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公开(公告)号：US07157549B2
公开(公告)日：2007-01-02
申请号：US10852980
申请日：2004-05-25
Applicant: Roderic P. Quirk , Robert T. Mathers
Inventor： Roderic P. Quirk , Robert T. Mathers
IPC: C08G65/10
CPC classification number: C08G65/105
Abstract: A method is provided for polymerizing oxiranes by employing a lithium-containing polymerization initiator in a liquid reaction medium devoid of polymerization additives. Linear and star polymers can be produced by practicing the subject method.
Abstract translation: 提供了在不含聚合添加剂的液体反应介质中使用含锂聚合引发剂使环氧烷聚合的方法。 线性和星形聚合物可以通过实践本发明的方法制备。
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2.发明授权Synthetic polymers with highly-functionalized liquid-rubber chain-end moieties 有权具有高官能化液体 - 橡胶链端部分的合成聚合物
公开(公告)号：US07235615B2
公开(公告)日：2007-06-26
申请号：US10782432
申请日：2004-02-18
Applicant: Roderic P. Quirk , Jin-Ping Zhou
Inventor： Roderic P. Quirk , Jin-Ping Zhou
CPC classification number: C08F297/04 , C08C19/30 , C08C19/44 , C08F8/00 , C08F297/02 , C08F12/08
Abstract: A method is provided for synthesizing a polymer that has highly-functionalized chain-end moieties. The method functionalizes liquid rubber to terminate a metallic or organometallic initiated living polymer. After the living polymer has been terminated with the functionalized liquid rubber, the functionalities on the residue of the liquid rubber are preferably modified to yield more advantageous functionalities.
Abstract translation: 提供了一种合成具有高度官能化的链端部分的聚合物的方法。 该方法使液体橡胶功能化以终止金属或有机金属引发的活性聚合物。 活性聚合物用功能化液体橡胶终止后，液态橡胶残余物的功能性被优选地改性以产生更有利的功能。
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公开(公告)号：US5798418A
公开(公告)日：1998-08-25
申请号：US683487
申请日：1996-07-18
Applicant: Roderic P. Quirk
Inventor： Roderic P. Quirk
IPC: C08C19/44 , C08F4/46 , C08F4/72 , C08F12/06 , C08F36/04 , C08F297/04 , C08G81/02 , C08G83/00 , C08F6/00
CPC classification number: C08G83/00 , C08C19/44 , C08F12/06 , C08F297/044 , C08F36/04 , C08F4/461 , C08F4/72 , C08G81/022
Abstract: The present invention provides novel, multi-arm or star-shaped polymers having mixed protected functional and non-functional ends, their optionally hydrogenated analogues, and the polymers produced by removal of the protecting groups. The invention also provides a process for the preparation of novel multi-arm or star-shaped polymers having branched-end functionality on some, but not all, of the branches. The multi-arm or star polymers of this invention are produced from more than one type of initiator, i.e., from both functional and non-functional initiators which, by design, incorporates both desired physical properties associated with multi-arm or star polymers with non-functional branch-ends and the versatility of functional branch end multi-arm or star polymers.
