摘要:
A separator for a battery includes a porous polymer film having a first surface and a second surface opposite to the first surface, wherein the first surface has openings distributed thereon communicating with pores of the porous polymer film, and the ratio of the total area of the openings to the area of the first surface is 89% or more and 96% or less. The diameters of the openings may be within the range of 0.8 μm or more and 40 μm or less. A region with a predetermined thickness including at least the first surface of the porous polymer film preferably includes at least one selected from the group consisting of polypropylene, and a copolymer of propylene and another copolymerizable monomer.
摘要:
A separator for a battery includes a porous polymer film having a first surface and a second surface opposite to the first surface, wherein the first surface has openings distributed thereon communicating with pores of the porous polymer film, and the ratio of the total area of the openings to the area of the first surface is 89% or more and 96% or less. The diameters of the openings may be within the range of 0.8 μm or more and 40 μm or less. A region with a predetermined thickness including at least the first surface of the porous polymer film preferably includes at least one selected from the group consisting of polypropylene, and a copolymer of propylene and another copolymerizable monomer.
摘要:
Disclosed is a non-aqueous electrolyte secondary battery including: an electrode assembly including a positive electrode including a belt-like positive electrode current collector and a positive electrode active material layer adhering to a surface of the positive electrode current collector, a negative electrode including a belt-like negative electrode current collector and a negative electrode active material layer adhering to a surface of the negative electrode current collector, and a separator for insulating the positive electrode from the negative electrode, the positive electrode, the negative electrode, and the separator being spirally wound together; and a non-aqueous electrolyte. The separator includes a heat resistant porous film including a heat resistant resin, a first polyolefin porous film covering entirely a surface of the heat resistant porous film on the positive electrode side, and a second polyolefin porous film covering entirely a surface of the heat resistant porous film on the negative electrode side. The heat resistant resin has a melting point or a heat deflection temperature higher than those of polyolefins included in the first and second polyolefin porous films. The heat resistant porous film has a thickness of 1 to 16 μm, each of the first and second polyolefin porous films has a thickness of 2 to 17 μm, and the separator has a thickness of 5 to 35 μm.
摘要:
Disclosed is a separator for a non-aqueous electrolyte secondary battery, the separator including a biaxially-oriented polyolefin porous film including extended-chain crystals and folded-chain crystals, wherein the extended-chain crystals and the folded-chain crystals form a shish-kebab structure. The average distance between the extended-chain crystals adjacent to each other is 1.5 μm or more and less than 11 μm, and the average distance between the folded-chain crystals adjacent to each other is 0.3 μm or more and less than 0.9 μm. A heat resistant porous film may be laminated on the polyolefin porous film. The heat resistant porous film includes a resin having heat resistance or a melting point higher than a melting point of the polyolefin porous film.
摘要:
Disclosed is a separator for a non-aqueous electrolyte secondary battery, the separator including a biaxially-oriented polyolefin porous film including extended-chain crystals and folded-chain crystals, wherein the extended-chain crystals and the folded-chain crystals form a shish-kebab structure. The average distance between the extended-chain crystals adjacent to each other is 1.5 μm or more and less than 11 μm, and the average distance between the folded-chain crystals adjacent to each other is 0.3 μm or more and less than 0.9 μm. A heat resistant porous film may be laminated on the polyolefin porous film. The heat resistant porous film includes a resin having heat resistance or a melting point higher than a melting point of the polyolefin porous film.
摘要:
A separator 4 for a lithium secondary battery includes a porous film 12 including a polyolefin layer 16 and a lubricant layer 14 disposed on a surface of the porous film 12. The lubricant layer 14 includes a particulate substance 22 and has a three-dimensional surface roughness of 0.15 to 1.45 μm. The particulate substance 22 can adhere to the surface of the porous film 12 by electrostatic attraction. The porous film 12 can further include a heat-resistant porous layer 18 between the polyolefin layer 16 and the lubricant layer 14. The separator 4 allows a winding core for the lithium secondary battery to be pulled out smoothly.
摘要:
A solid electrolyte of the present invention is represented by a general formula: LiaPbMcOdNe, where M is at least one element selected from the group consisting of Si, B, Ge, Al, C, Ga and S, and a, b, c, d and e respectively satisfy a=0.62 to 4.98, b=0.01 to 0.99, c=0.01 to 0.99, d=1.070 to 3.985, e=0.01 to 0.50, and b+c=1.0. The solid electrolyte hardly deteriorates in a wet atmosphere.
摘要:
In order to improve a storage stability at high temperatures of a lithium polymer battery including: a positive electrode comprising a lithium-containing complex oxide; a negative electrode comprising a material capable of absorbing and desorbing a lithium ion; and a separator comprising a liquid organic electrolyte and a host polymer retaining the liquid organic electrolyte, the separator is rendered homogeneous and excellent in the affinity with the organic electrolyte by using a crosslinked copolymer having a main-chain comprising a vinylidene fluoride unit and a side-chain comprising an alkylene oxide unit and at least one of an acrylate unit and methacrylate unit as the host polymer.
摘要:
The present invention relates to a solid electrolyte including Li, O, P and a transition metal element. In the solid electrolyte, because the transition metal element T is reduced prior to phosphorus atoms, it is possible to prevent the valence of phosphorus atoms from decreasing. Thereby, the decomposition of the solid electrolyte resulting from the decrease of valence of phosphorus atoms is prevented, and therefore high ion conductivity is retained even in a wet atmosphere.
摘要:
To provide an electrochemical device with a layer structure causing no deterioration of characteristics of materials, in the method for preparing an electrochemical device comprising a first current collector, a first electrode active material layer, a solid electrolyte layer, a second electrode active material layer and a second current collector, all of which are accumulated, the first electrode active material layer, the second electrode active material layer or the solid electrolyte layer is formed by supplying atoms, ions or clusters constituting the first electrode active material layer, the second electrode active material layer or the solid electrolyte layer to the substrate, while irradiating electrons or electromagnetic waves with energy prescribed according to the composition of the first electrode active material layer, the second electrode active material layer or the solid electrolyte layer.