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1.发明授权公开(公告)号：US09546327B2
公开(公告)日：2017-01-17
申请号：US14248391
申请日：2014-04-09
Applicant: SHELL OIL COMPANY
Inventor： Lawrence Stephen Kraus , John Anthony Smegal , Karl Marvin Krueger
IPC: C10G45/08
CPC classification number: C10G45/08 , C10G2300/202 , C10G2300/301
Abstract: A process and catalyst that provides for the upgrading of a high endpoint gas oil feedstock that contains significant concentrations of organic sulfur compound and organic nitrogen compounds. Included among the sulfur compounds are the dimethyl-dibenzothiophenes and derivative thereof. The catalyst of the process is an additive impregnated composition or a derivative thereof that further comprises cobalt and molybdenum. The process provides for the upgrading the high endpoint gas oil feedstock by significantly reducing the difficult to remove thiophene and nitrogen compounds and the process does this with a significantly reduced hydrogen consumption relative to processes using comparative catalysts.
Abstract translation: 提供含有显着浓度的有机硫化合物和有机氮化合物的高终点瓦斯油原料升级的方法和催化剂。 硫化合物中包括二甲基 - 二苯并噻吩及其衍生物。 该方法的催化剂是进一步包含钴和钼的添加剂浸渍组合物或其衍生物。 该方法提供了通过显着减少难以除去噻吩和氮化合物来升级高端点瓦斯油原料，并且该方法相对于使用比较催化剂的方法显着降低了氢消耗。
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公开(公告)号：US20140109464A1
公开(公告)日：2014-04-24
申请号：US14045190
申请日：2013-10-03
Applicant: SHELL OIL COMPANY
Inventor： Joseph Broun POWELL , John Anthony Smegal
IPC: C10L1/18
CPC classification number: C10L1/1802 , C10G3/42 , C10G3/50 , Y02E50/343 , Y02P30/20 , Y02T50/678
Abstract: A partially digested biomass solids is converted in a fixed bed catalytic reduction reactor under hydrothermal catalytic condition with a supported metal catalyst having a high void fraction. The catalyst having high void fraction allows high permeability and extends reaction run time.
Abstract translation: 在具有高空隙率的负载金属催化剂的水热催化条件下，在固定床催化还原反应器中转化部分消化的生物质固体。 具有高空隙率的催化剂允许高渗透性并延长反应运行时间。
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公开(公告)号：US11325108B2
公开(公告)日：2022-05-10
申请号：US14291144
申请日：2014-05-30
Applicant: Shell Oil Company
Inventor： John Anthony Smegal , Alexei Grigorievich Gabrielov , Ed Ganja , Theofiel Meuris
IPC: B01J27/19 , B01J31/02 , C10G45/08 , B01J37/02 , B01J35/00 , B01J23/85 , B01J37/18 , B01J37/20 , B01J21/04 , B01J35/10
Abstract: A composition that comprises a support material having incorporated therein a metal component and impregnated with an additive compound that is selected from the group of heterocyclic, polar compounds of the formula CxHnNyOz; wherein: x is an integer of at least 3; y is either 0, 1, 2, or 3; z is either 0, 1, 2, or 3; and n is the number of hydrogen atoms required to fill the remaining bonds with the carbon atoms of the molecule. The composition includes the support material that is impregnated with the additive compound and is useful in the hydroprocessing of hydrocarbon feedstocks, especially in the denitrogenation and desulfurization of distillate feedstocks to make ultra low sulfur diesel.
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公开(公告)号：US10118158B2
公开(公告)日：2018-11-06
申请号：US14254130
申请日：2014-04-16
Applicant: SHELL OIL COMPANY
Inventor： John Anthony Smegal
IPC: B01J23/883 , B01J21/04 , B01J37/08 , B01J23/85 , B01J27/199 , B01J35/00 , B01J35/02 , B01J35/10 , B01J37/00 , B01J37/02 , C10G45/08
Abstract: A method of hydrotreating a heavy hydrocarbon feedstock using a hydrotreating catalyst having specific properties that make it effective in removing nitrogen and sulfur from the feedstock is disclosed. The catalyst is composed of an alumina support particle having a specific pore diameter distribution which is achieved in part, by the use of pseudo-boehmite as the alumina source and specific calcining temperatures. The hydrotreatment catalyst also comprises a Group 6 metal component (e.g., molybdenum) and a Group 10 metal component (e.g., nickel), and optionally, a phosphorus metal component, which are supported by the alumina support particle.