Abstract translation: 本发明提供具有混合保护的官能和非官能末端的新型多臂或星形聚合物，它们任选氢化的类似物，以及通过除去保护基产生的聚合物。 本发明还提供了一种制备新颖的多臂或星形聚合物的方法，其在一些但不是全部的分支上具有支链官能团。 本发明的多臂或星形聚合物由多于一种类型的引发剂生产，即从功能性和非功能性引发剂两者产生，其通过设计将包含与多臂或星形聚合物相关的所需物理性能与非 - 功能分支端和功能性分支端多臂或星形聚合物的多功能性。
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4.发明授权Hydrogenated alkenyl aromatic-diene copolymers containing comonomers having silyl hydride units and their functionalized analogs 有权含有具有甲硅烷基氢化物单元及其官能化类似物的共聚单体的氢化烯基芳族 - 二烯共聚物
公开(公告)号：US09238765B2
公开(公告)日：2016-01-19
申请号：US14380932
申请日：2012-02-29
Applicant: Sergio Corona Galvan , Diana Martinez Wichtel , Luis Serrano Aviles , Montserrat Fernandez Munoz , Roderic P. Quirk , Vijay Chavan , Jonathan Janoski
Inventor： Sergio Corona Galvan , Diana Martinez Wichtel , Luis Serrano Aviles , Montserrat Fernandez Munoz , Roderic P. Quirk , Vijay Chavan , Jonathan Janoski
IPC: C08L19/02 , C09J153/00 , C08C19/02 , C08C19/25 , C08C19/44 , C08F293/00 , C08F297/04 , C09D153/00
CPC classification number: C09J153/005 , C08C19/02 , C08C19/25 , C08C19/44 , C08F293/005 , C08F297/04 , C09D153/005
Abstract: The present invention relates primarily to polymers comprising at least one alkenyl aromatic monomer, at least one conjugated diene monomer, and at least one monomer containing silyl hydride moieties, characterized in that said polymers are hydrogenated and preferably functionalized by hydrosilylation reactions between the silyl hydride groups on the polymer chain and the multiple bonds of any alkene or alkyne compound. Besides the described products, this invention comprises their synthesis processes and their uses, especially as thermofusible adhesives, in plastics impact modification, and in chain-extension reactions to obtain new materials, among others.
Abstract translation: 本发明主要涉及包含至少一种烯基芳族单体，至少一种共轭二烯单体和至少一种含甲硅烷基氢化物部分的单体的聚合物，其特征在于所述聚合物被氢化并优选通过甲硅烷基氢化物基团之间的氢化硅烷化反应 在聚合物链和任何烯烃或炔化合物的多重键上。 除了所描述的产品外，本发明包括其合成方法及其用途，特别是作为热熔粘合剂，在塑料冲击改性中，以及在延伸反应中获得新材料等。
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公开(公告)号：US06703446B2
公开(公告)日：2004-03-09
申请号：US10176816
申请日：2002-06-21
Applicant: James A. Schwindeman , Robert J. Letchford , Conrad W. Kamienski , Roderic P. Quirk
Inventor： James A. Schwindeman , Robert J. Letchford , Conrad W. Kamienski , Roderic P. Quirk
IPC: C08F29704
CPC classification number: C08F36/04 , C08C19/44 , C08F4/46 , C08F4/48 , C08F4/72 , C08F8/34 , C08F12/04 , C08F2810/40 , C08F112/08
Abstract: Hetero-telechelic polymers having the formula: FG—(Q)d—Z—J—[A(R1R2R3)]x (I) wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R1R2R3)]x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R1, R2, and R3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and cycloalkyl and substituted cycloalkyl containing 5 to 12 carbon atoms; and x is dependent on the valence of J and varies from one when J is oxygen or sulfur to two when J is nitrogen, with the proviso J and FG are not the same, and processes for making the same.
