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公开(公告)号：US5583244A
公开(公告)日：1996-12-10
申请号：US551807
申请日：1995-11-07
申请人： Satoshi Uchida , Akira Yamamoto , Ikuo Fukui , Mikio Endo , Hiroshi Umezawa , Shigehiro Nagura , Tohru Kubota
发明人： Satoshi Uchida , Akira Yamamoto , Ikuo Fukui , Mikio Endo , Hiroshi Umezawa , Shigehiro Nagura , Tohru Kubota
CPC分类号： C08B37/0018 , C08G77/42
摘要： Disclosed is a novel organosilicon-containing derivative of pullulan of which an organopolysiloxane moiety having a silethylene linkage is bonded to the glucose residue of pullulan through a urethane linkage. Different from conventional organopolysiloxane-modified pullulans, the inventive derivative is stable against attack of water and exhibits unique properties as a combination of the properties inherent in pullulan and in silicones. The organosilicon-containing pullulan of the invention can be easily prepared under mild reaction conditions by reacting an isocyanato group-containing organopolysiloxane with the glucosic hydroxy groups of pullulan.
摘要翻译： 公开了一种新型含有有机硅的支链淀粉衍生物，其中具有亚硫键的有机聚硅氧烷部分通过氨基甲酸酯键与支链淀粉的葡萄糖残基结合。 与传统的有机聚硅氧烷改性的起始链不同，本发明衍生物对水的侵蚀是稳定的，并且表现出作为支链淀粉和硅氧烷中固有的性质的组合的独特性质。 本发明的含有机硅的支链淀粉可以在温和的反应条件下通过含异氰酸酯基的有机聚硅氧烷与支链淀粉的葡糖羟基反应而容易地制备。
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公开(公告)号：US4728431A
公开(公告)日：1988-03-01
申请号：US771985
申请日：1985-09-03
CPC分类号： B01D61/362 , B01D63/02 , B01D71/44
摘要： The efficiency of the pervaporation method for the separation or enrichment of liquids in mixture, e.g. water and ethyl alcohol, can be greatly improved when the partitioning membrane is made of a polymeric composition comprising a specific organosilyl-substituted polyenic polymer composed of the monomeric moieties represented by the general formula ##STR1## in which R.sup.1 is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms and the groups denoted by R are each independently a hydrogen atom, a monovalent hydrocarbon group having 1 to 8 carbon atoms or a silicon-containing organic group such as those represented by the general formula --CH.sub.2 --SiMe.sub.2 R.sup.2, Me being a methyl group and R.sup.2 being a lower alkyl group having 1 to 4 carbon atoms. The performance and durability of the membrane can be further improved when the polymeric composition is a polymer blend of the above described polyenic polymer and a poly(trimethyl vinyl silane).
摘要翻译： 用于分离或富集混合物中的液体的渗透蒸发方法的效率，例如 当分隔膜由包含由通式“IMAGE”表示的单体部分组成的特定有机甲硅烷基取代的多烯聚合物的聚合物组合物中可以大大改善，其中R 1是氢原子或烷基 具有1至4个碳原子的基团和由R表示的基团各自独立地为氢原子，具有1至8个碳原子的一价烃基或含硅的有机基团，例如由通式-CH 2 -SiMe 2 R 2表示的基团， Me为甲基，R2为碳原子数1〜4的低级烷基。 当聚合物组合物是上述多元聚合物与聚（三甲基乙烯基硅烷）的聚合物共混物时，可以进一步改善膜的性能和耐久性。
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3.发明授权
公开(公告)号：US4734281A
公开(公告)日：1988-03-29
申请号：US9458
申请日：1987-02-02
申请人： Akira Yamamoto , Kinya Ogawa , Shigehiro Nagura
发明人： Akira Yamamoto , Kinya Ogawa , Shigehiro Nagura
摘要： An efficient cost- and labor-saving method is proposed for controlling the population of two kinds or more of different species of insectan pests in a field by means of distributing dispensers of sex pheromone compounds for the respective species of the insects when one of the sex pheromone compounds is an unsaturated C.sub.10 to C.sub.12 alcohol and the other is an unsaturated C.sub.14 to C.sub.20 acetate or aldehyde. When these two classes of the compounds are mixed in such a proportion that the overall solubility paramater .delta. of the mixture is 9.1 to 9.7 and the mixture is contained in a dispenser body made of polyethylene or a copolymer mainly composed of ethylene moiety, the two compounds can be concurrently emitted from the dispenser in the form of vapor each at a controlled rate over a desired length of time.