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5.发明授权Hydrothermal hydrocatalytic treatment of biomass using water tolerant catalysts 有权使用耐水催化剂的水热催化处理生物质
公开(公告)号：US09469822B2
公开(公告)日：2016-10-18
申请号：US14133704
申请日：2013-12-19
Applicant: Shell Oil Company
IPC: C07C1/00 , C10L1/18 , B01J21/04 , C10G1/06 , C10G3/00 , B01J37/20 , B01J23/882 , B01J35/10 , B01J37/02 , B01J23/86 , B01J23/88 , B01J35/00 , B01J35/02
CPC classification number: C10L1/1802 , B01J21/04 , B01J23/86 , B01J23/88 , B01J23/882 , B01J35/0046 , B01J35/026 , B01J35/1009 , B01J35/1014 , B01J35/1066 , B01J37/0201 , B01J37/20 , C10G1/065 , C10G3/46 , C10G3/48 , C10G3/50 , C10G2300/1014 , Y02E50/13 , Y02P30/20
Abstract: A method of hydrothermal hydrocatalytic treating biomass is provided. Lignocellulosic biomass solids is provided to a hydrothermal digestion unit in the presence of a digestive solvent, and a supported hydrogenolysis catalyst containing (a) sulfur, (b) Mo or W, and (c) Co, Ni or mixture thereof, incorporated into an alumina support, which support is predominantly alpha alumina; (ii) heating the lignocellulosic biomass solids and digestive solvent in the presence of hydrogen, and supported hydrogenolysis catalyst thereby forming a product solution containing plurality of oxygenated hydrocarbons, said alumina support having a specific surface area of up to about 30 m2/g and said catalyst retaining a crush strength of at least 50% after being subjected to an aqueous phase stability test compared with before the aqueous phase stability test or a crush strength of at least 0.25 kg after being subjected to an aqueous phase stability test.
Abstract translation: 提供了一种水热催化处理生物质的方法。 将木质纤维素生物质固体在消化溶剂存在下提供给水热消解装置，以及负载的氢解催化剂，其包含（a）硫，（b）Mo或W，和（c）Co，Ni或其混合物， 氧化铝载体，其主要是α氧化铝; （ii）在氢气存在下加热木质纤维素生物质固体和消化溶剂，以及负载的氢解催化剂，由此形成含有多个含氧烃的产物溶液，所述氧化铝载体的比表面积高达约30m 2 / g，所述 在进行水相稳定性试验后，与水相稳定性试验相比，在进行水相稳定性试验后，在进行水相稳定性试验后，将至少50％的压碎强度保持在至少0.25kg的压碎强度。
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公开(公告)号：US11027268B2
公开(公告)日：2021-06-08
申请号：US14453871
申请日：2014-08-07
Applicant: SHELL OIL COMPANY
Inventor： William Douglas Gillespie , Alexei Grigorievich Gabrielov , Peter Wolohan , John Anthony Smegal
IPC: B01J31/26 , B01J31/22 , C10G45/12 , C10G49/04 , B01J35/10 , B01J27/051 , B01J23/888 , B01J37/02 , B01J37/18 , B01J37/20 , B01J31/02 , B01J21/04 , B01J37/00
Abstract: A composition and method of making such a composition that has application in the hydroprocessing of hydrocarbon feedstocks. The method comprises selecting an organic additive by the use of a correlation model for predicting catalytic activity as a function of a physical property that is associated with the organic additive and incorporating the organic additive into a support material to provide the additive impregnated composition.
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7.发明授权
公开(公告)号：US09528052B2
公开(公告)日：2016-12-27
申请号：US14281425
申请日：2014-05-19
Applicant: SHELL OIL COMPANY
Inventor： John Anthony Smegal , Aristides Macris
Abstract: A process that provides for the improvement of the properties of a distillate feedstock that has significant concentrations of nitrogen and polyaromatic compounds. The process includes a first reaction zone that uses a base metal catalyst and is operated under high pressure conditions to provide for the hydrodenitrogenation of organic nitrogen and saturation of polyaromatic compounds contained in the distillate feedstock. The first reaction zone treated effluent is separated into a heavy fraction and a lighter fraction with the heavy fraction being charged to a second reaction zone that also uses a base metal catalyst and is operated under high pressure conditions to provide for the saturation of monaromatic compounds that are contained in the heavy fraction. The inventive process provides for a high quality, low-sulfur and low-nitrogen diesel product that has a significantly lower aromatics content than the distillate feedstock and having a high value for its high Cetane Index.
