used as an intermediate for organic syntheses and, in particular for synthesizing the product of formula (IV); ##STR4## which is marketed under the tradename "Carbofuran" and is a compound which is the active principle in soil insecticides of different overall compositions which are available on the market.

    摘要翻译： 式（I）的焦儿子的单 - 甲代烯丙基醚：通过使式（II）的焦儿茶素：II（II）与式（III）的甲代烯丙基酯反应制备： III）在有机或无机碱的存在下在均匀的溶解介质中，例如醇，脂族多元醇和其单醚或水。 焦儿茶酚的单甲代烯丙基醚用作有机合成的中间体，特别是用于合成式（IV）的产物; （IV），以商品名“呋喃丹”销售，是市场上可获得的不同总成分的土壤杀虫剂的活性成分的化合物。

    Display book with viewing compartment and self-illumination
    6.
    发明申请
    Display book with viewing compartment and self-illumination 审中-公开
    显示书与观景室和自我照明

    公开(公告)号：US20060066094A1

    公开(公告)日：2006-03-30

    申请号：US11282440

    申请日：2005-11-17

    申请人： Gabriella Piomboni ,  Stefano Campolmi

    发明人： Gabriella Piomboni ,  Stefano Campolmi

    IPC分类号： B42D3/00

    CPC分类号： B42D3/123

    摘要： The present invention relates to a display book system comprising a frame which defines a viewing window and a passé-par-tout which defines a viewing compartment, in a position aligned with the window of the frame, for accommodating a subject to be displayed and which is visible through the viewing window of the frame. A book portion can be annexed thereto to form the display book system. In alternative embodiments, a display book system is modified to provide a viewing compartment formed in association with the framed picture portion (frame, passé-par-tout) to allow display of discrete objects including three dimensional objects such as figurines as well as images and pictures, opaque or translucent, which are substantially two dimensional. Illumination capability is provided to allow lighting of the object displayed (front or back-lit) or self illumination. The frame itself can also be illuminated for, e.g., decorative motivation.

    摘要翻译： 本发明涉及一种显示书系统，其包括限定观察窗的框架和在与框架的窗口对准的位置中限定观察室的通行对准，用于容纳要显示的对象，以及哪个 通过框架的查看窗口可见。 书籍部分可以附在其上以形成展示簿系统。 在替代实施例中，修改显示书系统以提供与框架图片部分（框架，通配对）相关联地形成的观看室，以允许显示离散对象，包括诸如雕像以及图像的三维对象，以及 图片，不透明或半透明，其基本上是二维的。 提供照明能力以允许照亮所显示的物体（正面或背光）或自发光。 框架本身也可以被照亮，例如装饰动机。