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公开(公告)号：US10301234B2
公开(公告)日：2019-05-28
申请号：US14591850
申请日：2015-01-07
发明人： Greg Nyce , Richard Black , Peter Czerpak , Carlos Faz , Erik Freer , Hatem Harraz , Ajay Madgavkar , Jarod McCormick , William Michalak , Bipinkumar Patel , Guido Radaelli , Tim A. Rappold , Ron Runnebaum , Erik C. Scher , Aihua Zhang , Hassan Taheri , Humera A. Rafique , Joel Cizeron , Jin Ki Hong , Wayne Schammel
IPC分类号： B01J19/00 , B01J19/24 , B01J29/40 , C07C1/04 , C07C1/12 , C07C2/08 , C07C2/12 , C07C2/58 , C07C2/84 , C07C5/327 , C10G11/00 , C07C5/09 , C07C5/05 , C07C4/02 , C10G50/00 , C10G57/02 , C10L3/10 , F25J3/02 , C10G9/00 , C07C1/06
摘要： Integrated systems are provided for the production of higher hydrocarbon compositions, for example liquid hydrocarbon compositions, from methane using an oxidative coupling of methane system to convert methane to ethylene, followed by conversion of ethylene to selectable higher hydrocarbon products. Integrated systems and processes are provided that process methane through to these higher hydrocarbon products.
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公开(公告)号：US20180222818A1
公开(公告)日：2018-08-09
申请号：US15699798
申请日：2017-09-08
发明人： Guido Radaelli , Humera A. Rafique , Srinivas Vuddagiri , Erik C. Scher , Jarod McCormick , Joel Cizeron , Bipinkumar Patel , Satish Lakhapatri
摘要： The present disclosure provides oxidative coupling of methane (OCM) systems for small scale and world scale production of olefins. An OCM system may comprise an OCM subsystem that generates a product stream comprising C2+ compounds and non-C2+ impurities from methane and an oxidizing agent. At least one separations subsystem downstream of, and fluidically coupled to, the OCM subsystem can be used to separate the non-C2+ impurities from the C2+ compounds. A methanation subsystem downstream and fluidically coupled to the OCM subsystem can be used to react H2 with CO and/or CO2 in the non-C2+ impurities to generate methane, which can be recycled to the OCM subsystem. The OCM system can be integrated in a non-OCM system, such as a natural gas liquids system or an existing ethylene cracker.
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公开(公告)号：US20180093931A1
公开(公告)日：2018-04-05
申请号：US15647806
申请日：2017-07-12
发明人： Wayne P. Schammel , Anja Rumplecker , Joel M. Cizeron , Erik C. Scher , Fabio R. Zurcher , Greg Nyce , Jarod McCormick , Marian Alcid , Joel Gamoras , Daniel Rosenberg , Erik-Jan Ras
IPC分类号： C07C2/84 , B01J23/10 , B01J23/889 , B01J35/06 , B01J37/03 , B01J37/08 , C07C2/78 , B01J23/34 , C07C11/04
CPC分类号： C07C2/84 , B01J23/10 , B01J23/34 , B01J23/8892 , B01J35/06 , B01J37/03 , B01J37/084 , B01J37/088 , B01J2523/00 , C07C2/78 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2523/02 , C07C2523/10 , C07C2523/30 , C07C2523/34 , C07C2523/75 , C07C2523/889 , Y02P20/52 , B01J2523/24 , B01J2523/3706 , B01J2523/3725 , B01J2523/11 , B01J2523/22 , B01J2523/72 , B01J2523/12 , B01J2523/845 , B01J2523/69 , C07C11/04
摘要： Metal oxide catalysts comprising various dopants are provided. The catalysts are useful as heterogenous catalysts in a variety of catalytic reactions, for example, the oxidative coupling of methane to C2 hydrocarbons such as ethane and ethylene. Related methods for use and manufacture of the same are also disclosed.