Abstract translation: 提供具有显着浓度的氮和多芳族化合物的馏出物原料的性质的改进的方法。 该方法包括使用贱金属催化剂并在高压条件下操作以提供有机氮的加氢脱氮和馏出物原料中所含的多芳族化合物的饱和的第一反应区。 将第一反应区处理的流出物分离成重馏分和轻馏分，将重馏分装入第二反应区，第二反应区也使用贱金属催化剂，并在高压条件下操作以提供饱和的单芳族化合物， 包含在重馏分中。 本发明方法提供了高质量，低硫和低氮柴油产品，其具有比馏出物原料显着更低的芳族化合物含量，并且对于其高十六烷指数具有高值。
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8.发明授权Hydrothermal hydrocatalytic treatment of biomass using water tolerant catalysts 有权使用耐水催化剂的水热催化处理生物质
公开(公告)号：US09102584B2
公开(公告)日：2015-08-11
申请号：US14133709
申请日：2013-12-19
Applicant: Shell Oil Company
IPC: C07C29/153 , C01G1/02 , C07C29/60 , B01J21/06 , C10G1/06 , C10G3/00 , B01J37/20 , B01J23/882 , B01J27/19 , B01J37/02 , B01J23/86 , B01J23/88 , B01J27/188 , B01J35/00 , B01J35/10
CPC classification number: C07C29/60 , B01J21/063 , B01J21/066 , B01J23/86 , B01J23/88 , B01J23/882 , B01J27/188 , B01J27/19 , B01J35/002 , B01J35/008 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0201 , B01J37/20 , B01J2523/00 , C10G1/065 , C10G3/46 , C10G3/48 , C10G3/50 , C10G2300/1014 , Y02E50/343 , Y02P30/20 , B01J2523/48 , B01J2523/51 , B01J2523/68 , B01J2523/845
Abstract: A method of hydrothermal hydrocatalytic treating biomass is provided. Lignocellulosic biomass solids is provided to a hydrothermal digestion unit in the presence of a digestive solvent, and a supported hydrogenolysis catalyst containing (a) sulfur, (b) Mo or W, and (c) Co, Ni or mixture thereof, incorporated into a group 4 metal oxide support; (ii) heating the lignocellulosic biomass solids and digestive solvent in the presence of hydrogen, and the supported hydrogenolysis catalyst thereby forming a product solution containing plurality of oxygenated hydrocarbons, said catalyst retaining a crush strength of at least 50% after being subjected to an aqueous phase stability test compared with before the aqueous phase stability test or a crush strength of at least 0.25 kg after being subjected to an aqueous phase stability test.
Abstract translation: 提供了一种水热催化处理生物质的方法。 在消化溶剂存在下，将木质纤维素生物质固体提供给水热消解装置，以及含有（a）硫，（b）Mo或W的负载型氢解催化剂和（c）Co，Ni或其混合物 第4组金属氧化物载体; （ii）在氢气存在下加热木质纤维素生物质固体和消化溶剂，以及负载的氢解催化剂，由此形成含有多个氧化烃的产物溶液，所述催化剂在经受水溶液后保持至少50％的压碎强度 进行水相稳定性试验后的相稳定性试验或进行水相稳定性试验后的至少0.25kg的压碎强度。
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公开(公告)号：US09683182B2
公开(公告)日：2017-06-20
申请号：US14281485
申请日：2014-05-19
Applicant: SHELL OIL COMPANY
Inventor： John Anthony Smegal , Aristides Macris , Yvonne Johanna Lucas
Abstract: A process for making high cetane diesel. The process includes contacting a distillate feedstock in a hydrodenitrogenation and polyaromatics saturation zone and passing the resulting treated effluent to a high pressure stripping zone. The stripped liquid fraction from the high pressure stripping zone is contacted with a base metal catalyst under monoaromatics saturation conditions to yield a reactor product. The reactor product undergoes a separation to provide a hydrogen portion and a dearomatized distillate portion with the hydrogen portion being recycled and introduced into the high pressure stripping zone.
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公开(公告)号：US09447345B2
公开(公告)日：2016-09-20
申请号：US14045190
申请日：2013-10-03
Applicant: Shell Oil Company
Inventor： Joseph Broun Powell , John Anthony Smegal
CPC classification number: C10L1/1802 , C10G3/42 , C10G3/50 , Y02E50/343 , Y02P30/20 , Y02T50/678
Abstract: A partially digested biomass solids is converted in a fixed bed catalytic reduction reactor under hydrothermal catalytic condition with a supported metal catalyst having a high void fraction. The catalyst having high void fraction allows high permeability and extends reaction run time.
Abstract translation: 在具有高空隙率的负载金属催化剂的水热催化条件下，在固定床催化还原反应器中转化部分消化的生物质固体。 具有高空隙率的催化剂允许高渗透性并延长反应运行时间。