摘要翻译： 提出了一种有效的节省成本和节省劳动力的方法，用于通过为性别信息素化合物的分配器为各种昆虫分配一种性别，以控制两种或更多种不同种类的昆虫害虫的种群 信息素化合物是不饱和的C 10至C 12醇，另一种是不饱和C 14 -C 20乙酸酯或醛。 当这两种化合物的混合比例使得混合物的总体溶解度参数为9.1至9.7，并且该混合物包含在由聚乙烯或主要由乙烯部分组成的共聚物制成的分配器主体中时，两种化合物 可以以分别以蒸汽的形式从分配器以所需时间的受控速率同时发射。
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公开(公告)号：US4649185A
公开(公告)日：1987-03-10
申请号：US798757
申请日：1985-11-15
摘要： The contact lens of the invention is shaped of a poly(trimethylvinylsilane) resin having an average molecular weight of at least 200,000 or a copolymer based thereon. The contact lens has a very high oxygen permeability comparable to conventional transparent silicone rubbers so as to ensure a long time of continued wearing of the lens on the cornea with no adverse physiological influences and the material still has much better mechanical workability for precision shaping into a lens form than the transparent silicone rubbers.
摘要翻译： 本发明的隐形眼镜成型为平均分子量至少为200,000的聚（三甲基乙烯基硅烷）树脂或基于其的共聚物。 隐形眼镜具有与传统的透明硅橡胶相当的非常高的氧透过率，以便确保镜片在角膜上持续磨损的长时间，没有不利的生理影响，并且该材料仍然具有更好的机械加工性，用于精确成形为 透镜形式比透明硅橡胶。
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公开(公告)号：US4923119A
公开(公告)日：1990-05-08
申请号：US351200
申请日：1989-05-12
IPC分类号： A01M1/02 , A01M1/20 , A01N25/18 , A01N27/00 , A01N35/02 , A01N35/04 , A01N35/06 , A01N37/02 , A01N37/06 , A01N63/00 , B32B27/08
CPC分类号： B32B27/08 , A01M1/02 , A01M1/2044 , A01N25/18
摘要： A bag-like dispenser is proposed which contains a sex pheromone compound of insects and is used for sustainedly releasing the pheromone compound at a uniform emission rate over a long period of time so as to exhibit effectiveness for the population control of pests by distributing a number of the dispensers over fields. The bag-like dispenser body is formed of a specific polymeric laminate film having a thickness of 20-200 .mu.m and composed of at least two layers or, preferably, of three layers, in which one of the layers is a film of a polymer or copolymer of vinylidene chloride having a thickness of 4-20 .mu.m as the intermediate layer of the three-layered laminate and the other layer or each of the other layers is a film of a specific polymer having a specified thickness, such as a film of a polyolefin, copolymer of ethylene and vinyl acetate, poly(vinyl chloride), copolymer of vinyl chloride and vinyl acetate and the like.
