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公开(公告)号：US10081612B2
公开(公告)日：2018-09-25
申请号：US15417110
申请日：2017-01-26
申请人： Rennovia Inc.
发明人： Valery Sokolovskii , Mayya Lavrenko , Alfred Hagemeyer , Eric L. Dias , James A. W. Shoemaker , Vincent J. Murphy
IPC分类号： C07D307/28 , C07D307/12 , C07C29/60 , C07D307/42 , C07C29/17 , C07C29/132 , C07C29/10 , C07C29/09 , B01J8/04
CPC分类号： C07D307/28 , B01J8/04 , B01J2208/027 , C07C29/09 , C07C29/103 , C07C29/132 , C07C29/172 , C07C29/60 , C07D307/12 , C07D307/42 , C07C31/22 , C07C31/20
摘要： Industrial scale conversions of 5-hydroxymethylfurfural to commodity chemicals such as 1,2,6-hexanetriol and 1,6-hexanediol by chemocatalytic conversions using hydrogen and a heterogeneous reduction catalyst are provided. The reactions are suitable for use in continuous flow reactors. Methods of carrying out the conversions are provided, as are product and catalyst compositions.
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公开(公告)号：US20170165641A1
公开(公告)日：2017-06-15
申请号：US15441732
申请日：2017-02-24
申请人： Rennovia Inc.
发明人： Eric L. Dias , Alfred Hagemeyer , Hong X. Jiang , James Longmire , James A.W. Shoemaker , Valery Sokolovskii , Guang Zhu , Vincent J. Murphy , Gary M. Diamond
CPC分类号： B01J21/18 , B01J23/06 , B01J23/18 , B01J23/22 , B01J23/28 , B01J23/34 , B01J23/40 , B01J23/42 , B01J23/52 , B01J23/6567 , B01J23/70 , B01J23/755 , B01J23/892 , B01J35/002 , B01J35/008 , B01J35/0086 , B01J35/023 , B01J35/04 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J35/1066 , B01J35/1085 , B01J37/0009 , B01J37/0018 , B01J37/0201 , B01J37/0215 , B01J37/084 , B01J37/10 , C04B35/532 , C04B35/636 , C04B35/6365 , C04B35/638 , C04B38/0615 , C04B2111/0081 , C04B2235/424 , C04B2235/5409 , C04B2235/6586 , C04B2235/96 , C07C29/149 , C07C29/60 , C07C51/235 , C07C51/377 , C07C209/16 , C09C1/48 , C09C1/56 , C07C211/12 , C07C55/14 , C07C59/285 , C07C31/20 , C04B38/0054
摘要： Shaped porous carbon products and processes for preparing these products are provided. The shaped porous carbon products can be used, for example, as catalyst supports and adsorbents. Catalyst compositions including these shaped porous carbon products, processes of preparing the catalyst compositions, and various processes of using the shaped porous carbon products and catalyst compositions are also provided.
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3.发明申请公开(公告)号：US20170197930A1
公开(公告)日：2017-07-13
申请号：US15404996
申请日：2017-01-12
申请人： Rennovia Inc. , Stora Enso Oyj
发明人： Valery Sokolovskii , Vincent J. Murphy , Thomas R. Boussie , Gary M. Diamond , Eric L. Dias , Guang Zhu , James M. Longmire , Stanley Herrmann , Staffan Torssell , Mayya Lavrenko
IPC分类号： C07D307/68 , B01J8/02
CPC分类号： C07D307/68 , B01J8/02 , B01J2208/00893 , Y02P20/582
摘要： The present disclosure provides processes for the production of 2-5-furandicarboxylic acid (FDCA) and intermediates thereof by the chemocatalytic conversion of a furanic oxidation substrate. The present disclosure further provides processes for preparing derivatives of FDCA and FDCA-based polymers. In addition, the present disclosure provides crystalline preparations of FDCA, as well as processes for making the same.
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公开(公告)号：US09586920B2
公开(公告)日：2017-03-07
申请号：US14957551
申请日：2015-12-02
申请人： Rennovia Inc.
发明人： Valery Sokolovskii , Mayya Lavrenko , Alfred Hagemeyer , Eric L. Dias , James A. W. Shoemaker , Vincent J. Murphy
IPC分类号： C07D307/28 , C07D307/12 , C07D307/42 , C07C29/132 , C07C29/17 , C07C29/60 , B01J8/04 , C07C29/09 , C07C29/10
CPC分类号： C07D307/28 , B01J8/04 , B01J2208/027 , C07C29/09 , C07C29/103 , C07C29/132 , C07C29/172 , C07C29/60 , C07D307/12 , C07D307/42 , C07C31/22 , C07C31/20
摘要： Industrial scale conversions of 5-hydroxymethylfurfural to commodity chemicals such as 1,2,6-hexanetriol and 1,6-hexanediol by chemocatalytic conversions using hydrogen and a heterogeneous reduction catalyst are provided. The reactions are suitable for use in continuous flow reactors. Methods of carrying out the conversions are provided, as are product and catalyst compositions.
