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    Method Of Preparing And Using A Molecular Sieve
    1.
    发明申请
    Method Of Preparing And Using A Molecular Sieve 审中-公开
    制备和使用分子筛的方法

    公开(公告)号：US20100087610A1

    公开(公告)日：2010-04-08

    申请号：US12533745

    申请日：2009-07-31

    申请人： Stephen N. Vaughn ,  Machteld M. Mertens ,  Thomas H. Colle

    发明人： Stephen N. Vaughn ,  Machteld M. Mertens ,  Thomas H. Colle

    IPC分类号： C08F4/52 ,  C01B37/08 ,  C07C1/00

    CPC分类号： C08F10/00 ,  B01J29/85 ,  C01B39/54 ,  C07C1/20 ,  C07C2529/85 ,  C08F110/02 ,  C08F210/16 ,  Y02P20/52 ,  Y02P30/42 ,  C07C11/04 ,  C07C11/06 ,  C07C11/02 ,  C08F4/16 ,  C08F4/12 ,  C08F210/06

    摘要： A crystalline microporous silicoaluminophosphate (SAPO) molecular sieve is prepared by: (a) providing a reaction mixture having a molar composition within the following ranges: P:Al from 0.75 to 1.25, Si:Al2 from 0.01 to 0.32, H2O:Al2 from 25 to 50, and R:Al2 from 1 to 3, where R designates a structure directing agent (template), and wherein the molar ratios for the aluminum, phosphorus, and silicon sources are calculated based on the oxide forms; (b) heating the mixture to a crystallization temperature of between 150° C. to 250° C. to form the crystalline molecular sieve within the reaction mixture; and (c) following crystallization in step (b), aging the crystalline molecular sieve in an alkaline liquid at a temperature below the crystallization temperature from 0.5 hour for up to 120 hours. Aging can affect both catalyst life and catalyst activity.

    摘要翻译： 通过以下步骤制备结晶微孔硅铝磷酸盐（SAPO）分子筛：（a）提供具有以下范围内的摩尔组成的反应混合物：P：Al为0.75至1.25，Si：Al 2为0.01至0.32，H 2 O：Al 2为25 至50，R：Al 2为1至3，其中R表示结构导向剂（模板），其中基于氧化物形式计算铝，磷和硅源的摩尔比; （b）将混合物加热至150℃至250℃的结晶温度以在反应混合物内形成结晶分子筛; 和（c）在步骤（b）中结晶之后，在低于结晶温度的温度下将结晶分子筛在碱性液体中老化0.5小时达120小时。 老化可影响催化剂寿命和催化剂活性。

    Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins
    2.
    发明授权
    Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins 有权
    含有菱沸石的分子筛的合成及其在含氧化合物转化为烯烃的用途

    公开(公告)号：US08399578B2

    公开(公告)日：2013-03-19

    申请号：US13589289

    申请日：2012-08-20

    申请人： Machteld M. Mertens ,  Stephen N. Vaughn

    发明人： Machteld M. Mertens ,  Stephen N. Vaughn

    IPC分类号： C01B39/54 ,  C01B37/08 ,  C07C1/20 ,  C07C2/10

    CPC分类号： C07C1/20 ,  B01J29/85 ,  B01J29/90 ,  B01J2229/42 ,  C01B39/54 ,  C07C2529/85 ,  Y02P20/52 ,  Y02P20/584 ,  Y02P30/42 ,  C07C11/06 ,  C07C11/04

    摘要： In a method of synthesizing a silicoaluminophosphate molecular sieve having 90+% CHA framework-type character, a reaction mixture is prepared comprising sources of water, silicon, aluminum, and phosphorus, as well as an organic template. In one aspect, the reaction mixture is heated at more than 10° C./hour to a crystallization temperature and is retained at the crystallization temperature or within the crystallization temperature range for a crystallization time from 16 hours to 350 hours to produce the silicoaluminophosphate molecular sieve. In another aspect, the reaction mixture is heated at less than 10° C./hour to a crystallization temperature from about 150° C. to about 225° C. and is then retained there for less than 10 hours to produce the silicoaluminophosphate molecular sieve. The molecular sieve can then be recovered from the reaction mixture and, preferably, used in a hydrocarbon conversion process, such as oxygenates to olefins.

    摘要翻译： 在合成具有90 + CHA框架型特征的硅铝磷酸盐分子筛的方法中，制备包含水，硅，铝和磷源以及有机模板的反应混合物。 在一个方面，将反应混合物在大于10℃/小时加热至结晶温度，并保持在结晶温度或结晶温度范围内，结晶时间为16小时至350小时，以产生硅铝磷酸盐分子 筛。 在另一方面，将反应混合物在小于10℃/小时加热至约150℃至约225℃的结晶温度，然后将其保留在少于10小时以产生硅铝磷酸盐分子筛 。 然后可以从反应混合物中回收分子筛，并且优选用于烃转化方法，例如含氧化合物至烯烃。