公开(公告)号：US11211559B2

公开(公告)日：2021-12-28

申请号：US13273753

申请日：2011-10-14

申请人： Stephen R. Forrest ,  Brian E. Lassiter ,  Jun Y. Lee ,  Kyoung S. Yook ,  Soon O. Jeon ,  Byung D. Chin

发明人： Stephen R. Forrest ,  Brian E. Lassiter ,  Jun Y. Lee ,  Kyoung S. Yook ,  Soon O. Jeon ,  Byung D. Chin

IPC分类号： H01L51/44 ,  H01L51/00 ,  B82Y10/00 ,  H01L51/42

摘要： There is disclosed ultrathin film material templating layers that force the morphology of subsequently grown electrically active thin films have been found to increase the performance of small molecule organic photovoltaic (OPV) cells. There is disclosed electron-transporting material, such as hexaazatriphenylene-hexacarbonitrile (HAT-CN) can be used as a templating material that forces donor materials, such as copper phthalocyanine (CuPc) to assume a vertical-standing morphology when deposited onto its surface on an electrode, such as an indium tin oxide (ITO) electrode. It has been shown that for a device with HAT-CN as the templating buffer layer, the fill factor and short circuit current of CuPc:C60 OPVs were both improved compared with cells lacking the HAT-CN template. This is explained by the reduction of the series resistance due to the improved crystallinity of CuPc grown onto the ITO surface.

公开(公告)号：US20120090685A1

公开(公告)日：2012-04-19

申请号：US13273753

申请日：2011-10-14

申请人： Stephen R. Forrest ,  Brian E. Lassiter ,  Jun Y. Lee ,  Kyoung S. Yook ,  Soon O. Jeon ,  Byung D. Chin

发明人： Stephen R. Forrest ,  Brian E. Lassiter ,  Jun Y. Lee ,  Kyoung S. Yook ,  Soon O. Jeon ,  Byung D. Chin

IPC分类号： H01L51/44 ,  H01L51/46 ,  H01L51/48 ,  B82Y40/00 ,  B82Y99/00

CPC分类号： H01L51/0012 ,  B82Y10/00 ,  H01L51/001 ,  H01L51/0046 ,  H01L51/0072 ,  H01L51/424 ,  H01L51/4246 ,  H01L51/4253 ,  Y02E10/549 ,  Y02P70/521

摘要： There is disclosed ultrathin film material templating layers that force the morphology of subsequently grown electrically active thin films have been found to increase the performance of small molecule organic photovoltaic (OPV) cells. There is disclosed electron-transporting material, such as hexaazatriphenylene-hexacarbonitrile (HAT-CN) can be used as a templating material that forces donor materials, such as copper phthalocyanine (CuPc) to assume a vertical-standing morphology when deposited onto its surface on an electrode, such as an indium tin oxide (ITO) electrode. It has been shown that for a device with HAT-CN as the templating buffer layer, the fill factor and short circuit current of CuPc:C60 OPVs were both improved compared with cells lacking the HAT-CN template. This is explained by the reduction of the series resistance due to the improved crystallinity of CuPc grown onto the ITO surface.

摘要翻译： 已经公开了超薄膜材料模板层，其强制随后生长的电活性薄膜的形态已经被发现增加小分子有机光伏（OPV）电池的性能。 公开了电子传输材料，例如六氮杂三亚苯基 - 六甲腈（HAT-CN）可用作模板材料，其在诸如铜酞菁（CuPc）等沉积在其表面上时呈现垂直立体形态 诸如氧化铟锡（ITO）电极的电极。 已经表明，对于具有HAT-CN作为模板缓冲层的器件，与缺乏HAT-CN模板的细胞相比，CuPc：C60 OPV的填充因子和短路电流都有所改善。 这通过由于生长到ITO表面上的CuPc的改善的结晶度而降低串联电阻来解释。