摘要翻译： 提供了通过使用氢和多相还原催化剂的化学转化将5-羟甲基糠醛转化为商品化学品如1,2,6-己三醇和1,6-己二醇的工业规模转化。 这些反应适用于连续流动反应器。 提供了进行转化的方法，以及产物和催化剂组合物。
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公开(公告)号：US20150321187A1
公开(公告)日：2015-11-12
申请号：US14699942
申请日：2015-04-29
申请人： Rennovia Inc.
发明人： Eric L. Dias , Alfred Hagemeyer , Hong X. Jiang , James Longmire , James A.W. Shoemaker , Valery Sokolovskii , Guang Zhu , Vincent J. Murphy , Gary M. Diamond
IPC分类号： B01J35/04 , C07C51/377 , C07C29/60 , C07C209/16 , B01J35/02 , B01J37/10 , B01J37/00 , B01J37/02 , B01J35/10 , B01J35/00 , C07C51/235 , B01J37/04
CPC分类号： B01J21/18 , B01J23/06 , B01J23/18 , B01J23/22 , B01J23/28 , B01J23/34 , B01J23/40 , B01J23/42 , B01J23/52 , B01J23/6567 , B01J23/70 , B01J23/755 , B01J23/892 , B01J35/002 , B01J35/008 , B01J35/0086 , B01J35/023 , B01J35/04 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J35/1066 , B01J35/1085 , B01J37/0009 , B01J37/0018 , B01J37/0201 , B01J37/0215 , B01J37/084 , B01J37/10 , C04B35/532 , C04B35/636 , C04B35/6365 , C04B35/638 , C04B38/0615 , C04B2111/0081 , C04B2235/424 , C04B2235/5409 , C04B2235/6586 , C04B2235/96 , C07C29/149 , C07C29/60 , C07C51/235 , C07C51/377 , C07C209/16 , C09C1/48 , C09C1/56 , C07C211/12 , C07C55/14 , C07C59/285 , C07C31/20 , C04B38/0054
摘要： Shaped porous carbon products and processes for preparing these products are provided. The shaped porous carbon products can be used, for example, as catalyst supports and adsorbents. Catalyst compositions including these shaped porous carbon products, processes of preparing the catalyst compositions, and various processes of using the shaped porous carbon products and catalyst compositions are also provided.
摘要翻译： 提供成形的多孔碳产品和制备这些产品的方法。 成形的多孔碳产品可以用作例如催化剂载体和吸附剂。 还提供了包括这些成形多孔碳产品的催化剂组合物，制备催化剂组合物的方法，以及使用成形多孔碳产物和催化剂组合物的各种方法。
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公开(公告)号：US09682368B2
公开(公告)日：2017-06-20
申请号：US14699942
申请日：2015-04-29
申请人： Rennovia Inc.
发明人： Eric L. Dias , Alfred Hagemeyer , Hong X. Jiang , James Longmire , James A. W. Shoemaker , Valery Sokolovskii , Guang Zhu , Vincent J. Murphy , Gary M. Diamond
IPC分类号： B01J35/04 , C07C29/60 , B01J37/10 , C07C51/235 , C07C51/377 , C04B35/636 , C04B35/638 , B01J37/00 , B01J37/02 , B01J35/10 , B01J35/00 , B01J35/02 , B01J37/08 , B01J21/18 , B01J23/42 , B01J23/52 , B01J23/656 , B01J23/89 , C07C29/149 , C07C209/16 , C04B35/532 , C04B38/06 , B01J23/40 , B01J23/06 , B01J23/18 , B01J23/22 , B01J23/28 , B01J23/34 , B01J23/70 , B01J23/755 , C04B111/00
CPC分类号： B01J21/18 , B01J23/06 , B01J23/18 , B01J23/22 , B01J23/28 , B01J23/34 , B01J23/40 , B01J23/42 , B01J23/52 , B01J23/6567 , B01J23/70 , B01J23/755 , B01J23/892 , B01J35/002 , B01J35/008 , B01J35/0086 , B01J35/023 , B01J35/04 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J35/1066 , B01J35/1085 , B01J37/0009 , B01J37/0018 , B01J37/0201 , B01J37/0215 , B01J37/084 , B01J37/10 , C04B35/532 , C04B35/636 , C04B35/6365 , C04B35/638 , C04B38/0615 , C04B2111/0081 , C04B2235/424 , C04B2235/5409 , C04B2235/6586 , C04B2235/96 , C07C29/149 , C07C29/60 , C07C51/235 , C07C51/377 , C07C209/16 , C09C1/48 , C09C1/56 , C07C211/12 , C07C55/14 , C07C59/285 , C07C31/20 , C04B38/0054
摘要： Shaped porous carbon products and processes for preparing these products are provided. The shaped porous carbon products can be used, for example, as catalyst supports and adsorbents. Catalyst compositions including these shaped porous carbon products, processes of preparing the catalyst compositions, and various processes of using the shaped porous carbon products and catalyst compositions are also provided.