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4.发明申请公开(公告)号：US20170341997A1
公开(公告)日：2017-11-30
申请号：US15418080
申请日：2017-01-27
发明人： Greg Nyce , Erik C. Scher , Ajay Madgavkar , Samuel Weinberger , Rahul Iyer , Lawrence Peck , Joel Herger , Benjamin Saydah
CPC分类号： C07C2/04 , C07C2/82 , C07C2/84 , C10G50/00 , C10G2300/1025 , F25J3/0219 , F25J3/0233 , F25J3/0238 , F25J3/0257 , F25J2205/04 , F25J2210/12 , F25J2215/62 , F25J2220/02 , F25J2230/30 , F25J2240/02 , F25J2245/02 , Y02P20/125 , C07C11/04
摘要： Integrated systems are provided for the production of higher hydrocarbon compositions, for example liquid hydrocarbon compositions, from methane using an oxidative coupling of methane system to convert methane to ethylene, followed by conversion of ethylene to selectable higher hydrocarbon products. Integrated systems and processes are provided that process methane through to these higher hydrocarbon products.
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公开(公告)号：US20170260114A1
公开(公告)日：2017-09-14
申请号：US15335183
申请日：2016-10-26
发明人： Greg Nyce , Peter Czerpak , Carlos Faz , Jarod McCormick , William Michalak , Bipinkumar Patel , Guido Radaelli , Tim A. Rappold , Ron Runnebaum , Erik C. Scher , Aihua Zhang , Joel Cizeron
IPC分类号： C07C2/12 , C07C1/12 , C07C1/04 , C07C2/84 , C07C5/327 , C07C11/04 , C07C5/05 , B01J19/24 , C10L3/10 , C10G50/00 , C07C4/02 , F25J3/02 , C10G57/02 , C07C5/09
CPC分类号： C07C2/84 , B01J19/24 , B01J19/245 , B01J29/40 , B01J2219/00074 , B01J2219/00103 , B01J2219/24 , C07C1/0425 , C07C1/0435 , C07C1/06 , C07C1/12 , C07C2/12 , C07C2/58 , C07C4/02 , C07C5/05 , C07C5/09 , C07C5/327 , C07C2523/46 , C07C2523/755 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/70 , C07C2529/85 , C10G9/00 , C10G11/00 , C10G50/00 , C10G57/02 , C10G2400/20 , C10G2400/30 , C10L3/10 , F25J3/0209 , F25J3/0219 , F25J3/0233 , F25J3/0238 , F25J3/0247 , F25J3/0257 , F25J2200/02 , F25J2200/74 , F25J2205/04 , F25J2210/02 , F25J2210/04 , F25J2210/12 , F25J2230/08 , F25J2240/02 , F25J2245/02 , F25J2260/20 , F25J2260/60 , F25J2270/04 , F25J2270/06 , F25J2270/12 , F25J2270/60 , F25J2270/90 , F25J2290/80 , Y02P20/52 , Y02P20/582 , Y02P30/40 , C07C11/04
摘要： Integrated systems are provided for the production of higher hydrocarbon compositions, for example liquid hydrocarbon compositions, from methane using an oxidative coupling of methane system to convert methane to ethylene, followed by conversion of ethylene to selectable higher hydrocarbon products. Integrated systems and processes are provided that process methane through to these higher hydrocarbon products.
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公开(公告)号：US09701597B2
公开(公告)日：2017-07-11
申请号：US14592668
申请日：2015-01-08
发明人： Humera A. Rafique , Srinivas Vuddagiri , Hatem Harraz , Guido Radaelli , Erik C. Scher , Jarod McCormick , Rahul Iyer , Suchia Duggal , Joel Cizeron , Jin Ki Hong
IPC分类号： C07C2/84 , B01J19/24 , C07C1/04 , B01J23/00 , C07C1/12 , C07C5/327 , B01J21/04 , B01J23/46 , B01J23/755 , B01J35/00 , B01J35/06 , C07C4/02
CPC分类号： C07C2/84 , B01J19/245 , B01J21/04 , B01J23/00 , B01J23/462 , B01J23/755 , B01J35/0013 , B01J35/06 , B01J2219/00006 , B01J2219/00074 , B01J2219/24 , C07C1/041 , C07C1/0425 , C07C1/0485 , C07C1/12 , C07C4/02 , C07C5/327 , Y02P20/121 , Y02P20/123 , Y02P20/124 , Y02P20/126 , Y02P20/52 , Y02P20/572 , C07C9/04 , C07C11/02 , C07C11/04
摘要： The present disclosure provides oxidative coupling of methane (OCM) systems for small scale and world scale production of olefins. An OCM system may comprise an OCM subsystem that generates a product stream comprising C2+ compounds and non-C2+ impurities from methane and an oxidizing agent. At least one separations subsystem downstream of, and fluidically coupled to, the OCM subsystem can be used to separate the non-C2+ impurities from the C2+ compounds. A methanation subsystem downstream and fluidically coupled to the OCM subsystem can be used to react H2 with CO and/or CO2 in the non-C2+ impurities to generate methane, which can be recycled to the OCM subsystem. The OCM system can be integrated in a non-OCM system, such as a natural gas liquids system or an existing ethylene cracker.