Abstract translation: 具有下式的异烟酰基聚合物：其中FG是被保护或未被保护的官能团; Q是通过引入选自共轭二烯烃，烯基取代的芳族烃及其混合物的化合物衍生的饱和或不饱和烃基; d为10〜200的整数; Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; J是氧，硫或氮; [A（R 1 R 2 R 3）] x是保护基，其中A是选自元素周期表Ⅳa族的元素; R 1，R 2和R 3各自独立地选自氢，烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的取代烷基，含低级烷基的低级烷基 烷基，低级烷硫基和低级二烷基氨基，环烷基和取代环烷基，含有5至12个碳原子; 并且x取决于J的化合价，并且当J是氮时，当J是氧或硫时，J的值是不同的，条件是J和FG不相同，并且其制备方法。
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公开(公告)号：US20130144083A1
公开(公告)日：2013-06-06
申请号：US13808406
申请日：2011-07-06
Applicant: Xuehui Dong , Wenbin Zhang , Stephen Z. D. Cheng , Roderic P. Quirk
Inventor： Xuehui Dong , Wenbin Zhang , Stephen Z. D. Cheng , Roderic P. Quirk
IPC: C01B31/02
CPC classification number: C01B31/0213 , C01B32/152 , C07C17/16 , C07C23/18 , C07C29/42 , C07C29/68 , C07C35/44 , C07C69/606 , C07C69/63 , C07C2604/00 , C07C35/46
Abstract: The preparation of novel fullerynes which are fullerenes (e.g. C60, C70, C80, etc.) that contain one or more alkyne functionalities and may contain additional functional groups such as hydroxyls, halogens, esters, haloesters, phenyl, oligo(ethylene glycol)s, perfluorinated alkyl chains, and the like. Two desired preparation routes are disclosed. The first one is the Fischer esterification in desired solvents using a special designed reactor in contrast to the heretofore initial Steglich reaction that results in side reactions and low yields. The second one uses acetylide Grignard reagents that have reduced nucleophilicity and higher stability in contrast to the use of heretofore initial lithium organyls or other Grignard reagents that would add to C60 with possible multi-additions in an uncontrollable manner.
Abstract translation: 含有一个或多个炔官能团并且可以含有另外的官能团例如羟基，卤素，酯，卤代酯，苯基，低聚（乙二醇）的富勒烯（例如C60，C70，C80等）的新型富勒烯的制备 ，全氟化烷基链等。 公开了两种期望的制备途径。 第一种是在所需溶剂中使用特殊设计的反应器进行费歇尔酯化，与迄今为止初始的Steglich反应相反，其导致副反应和低产率。 第二种使用与使用迄今初始的锂有机物或其他格利雅试剂相比，其具有降低的亲核性和更高的稳定性的乙炔化物格氏试剂，其将以不可控的方式以可能的多次添加添加到C60。
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7.发明授权Functionalized initiators for anionic polymerization, protected functionalized polymers, deprotected analogues thereof, and methods of making the same 失效用于阴离子聚合的官能化引发剂，保护的官能化聚合物，其去保护的类似物及其制备方法
公开(公告)号：US06720391B2
公开(公告)日：2004-04-13
申请号：US10062331
申请日：2002-02-01
Applicant: James Anthony Schwindeman , Robert J. Letchford , Eric John Granger , Roderic P. Quirk
IPC: C08F818
Abstract: The present invention provides functionalized electrophiles, their analogous initiators, and processes for preparing these compounds. The present invention also relates to homotelechelic, heterotelechelic, and radial functional polydiene polymers, polyarylene polymers and polydiene/polyarylene copolymers, their optionally hydrogenated analogues, their optionally deprotected analogues, and processes for preparing these functionalized polymers.
Abstract translation: 本发明提供功能化的亲电子试剂，它们的类似的引发剂，以及制备这些化合物的方法。 本发明还涉及同基亚类，异触耳和径向功能聚二烯聚合物，聚亚芳基聚合物和聚二烯/聚亚芳基共聚物，它们任选氢化的类似物，它们任选脱保护的类似物，以及制备这些官能化聚合物的方法。
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公开(公告)号：US06350723B1
公开(公告)日：2002-02-26
申请号：US09450247
申请日：1999-11-29
Applicant: Munmaya K. Mishra , Roderic P. Quirk , Robert S. Porzio
Inventor： Munmaya K. Mishra , Roderic P. Quirk , Robert S. Porzio
IPC: C10M14514
CPC classification number: C10M145/14 , C10M143/12 , C10M2205/06 , C10M2209/084 , C10M2221/02
Abstract: Block copolymers having a molecular weight distribution of between 1.0 and 5.0 comprising at least one block of polymerized alkyl methacrylate monomer(s), wherein from 50 to 100% by weight of the monomers for forming the alkyl methacrylate block are C12-C30 alkyl methacrylates, and a block of a polymerized conjugated alkadiene. The block copolymers of the present invention are useful as viscosity index improvers in lubricating oil compositions as well as compatibilizers for compositions containing both polymethacrylates and olefin copolymers or hydrogenated block polymers.
