公开(公告)号：US09724679B2

公开(公告)日：2017-08-08

申请号：US14936005

申请日：2015-11-09

Applicant: SHELL OIL COMPANY

Inventor： Alexei Grigorievich Gabrielov ,  Ed Ganja ,  Salvatore Philip Torrisi

IPC: B01J27/19 ,  B01J35/10 ,  B01J37/02 ,  C10G45/08 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J35/00 ,  B01J37/18 ,  B01J37/20 ,  C10G49/04 ,  B01J35/02 ,  B01J37/04

CPC classification number: B01J27/19 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J23/8885 ,  B01J35/002 ,  B01J35/026 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/0236 ,  B01J37/04 ,  B01J37/18 ,  B01J37/20 ,  C10G45/08 ,  C10G49/04

Abstract: A hydroprocessing catalyst composition that comprises a shaped support that is formed from a mixture of inorganic oxide powder and catalyst fines and wherein the shaped support has incorporated therein at least one metal component, a chelating agent and a polar additive. The hydroprocessing catalyst composition is prepared by incorporating into the shaped support a metal component, a chelating agent and a polar additive. The hydroprocessing catalyst composition has particular application in the catalytic hydroprocessing of petroleum derived feedstocks.

公开(公告)号：US10329497B2

公开(公告)日：2019-06-25

申请号：US15164488

申请日：2016-05-25

Applicant: SHELL OIL COMPANY

Inventor： Alexei Grigorievich Gabrielov ,  Ed Ganja ,  Salvatore Philip Torrisi

IPC: B01J31/26 ,  B01J31/38 ,  B01J35/10 ,  C10G45/08 ,  C10G45/12 ,  B01J37/20 ,  B01J23/85 ,  B01J37/02 ,  B01J27/188

Abstract: A hydroprocessing catalyst composition that comprises a metal-incorporated support having incorporated therein a metal component and a chelating agent, and, further comprising a polar additive. The catalyst composition is prepared by incorporating in a single step at least one metal component and a chelating agent into a support material to form a metal-incorporated support followed by drying the metal-incorporated support and thereafter incorporating therein a polar additive.

公开(公告)号：US11325108B2

公开(公告)日：2022-05-10

申请号：US14291144

申请日：2014-05-30

Applicant: Shell Oil Company

Inventor： John Anthony Smegal ,  Alexei Grigorievich Gabrielov ,  Ed Ganja ,  Theofiel Meuris

IPC: B01J27/19 ,  B01J31/02 ,  C10G45/08 ,  B01J37/02 ,  B01J35/00 ,  B01J23/85 ,  B01J37/18 ,  B01J37/20 ,  B01J21/04 ,  B01J35/10

Abstract: A composition that comprises a support material having incorporated therein a metal component and impregnated with an additive compound that is selected from the group of heterocyclic, polar compounds of the formula CxHnNyOz; wherein: x is an integer of at least 3; y is either 0, 1, 2, or 3; z is either 0, 1, 2, or 3; and n is the number of hydrogen atoms required to fill the remaining bonds with the carbon atoms of the molecule. The composition includes the support material that is impregnated with the additive compound and is useful in the hydroprocessing of hydrocarbon feedstocks, especially in the denitrogenation and desulfurization of distillate feedstocks to make ultra low sulfur diesel.

公开(公告)号：US09988582B2

公开(公告)日：2018-06-05

申请号：US14684580

申请日：2015-04-13

Applicant: SHELL OIL COMPANY

Inventor： Alexei Grigorievich Gabrielov ,  Ed Ganja ,  Salvatore Philip Torrisi

IPC: B01J23/94 ,  B01J23/96 ,  B01J27/28 ,  B01J27/32 ,  C10G45/04 ,  B01J27/19 ,  B01J37/02 ,  B01J38/02 ,  B01J38/50 ,  B01J38/52 ,  B01J38/62 ,  B01J38/66 ,  C10G49/02 ,  B01J27/24

CPC classification number: C10G45/04 ,  B01J23/94 ,  B01J27/19 ,  B01J27/24 ,  B01J27/285 ,  B01J37/0203 ,  B01J38/02 ,  B01J38/50 ,  B01J38/52 ,  B01J38/62 ,  B01J38/66 ,  C10G49/02 ,  C10G2300/703

Abstract: A regenerated spent hydroprocessing catalyst treated with a chelating agent and having incorporated therein a polar additive.