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公开(公告)号：US09556086B2
公开(公告)日：2017-01-31
申请号：US14789901
申请日：2015-07-01
发明人： Wayne P. Schammel , Julian Wolfenbarger , Milind Ajinkya , Jon McCarty , Joel M. Cizeron , Sam Weinberger , Justin Dwight Edwards , David Sheridan , Erik C. Scher , Jarod McCormick , Fabio R. Zurcher , Alex Tkachenko , Joel Gamoras , Dmitry Karshtedt , Greg Nyce
CPC分类号： C07C2/84 , B01J8/001 , B01J8/0257 , B01J8/0453 , B01J8/0457 , B01J8/0496 , B01J8/067 , B01J2208/00044 , B01J2208/00061 , B01J2208/00176 , B01J2208/00256 , B01J2208/0053 , B01J2208/00539 , B01J2208/00548 , B01J2208/00557 , B01J2208/00628 , B01J2208/025 , B01J2208/027 , B01J2219/00198 , B01J2219/002 , B01J2219/00202 , B01J2219/00213 , B01J2219/00231 , B01J2219/00238 , C10G50/00 , C10G2300/1025 , C10G2300/1092 , C10G2400/02 , C10G2400/20 , Y02P30/40 , C07C11/02
摘要： Systems and methods conducive to the formation of one or more alkene hydrocarbons using a methane source and an oxidant in an oxidative coupling of methane (OCM) reaction are provided. One or more vessels each containing one or more catalyst beds containing one or more catalysts each having similar or differing chemical composition or physical form may be used. The one or more catalyst beds may be operated under a variety of conditions. At least a portion of the catalyst beds may be operated under substantially adiabatic conditions. At least a portion of the catalyst beds may be operated under substantially isothermal conditions.
摘要翻译： 提供了有助于在甲烷氧化偶联（OCM）反应中使用甲烷源和氧化剂形成一种或多种烯烃的系统和方法。 可以使用一个或多个容器，每个容器含有一种或多种含有一种或多种具有相似或不同化学组成或物理形式的催化剂床。 一种或多种催化剂床可以在各种条件下操作。 催化剂床的至少一部分可以在基本绝热的条件下操作。 催化剂床的至少一部分可以在基本等温条件下操作。
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公开(公告)号：US09512047B2
公开(公告)日：2016-12-06
申请号：US15076512
申请日：2016-03-21
发明人： Greg Nyce , Peter Czerpak , Carlos Faz , Jarod McCormick , William Michalak , Bipinkumar Patel , Guido Radaelli , Tim A. Rappold , Ron Runnebaum , Erik C. Scher , Aihua Zhang , Joel Cizeron
IPC分类号： C07C1/00 , C07C27/00 , C07C2/12 , B01J19/24 , C07C1/12 , C07C1/04 , C07C2/84 , C07C5/327 , C07C5/09 , C07C5/05 , C07C4/02 , C10G50/00 , C10G57/02 , C10L3/10
CPC分类号： C07C2/12 , B01J19/24 , B01J19/245 , B01J2219/00074 , B01J2219/24 , C07C1/0425 , C07C1/12 , C07C2/84 , C07C4/02 , C07C5/05 , C07C5/09 , C07C5/327 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/70 , C07C2529/85 , C10G9/00 , C10G50/00 , C10G57/02 , C10G2400/20 , C10G2400/30 , C10L3/10 , F25J3/0209 , F25J3/0219 , F25J3/0233 , F25J3/0238 , F25J3/0247 , F25J3/0257 , F25J2200/02 , F25J2200/74 , F25J2205/04 , F25J2210/02 , F25J2210/04 , F25J2210/12 , F25J2230/08 , F25J2240/02 , F25J2245/02 , F25J2260/20 , F25J2260/60 , F25J2270/04 , F25J2270/06 , F25J2270/12 , F25J2270/60 , F25J2270/90 , F25J2290/80 , Y02P20/52 , Y02P20/582 , Y02P30/40 , C07C11/04
摘要： Integrated systems are provided for the production of higher hydrocarbon compositions, for example liquid hydrocarbon compositions, from methane using an oxidative coupling of methane system to convert methane to ethylene, followed by conversion of ethylene to selectable higher hydrocarbon products. Integrated systems and processes are provided that process methane through to these higher hydrocarbon products.