Abstract translation: 分子量分布为1.0至5.0的嵌段共聚物包含至少一个聚合的甲基丙烯酸烷基酯单体的嵌段，其中50-100重量％的用于形成甲基丙烯酸烷基酯嵌段的单体是甲基丙烯酸C12-C30烷基酯， 和聚合的共轭二烯嵌段。 本发明的嵌段共聚物可用作润滑油组合物中的粘度指数改进剂以及含有聚甲基丙烯酸酯和烯烃共聚物或氢化嵌段聚合物的组合物的增容剂。
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公开(公告)号：US6160054A
公开(公告)日：2000-12-12
申请号：US687111
申请日：1996-07-18
Applicant: James A. Schwindeman , Robert J. Letchford , Conrad W. Kamienski , Roderic P. Quirk
Inventor： James A. Schwindeman , Robert J. Letchford , Conrad W. Kamienski , Roderic P. Quirk
IPC: C08C19/44 , C08F4/46 , C08F4/48 , C08F4/72 , C08F8/00 , C08F12/04 , C08F36/04 , C08F297/04 , C08F8/30 , C08F8/46
CPC classification number: C08F36/04 , C08C19/44 , C08F4/46 , C08F4/48 , C08F4/72 , C08F8/34 , C08F12/04 , C08F2810/40 , C08F112/08
Abstract: Hetero-telechelic polymers having the formula:FG--(Q).sub.d --Z--J--[A(R.sup.1 R.sup.2 R.sup.3)].sub.x (I)wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R.sup.1 R.sup.2 R.sup.3)].sub.x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R.sup.1, R.sup.2, and R.sup.3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and cycloalkyl and substituted cycloalkyl containing 5 to 12 carbon atoms; and x is dependent on the valence of J and varies from one when J is oxygen or sulfur to two when J is nitrogen, with the proviso J and FG are not the same, and processes for making the same.
Abstract translation: 具有式FG-（Q）d-Z-J- [A（R 1 R 2 R 3）] x（I）的异烟酰基聚合物，其中FG是受保护或未被保护的官能团; Q是通过引入选自共轭二烯烃，烯基取代的芳族烃及其混合物的化合物衍生的饱和或不饱和烃基; d为10〜200的整数; Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; J是氧，硫或氮; [A（R1R2R3）] x为保护基，其中A为选自元素周期表第Ⅳa族的元素; R 1，R 2和R 3各自独立地选自氢，烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的取代烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的芳基或取代芳基 和含有5至12个碳原子的环烷基和取代的环烷基; 并且x取决于J的化合价，并且当J是氮时，当J是氧或硫时，J的值是不同的，条件是J和FG不相同，并且其制备方法。
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公开(公告)号：US5780551A
公开(公告)日：1998-07-14
申请号：US657084
申请日：1996-06-03
Applicant: John F. Engel , James A. Schwindeman , Roderic P. Quirk , Conrad W. Kamienski
Inventor： John F. Engel , James A. Schwindeman , Roderic P. Quirk , Conrad W. Kamienski
CPC classification number: C08G81/022 , C08C19/44 , C08F12/06 , C08F297/044 , C08F36/04 , C08F4/461 , C08G64/18
Abstract: This invention concerns novel, unsymmetrically protected, telechelically functionalized linear and star or multi-arm polymers, their optionally hydrogenated analogues, the polymers produced by selective removal of the protecting groups, the segmented block polymers produced by further reaction of these selectively deprotected polymers with selected comonomers, and the processes to prepare these polymers.
Abstract translation: 本发明涉及新颖的，不对称保护的，电视功能化的线性和星形或多臂聚合物，它们任选氢化的类似物，通过选择性去除保护基产生的聚合物，通过这些选择性去保护的聚合物与所选择的进一步反应产生的分段嵌段聚合物 共聚单体，以及制备这些聚合物的方法。