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公开(公告)号：US4761436A
公开(公告)日：1988-08-02
申请号：US921107
申请日：1986-10-21
申请人： Yoshiyuki Kohno , Kenichi Tomita , Minoru Takamizawa , Tetsuya Mayuzumi , Shigehiro Nagura , Akira Yamamoto
发明人： Yoshiyuki Kohno , Kenichi Tomita , Minoru Takamizawa , Tetsuya Mayuzumi , Shigehiro Nagura , Akira Yamamoto
IPC分类号： C08F275/00 , G02B1/04 , C08F289/00 , G02C7/04
CPC分类号： C08F275/00 , G02B1/043
摘要： A contact lens comprising a lens substrate in shape of a lens which comprises a triorganovinylsilane based polymer, said lens substrate having a hydrophilic polymeric chain grafted onto the surface thereof. This contact lens is not only excellent in oxygen permeability, mechanical strength, dimensional stability, vision correcting ability, staining resistance and handleability, but also good in affinity with eyes due to good hydrophilic property possessed by the surface, which can be worn continuously for a long time.
摘要翻译： 一种隐形眼镜，包括透镜形状的透镜基片，其包含三有机基乙烯基硅烷基聚合物，所述透镜基底具有接枝到其表面上的亲水性聚合物链。 该隐形眼镜不仅具有优异的透氧性，机械强度，尺寸稳定性，视力矫正能力，抗污染性和可操作性，而且由于表面具有良好的亲水性而对眼睛的亲和性也良好，可以连续佩戴 长时间。
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公开(公告)号：US4567245A
公开(公告)日：1986-01-28
申请号：US681861
申请日：1984-12-14
IPC分类号： C08F38/00 , B01D53/22 , C08F238/00 , C08F238/02 , C08F230/08
CPC分类号： C08F238/00
摘要： The invention provides a novel substituted polyacetylene copolymer having an outstandingly large oxygen permeation coefficient of 6.times.10.sup.-8 cm.sup.3 (STP).multidot.cm/cm.sup.2 .multidot.sec.multidot.cmHg or larger and a separation factor between oxygen and nitrogen of 2.0 or larger along with a high tensile strength of 200 kg/cm.sup.2 or larger in the form of a film and useful as a gas permeation element in the separation or enrichment of oxygen from or in air. The copolymer is obtained by the copolymerization of 1-trimethylsilyl-1-propyne and 1-(1',1',3',3'-tetramethyl-1',3'-disilabutyl)-1-propyne in a molar ratio of 30:70 to 95:5 and the copolymer should preferably have a number-average molecular weight of at least 1.times.10.sup.4.
摘要翻译： 本发明提供了一种新颖的取代聚乙炔共聚物，具有优异的氧渗透系数为6×10 -8 cm 3（STP）×cm / cm 2×sec×cmHg以上，氧与氮之间的分离系数为2.0以上，高拉伸强度为200kg / cm2或更大，并且可用作气体渗透元件，用于从空气中分离或富集氧气。 该共聚物通过1-甲基甲硅烷基-1-丙炔与1-（1'，1'，3'，3'-四甲基-1'，3'-二丁基丁-1-炔）的摩尔比 30:70〜95:5，共聚物的数均分子量优选为1×10 4以上。
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公开(公告)号：US4834745A
公开(公告)日：1989-05-30
申请号：US29950
申请日：1987-03-25
申请人： Kinya Ogawa , Akira Yamamoto , Noboru Aiba , Shigehiro Nagura
发明人： Kinya Ogawa , Akira Yamamoto , Noboru Aiba , Shigehiro Nagura
CPC分类号： A01N25/18
摘要： The invention provides a dispenser form for substainedly releasing vapor of a sex pheromone compound of pest insects with an object to control the population of the insects. The invention dispenser is characterized by the features that: the capacity thereof is sufficiently large to contain at least 100 mg of the pheromone; the barrier wall thereof through which the pheromone permeates to be released from the outer surface is made of a polymeric material swellable with the pheromone in an equilibrium swelling of 2-6% by weight at 20.degree. C.; and the outer surface area S thereof given in mm.sup.2 is sufficient to give a ratio S/W, W being the amount of the pheromone contained therein given in mg, in the range from 4 to 11. The rate of pheromone emission from the dispenser is relatively constant at 0.6 mg/day or larger over a long period of time of, for example, 3 months or longer.