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公开(公告)号：US20170120223A1
公开(公告)日：2017-05-04
申请号：US15132048
申请日：2016-04-18
申请人： Rennovia Inc.
发明人： Valery Sokolovskii , Alfred Hagemeyer , James A.W. Shoemaker , Elif Ispir Gürbüz , Guang Zhu , Eric L. Dias
IPC分类号： B01J23/755 , B01J23/652 , B01J21/18 , B01J35/00 , B01J35/04 , C07C51/31 , B01J37/00 , B01J37/08 , B01J37/18 , C07D307/20 , C07C29/60 , C07C209/16 , B01J23/68 , B01J37/04
CPC分类号： B01J23/755 , B01J21/18 , B01J23/30 , B01J23/42 , B01J23/6527 , B01J23/687 , B01J27/22 , B01J35/0006 , B01J35/023 , B01J35/026 , B01J35/04 , B01J35/1004 , B01J35/1033 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J35/1066 , B01J37/0018 , B01J37/04 , B01J37/084 , B01J37/18 , B01J2523/00 , C01B32/382 , C01P2004/60 , C01P2006/12 , C01P2006/16 , C04B35/111 , C04B35/117 , C04B35/532 , C04B35/636 , C04B35/6365 , C04B2235/3258 , C04B2235/3279 , C04B2235/40 , C04B2235/404 , C04B2235/405 , C04B2235/407 , C04B2235/408 , C04B2235/424 , C04B2235/442 , C04B2235/5409 , C04B2235/6021 , C04B2235/6562 , C04B2235/6567 , C04B2235/658 , C04B2235/6582 , C04B2235/6586 , C04B2235/664 , C07C29/60 , C07C51/313 , C07C51/377 , C07C209/16 , C07D307/20 , C09C1/48 , C07C59/285 , C07C55/14 , C07C31/20 , B01J2523/19 , B01J2523/69 , B01J2523/828 , B01J2523/31 , B01J2523/847
摘要： The present invention provides a porous metal-containing carbon-based material that is stable at high temperatures under aqueous conditions. The porous metal-containing carbon-based materials are particularly useful in catalytic applications. Also provided, are methods for making and using porous shaped metal-carbon products prepared from these materials.
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8.发明申请公开(公告)号：US20170015642A1
公开(公告)日：2017-01-19
申请号：US15132178
申请日：2016-04-18
申请人： RENNOVIA, INC.
发明人： Valery Sokolovskii , Eric L. Dias , Hong X. Jiang , James M. Longmire , Vincent J. Murphy , Christopher Paul Dunckley , Gary M. Diamond , Thomas R. Boussie , James A.W. Shoemaker , Liza Lopez Soto
IPC分类号： C07D307/46 , B01D61/14 , C07D307/42
CPC分类号： C07D307/46 , B01D61/027 , B01D61/145 , B01D61/362 , B01D61/58 , B01D2311/04 , B01D2311/06 , B01D2311/2623 , B01D2311/2626 , B01D2311/263 , B01D2311/2649 , B01D2311/2669 , C07D307/42 , C07D307/50
摘要： The present invention relates generally to processes for converting fructose-containing feedstocks to a product comprising 5-(hydroxymethyl)furfural (HMF) and water in the presence of water, solvent and an acid catalyst. In some embodiments, the conversion of fructose to HMF is controlled at a partial conversion endpoint characterized by a yield of HMF from fructose that does not exceed about 80 mol %. In these and other embodiments, the processes provide separation techniques for separating and recovering the product, unconverted fructose, solvent and acid catalyst to enable the effective recovery and reutilization of reaction components.
摘要翻译： 本发明一般涉及在水，溶剂和酸催化剂存在下将含果糖的原料转化成包含5-（羟甲基）糠醛（HMF）和水的产物的方法。 在一些实施方案中，将果糖转化成HMF是在部分转化终点处控制的，其特征在于果糖的HMF的产率不超过约80mol％。 在这些和其它实施方案中，该方法提供了用于分离和回收产物，未转化的果糖，溶剂和酸催化剂的分离技术，以使得能够有效地回收和再利用反应组分。
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