公开(公告)号：US11154848B2

公开(公告)日：2021-10-26

申请号：US16272501

申请日：2019-02-11

Applicant: SHELL OIL COMPANY

Inventor： Alexei Grigorievich Gabrielov ,  Ed Ganja ,  Salvatore Philip Torrisi

IPC: B01J35/02 ,  B01J23/882 ,  B01J23/883 ,  B01J27/19 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  C10G45/08 ,  B01J31/02 ,  B01J31/04 ,  B01J31/06

Abstract: A hydroprocessing catalyst composition that comprises a chelant treated metal containing support material having incorporated therein a polar additive. The catalyst composition is prepared by incorporating at least one metal component into a support material followed by treating the metal incorporated support with a chelating agent and thereafter incorporating a polar additive into the chelant treated composition.

公开(公告)号：US10099208B2

公开(公告)日：2018-10-16

申请号：US15648802

申请日：2017-07-13

Applicant: SHELL OIL COMPANY

Inventor： Alexei Grigorievich Gabrielov ,  Ed Ganja ,  Salvatore Philip Torrisi

IPC: B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J27/19 ,  B01J35/00 ,  B01J35/02 ,  B01J35/10 ,  B01J37/02 ,  B01J37/04 ,  B01J37/18 ,  B01J37/20 ,  C10G45/08 ,  C10G49/04

Abstract: A hydroprocessing catalyst composition that comprises a shaped support that is formed from a mixture of inorganic oxide powder and catalyst fines and wherein the shaped support has incorporated therein at least one metal component, a chelating agent and a polar additive. The hydroprocessing catalyst composition is prepared by incorporating into the shaped support a metal component, a chelating agent and a polar additive. The hydroprocessing catalyst composition has particular application in the catalytic hydroprocessing of petroleum derived feedstocks.

公开(公告)号：US09920259B2

公开(公告)日：2018-03-20

申请号：US14816531

申请日：2015-08-03

Applicant: SHELL OIL COMPANY

Inventor： Alexei Grigorievich Gabrielov ,  Ed Ganja ,  Theofiel Meuris ,  Maxim Vasilievich Ovchinnikov

IPC: C10G45/08 ,  C10G45/06 ,  B01J31/02 ,  B01J21/04 ,  B01J23/75 ,  B01J23/755 ,  B01J23/88 ,  B01J23/882 ,  B01J23/883 ,  B01J27/19 ,  B01J35/02 ,  B01J35/10 ,  B01J37/02

CPC classification number: C10G45/08 ,  B01J21/04 ,  B01J23/75 ,  B01J23/755 ,  B01J23/88 ,  B01J23/882 ,  B01J23/883 ,  B01J27/19 ,  B01J31/02 ,  B01J31/0201 ,  B01J31/0235 ,  B01J35/026 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1066 ,  B01J37/0203 ,  B01J37/0207 ,  C10G45/06 ,  C10G2300/1044 ,  C10G2300/1051 ,  C10G2300/1055 ,  C10G2300/1059 ,  C10G2300/1088 ,  C10G2300/301

Abstract: A composition having a substantial or material absence of or no phosphorous and comprising a support material, a metal compound and either a hydrocarbon oil or a polar additive or a combination of both a hydrocarbon oil and polar additive. The polar additive has particularly defined properties including having a dipole moment of at least 0.45. The composition is useful in the hydroprocessing of hydrocarbon feedstocks, and it is especially useful in the hydrotreating of vacuum gas oils and petroleum resid feedstocks.