摘要翻译： 本发明提供了一种分配器形式，用于以害虫的性信息素化合物的特征性释放蒸气为目的，以控制昆虫的群体。 本发明分配器的特征在于：其容量足够大以容纳至少100mg信息素; 信息素透过其从外表面释放的阻挡壁由在20℃下以2-6重量％的平衡溶胀的信息素溶胀的聚合物材料制成。 其以mm2表示的外表面积S足以使其中所含的信息素的量的比例S / W，以mg给出，其中以mg计，在4至11的范围内。来自分配器的信息素发射率为 相对恒定，在0.6mg /天或更长的时间内，例如3个月或更长时间。
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公开(公告)号：US4689267A
公开(公告)日：1987-08-25
申请号：US759308
申请日：1985-07-26
CPC分类号： B01D69/08 , B01D69/12 , B01D71/44 , Y10T428/2935 , Y10T428/2962 , Y10T428/2965 , Y10T428/2967 , Y10T428/2969 , Y10T428/2975
摘要： This invention provides a composite hollow fiber comprising a porous hollow fiber substrate and a coating layer formed on at least one of the outer surface and the inner surface of said substrate. The coating layer comprises a polymer having at least one of the structural units represented by the formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom or a lower alkyl group; R.sup.2, R.sup.3 and R.sup.4, which may be identical or different, represent a hydrogen atom, a monovalent hydrocarbon group having 1 to 8 carbon atoms or a monovalent silicon-containing organic group.This composite hollow fiber is excellent in gas permeability and gas separation performance and has high heat resistance, humidity resistance and mechanical strength.
摘要翻译： 本发明提供了一种复合中空纤维，其包括多孔中空纤维基材和形成在所述基材的外表面和内表面中的至少一个上的涂层。 涂层包含具有式（I）表示的至少一个结构单元的聚合物：其中R 1表示氢原子或低级烷基; R2，R3和R4可以相同或不同，表示氢原子，碳原子数为1〜8的一价烃基或一价含硅有机基团。 该复合中空纤维的气体渗透性和气体分离性能优异，并且具有高耐热性，耐湿性和机械强度。
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公开(公告)号：US20050089796A1
公开(公告)日：2005-04-28
申请号：US10933013
申请日：2004-09-01
申请人： Kenji Funatsu , Tsunehiro Nishi , Shigehiro Nagura
发明人： Kenji Funatsu , Tsunehiro Nishi , Shigehiro Nagura
IPC分类号： C08F220/26 , C08F220/28 , G03C1/76 , G03F7/039 , H01L21/027
CPC分类号： G03F7/0397 , C08F220/26 , Y10S430/111
摘要： Provided is a polymer useful as a base resin of a resist material featuring a high resolution, patterns with less sidewall roughness, practically acceptable etching resistance, and a substantial margin allowed for heat treatment temperature after exposure. The polymer has a weight-average molecular weight of from 1,000 to 50,000 and comprises at least one repeating unit of formula (1) below, at least one repeating unit of formula (2) below and at least one repeating unit of formula (3) below. A resist material comprising the polymer is also provided. In addition, provided is a pattern formation process comprising steps of applying the resist material onto a substrate, heating the film, exposing the heated film through a photomask to high energy radiation or electron beam, heating the exposed film and then developing with a developer.
摘要翻译： 提供了可用作抗蚀剂材料的基础树脂的聚合物，其特征在于具有高分辨率，具有较小侧壁粗糙度的图案，实际上可接受的耐蚀刻性，以及曝光后允许的热处理温度的显着余量。 所述聚合物的重均分子量为1,000至50,000，并且包含至少一种下式（1）的重复单元，至少一个下式的式（2）的重复单元和至少一个式（3）的重复单元， 下面。 还提供了包含聚合物的抗蚀剂材料。 此外，提供了图案形成方法，其包括以下步骤：将抗蚀剂材料施加到基底上，加热膜，将加热的膜通过光掩模曝光到高能量辐射或电子束，加热曝光的膜，然后用显影剂显影。
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