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公开(公告)号：US20160107143A1
公开(公告)日：2016-04-21
申请号：US14777333
申请日：2014-03-14
发明人： Wayne P. Schammel , Anja Rumplecker , Joel M. Cizeron , Erik C. Scher , Fabio R. Zurcher , Greg Nyce , Jarod McCormick , Marian Alcid , Joel Gamoras , Daniel Rosenberg , Erik-Jan Ras
CPC分类号： C07C2/84 , B01J23/10 , B01J23/34 , B01J23/8892 , B01J35/06 , B01J37/03 , B01J37/084 , B01J37/088 , B01J2523/00 , B01J2523/22 , B01J2523/72 , C07C2/78 , C07C11/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2523/02 , C07C2523/10 , C07C2523/30 , C07C2523/34 , C07C2523/75 , C07C2523/889 , Y02P20/52 , B01J2523/24 , B01J2523/3706 , B01J2523/3725 , B01J2523/11 , B01J2523/12 , B01J2523/845 , B01J2523/69
摘要： Metal oxide catalysts comprising various dopants are provided. The catalysts are useful as heterogeneous catalysts in a variety of catalytic reactions, for example, the oxidative coupling of methane to C2 hydrocarbons such as ethane and ethylene. Related methods for use and manufacture of the same are also disclosed.
摘要翻译： 提供了包含各种掺杂剂的金属氧化物催化剂。 催化剂可用作各种催化反应中的非均相催化剂，例如甲烷与C2烃如乙烷和乙烯的氧化偶联。 还公开了相关的使用和制造方法。
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公开(公告)号：US20150307415A1
公开(公告)日：2015-10-29
申请号：US14789946
申请日：2015-07-01
发明人： Humera A. Rafique , Srinivas Vuddagiri , Guido Radaelli , Erik C. Scher , Jarod McCormick , Joel Cizeron
CPC分类号： C07C2/84 , B01J19/245 , B01J21/04 , B01J23/00 , B01J23/462 , B01J23/755 , B01J35/0013 , B01J35/06 , B01J2219/00006 , B01J2219/00074 , B01J2219/24 , C07C1/041 , C07C1/0425 , C07C1/0485 , C07C1/12 , C07C4/02 , C07C5/327 , Y02P20/121 , Y02P20/123 , Y02P20/124 , Y02P20/126 , Y02P20/52 , Y02P20/572 , C07C9/04 , C07C11/02 , C07C11/04
摘要： The present disclosure provides oxidative coupling of methane (OCM) systems for small scale and world scale production of olefins. An OCM system may comprise an OCM subsystem that generates a product stream comprising C2+ compounds and non-C2+ impurities from methane and an oxidizing agent. At least one separations subsystem downstream of, and fluidically coupled to, the OCM subsystem can be used to separate the non-C2+ impurities from the C2+ compounds. A methanation subsystem downstream and fluidically coupled to the OCM subsystem can be used to react H2 with CO and/or CO2 in the non-C2+ impurities to generate methane, which can be recycled to the OCM subsystem. The OCM system can be integrated in a non-OCM system, such as a natural gas liquids system or an existing ethylene cracker.
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