Cyclic amine based polymers and process for their production
    1.
    发明授权
    Cyclic amine based polymers and process for their production 有权
    循环胺基聚合物及其生产方法

    公开(公告)号:US6111056A

    公开(公告)日:2000-08-29

    申请号:US153307

    申请日:1998-09-15

    摘要: A cyclic amine containing polymer substantially free of primary and secondary amino groups which is prepared by reacting:a) an amine selected from the group consisting of:i) cyclic amines having at least one nitrogen atom in the ring and at least one primary amino alkyl group bonded to the nitrogen atom of the ring, andii) mixtures of cyclic amines containing at least two nitrogen atoms which react with a cross-linking agent with at least one other amine containing 1-6 nitrogen atoms which react with a cross-linking agent, withb) at least one cross-linker selected from the group consisting of at least one compound containing two groups which react with the primary amino group and said nitrogen atoms and mixtures of at least one compound containing two groups which react with the primary amino group and said nitrogen atoms with at least one compound containing at least three groups which react with the primary amino group and said nitrogen atoms in a molar ratio of (a):(b) of from 2.5:1 to 1:1.5 thereby forming a cyclic amine containing polymer containing primary or secondary amino groups and reacting said cyclic amine based polymer, withc) an alkylating agent selected from the group consisting of epoxides, alkyl halides, arylalkyl halides, dimethyl sulfate, diethyl sulfate, mixtures of formic acid and an aldehyde, and mixtures of formic acid and a ketone, to convert more than 80% of the primary and secondary nitrogen groups into tertiary nitrogen groups.

    摘要翻译: 一种基本上不含伯和仲氨基的含环胺的聚合物,其通过以下方法制备:a)选自以下的胺:i)环中具有至少一个氮原子的环胺和至少一个伯氨基烷基 基团与环的氮原子键合,以及ii)含有至少两个氮原子的环状胺的混合物,其与交联剂与至少一种含有1-6个氮原子的其它胺反应,其与交联反应 其中b)至少一个选自至少一种含有两个与伯氨基和所述氮原子反应的基团的化合物的交联剂以及至少一种含有两个与主要氨基反应的基团的化合物的混合物 氨基和所述氮原子与至少一种含有至少三个与伯氨基和所述氮原子反应的化合物,其摩尔比为(a):(b)为2 1.5:1至1:1.5,由此形成含有伯胺或仲氨基的含环胺的聚合物,并使所述环胺基聚合物与c)选自环氧化物,烷基卤,芳烷基卤化物,二甲基 硫酸盐,二乙基硫酸盐,甲酸和醛的混合物,以及甲酸和酮的混合物,将80%以上的初级和次级氮基团转化为叔氮基团。

    Polymer and process for their production
    3.
    发明授权
    Polymer and process for their production 有权
    聚合物及其生产工艺

    公开(公告)号:US6111057A

    公开(公告)日:2000-08-29

    申请号:US131234

    申请日:1998-08-07

    摘要: An amino acid based polymer, oligomer or copolymer containing at least 5 mol % of units of a basic amino acid selected from the group consisting of lysine, argenine, ortnithine, trgptophane and mixtures thereof and at least about 5 mol % of a polymerizable compound selected from the group consisting of aliphatic or cycloaliphatic amines, alicyclic amines, diamines, triamines, tetraamines, aliphatic amino alcohols or mixtures thereof, an a process for the production of the said polymer, oligomer or copolymer by condensing at a temperature of at least 120.degree. C. said basic amino acid with at least one of said polymerizable compounds.

    摘要翻译: 含有至少5摩尔%的碱基氨基酸的单元的氨基酸类聚合物,低聚物或共聚物,所述碱性氨基酸选自赖氨酸,argenine,ortnithine,trgptophone及其混合物,以及至少约5mol%选择的可聚合化合物 由脂族或脂环族胺,脂环族胺,二胺,三胺,四胺,脂族氨基醇或其混合物组成的组,通过在至少120℃的温度下冷凝来生产所述聚合物,低聚物或共聚物的方法 C.所述碱性氨基酸与所述可聚合化合物中的至少一种。

    Condensation products of basic amino acids with copolymerizable
compounds and a process for their production
    4.
    发明授权
    Condensation products of basic amino acids with copolymerizable compounds and a process for their production 有权
    碱性氨基酸与可共聚化合物的缩合产物及其生产方法

    公开(公告)号:US6034204A

    公开(公告)日:2000-03-07

    申请号:US131282

    申请日:1998-08-07

    摘要: Condensation products of basic amino acids with copolymerizable compounds which are obtainable by condensing(a) a basic amino acid selected from the group consisting of lysine, arginine, ornithine, tryptophane and mixtures thereof,(b) a copolymerizable compound selected from the group consisting of saturated monobasic carboxylic acids, unsaturated mono-basic carboxylic acids, polybasic carboxylic acids, carboxylic acid anhydrides, diketenes, monohydroxycarboxylic acids, polyhydroxycarboxylic acids and mixtures thereof, and optionally(c) at least one compound selected from the group consisting of amines, lactams, non-proteinogenic acids, alcohols, alkoxylated alcohols, alkoxylated amines, amino sugars, carbohydrates and sugar carboxylic acidsin a molar ratio of (a):(b) of from 100:1 to 1:1 at a temperature of at least 120.degree. C., and a process for the production of said condensation products by condensing compounds (a) and (b) and optionally (c) at a temperature of from 120.degree. to 300.degree. C.

    摘要翻译: 碱性氨基酸与可共聚化合物的缩合产物可通过将(a)选自赖氨酸,精氨酸,鸟氨酸,色氨酸及其混合物的碱性氨基酸缩合得到(a)可共聚合的化合物, 饱和一元羧酸,不饱和单碱羧酸,多元羧酸,羧酸酐,二烯酮,单羟基羧酸,聚羟基羧酸及其混合物,以及任选地(c)至少一种选自胺,内酰胺, 摩尔比为(a):(b)为100:1-1:1的非蛋白质酸,醇,烷氧基化醇,烷氧基化胺,氨基糖,碳水化合物和糖羧酸,至少120℃ 以及通过将化合物(a)和(b)和任选(c)在120℃至3℃的温度下缩合来生产所述缩合产物的方法 00℃