摘要:
The membrane electrode assembly of the present invention for the proton-exchange membrane fuel cell includes a polymer electrolyte membrane and an electrode catalyst layer, wherein at least a part of the polymer electrolyte membrane infiltrates into the electrode catalyst layer, and wherein the polymer electrolyte membrane is formed by polymerizing a composition containing at least a compound having proton conductivity and a compound having activity to an active energy ray, or a composition containing at least a compound having proton conductivity and activity to the active energy ray. The object of the present invention is to provide a membrane electrolyte assembly for realizing a high-output proton-exchange membrane fuel cell by improving a bonding state between the polymer electrolyte membrane and the electrode catalyst layer to reduce an internal resistance, and by providing a three-dimensional three-phase interface to increase reaction areas.
摘要:
There are provided a polymer electrolyte membrane having at least one surface with an average surface roughness Ra′ of from 30 nm to 500 nm and a surface area ratio Sr of 1.2 or more in which Sr is defined as S/S0 with S0 representing a surface area when the at least one surface is ideally flat and S representing an actual surface area of the at least one surface, and a polymer electrolyte fuel cell comprising the polymer electrolyte membrane. Thereby, a polymer electrolyte fuel cell is provided that improves the efficiency of contact between the polymer electrolyte membrane and the catalyst, efficiently separates hydrogen ions and electrons produced on the catalyst, and provides high output characteristics.
摘要:
An electrolyte membrane made of a phosphate-containing siloxane-based polymer for fuel cell, where the polymer comprises a siloxane backbone and a poly(meth)acrylate chain to which phosphate groups are attached, and the polymer is formed by vinyl polymerization of a silane compound having a (meth)acrylate functional group or a hydrolysis-polycondensation product thereof and a (meth)acrylate compound having a phosphate group, followed by siloxane crosslinking. The electrolyte membrane of a siloxane-based polymer has a high conductivity for a fuel cell.
摘要:
An electrolyte membrane made of a phosphate-containing siloxane-based polymer for fuel cell, where the polymer comprises a siloxane backbone and a poly(meth)acrylate chain to which phosphate groups are attached, and the polymer is formed by vinyl polymerization of a silane compound having a (meth)acrylate functional group or a hydrolysis-polycondensation product thereof and a (meth)acrylate compound having a phosphate group, followed by siloxane crosslinking. The electrolyte membrane of a siloxane-based polymer has a high conductivity for a fuel cell.
摘要:
There are provided a polymer electrolyte membrane having at least one surface with an average surface roughness Ra′ of from 30 nm to 500 nm and a surface area ratio Sr of 1.2 or more in which Sr is defined as S/S0 with S0 representing a surface area when the at least one surface is ideally flat and S representing an actual surface area of the at least one surface, and a polymer electrolyte fuel cell comprising the polymer electrolyte membrane. Thereby, a polymer electrolyte fuel cell is provided that improves the efficiency of contact between the polymer electrolyte membrane and the catalyst, efficiently separates hydrogen ions and electrons produced on the catalyst, and provides high output characteristics.
摘要翻译:提供了具有至少一个平均表面粗糙度Ra'为30nm至500nm并且表面积比Sr为1.2或更大的表面积比Sr的聚合物电解质膜,其中Sr定义为S / S < / SUB>,其表示当所述至少一个表面理想地平坦且S表示所述至少一个表面的实际表面积时的表面积,以及包含所述聚合物电解质的聚合物电解质燃料电池 膜。 由此,提供了提高高分子电解质膜与催化剂的接触效率的高分子电解质型燃料电池,能有效地分离在催化剂上产生的氢离子和电子,提供高输出特性。
摘要:
An anti-fogging coating material is disclosed which comprises a phosphoric acid compound binder; and oxide particles having an average particle diameter of 1 to 300 nm mixed with the phosphoric acid compound binder and provides an anti-fogging coating with a high hydrophilic property and a high water absorption property, capable of retaining the high hydrophilic property for a long period of time.
摘要:
A DNA hybrid which comprises a porous oxide matrix and DNA immobilized thereon, and is useful for environmental clean-up, where the hybrid is prepared by removing a dispersion medium from a dispersion of colloidal oxide and DNA.
摘要:
A DNA hybrid which comprises a porous oxide matrix and DNA immobilized thereon, and is useful for environmental clean-up, where the hybrid is prepared by removing a dispersion medium from a dispersion of colloidal oxide and DNA.
摘要:
Provided are a DNA carrier where DNA is firmly held in a substrate, which can reduce the elution of DNA into water and can take full advantage of the capability of DNA to selectively and specifically collect a substance; and a method of producing the DNA carrier. Also provided is a collection system using DNA, which can be used in the high-accuracy detection of a particular substance and in an environmental cleanup capable of efficiently removing a substance, in which the DNA carrier is used to collect the substance contained in air or water by taking full advantage of the capability of DNA to selectively and specifically collect the substance. The DNA carrier is one where DNA is held in a porous matrix containing polyorganosiloxane with a basic functional group and particles. Preferably, the polyorganosiloxane with a basic functional group contains a hydrolysis condensate of one or more of particular silane compounds with an amino group.
摘要:
A DNA hybrid which comprises a porous oxide matrix and DNA immobilized thereon, and is useful for environmental clean-up, where the hybrid is prepared by removing a dispersion medium from a dispersion of colloidal oxide and DNA.